{"id":793,"date":"2023-07-21T05:06:58","date_gmt":"2023-07-21T05:06:58","guid":{"rendered":"https:\/\/chemuza.org\/tr\/dimetilsulfoksit-dmso-c2h6os\/"},"modified":"2023-07-21T05:06:58","modified_gmt":"2023-07-21T05:06:58","slug":"dimetilsulfoksit-dmso-c2h6os","status":"publish","type":"post","link":"https:\/\/chemuza.org\/tr\/dimetilsulfoksit-dmso-c2h6os\/","title":{"rendered":"Dimetil s\u00fclfoksit (dmso) \u2013 c2h6os, 67-68-5"},"content":{"rendered":"

Dimetil s\u00fclfoksit (DMSO), polar ve polar olmayan bile\u015fikleri \u00e7\u00f6zme yetene\u011fine sahip, renksiz bir s\u0131v\u0131d\u0131r. Yayg\u0131n olarak organik reaksiyonlarda \u00e7\u00f6z\u00fcc\u00fc olarak ve h\u00fccre korunmas\u0131nda kriyoprotektan olarak kullan\u0131l\u0131r.<\/p>\n

\n\n\n\n\n\n\n\n
IUPAC Ad\u0131<\/td>\n Metils\u00fclfinilmetan<\/td>\n<\/tr>\n
Molek\u00fcler form\u00fcl<\/td>\n C2H6OS<\/td>\n<\/tr>\n
CAS numaras\u0131<\/td>\n 67-68-5<\/td>\n<\/tr>\n
E\u015f anlaml\u0131<\/td>\n DMSO, metils\u00fclfoksit, dimetils\u00fclfoksit, s\u00fclfinilbis (metan), metan, s\u00fclfinilbis-, vb.<\/td>\n<\/tr>\n
InChI<\/td>\n InChI=1S\/C2H6OS\/c1-4(2)3\/h1-2H3<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n

Dimetil s\u00fclfoksitin \u00f6zellikleri<\/strong><\/h2>\n

Dimetil s\u00fclfoksit form\u00fcl\u00fc<\/h3>\n

DMSO’nun kimyasal form\u00fcl\u00fc C2H6OS’tur. \u0130ki karbon atomu, alt\u0131 hidrojen atomu ve bir k\u00fck\u00fcrt atomunun yan\u0131 s\u0131ra bir oksijen atomundan olu\u015fur. Bu renksiz s\u0131v\u0131 bile\u015fik olduk\u00e7a polard\u0131r ve hem polar hem de polar olmayan bile\u015fikleri \u00e7\u00f6zebilir, bu da onu bir\u00e7ok organik reaksiyonda \u00e7ok y\u00f6nl\u00fc bir solvent haline getirir.<\/p>\n

Dimetils\u00fclfoksit Molar K\u00fctlesi<\/h3>\n

DMSO’nun molar k\u00fctlesi 78,13 g\/mol’d\u00fcr. Bu de\u011fer bir mol DMSO molek\u00fcl\u00fcn\u00fcn k\u00fctlesini temsil eder. Molek\u00fcl\u00fcn t\u00fcm kurucu atomlar\u0131n\u0131n atomik k\u00fctlelerinin eklenmesiyle hesaplan\u0131r. Molar k\u00fctle, stokiyometri, \u00e7\u00f6zelti konsantrasyonu ve molek\u00fcler a\u011f\u0131rl\u0131k belirleme dahil olmak \u00fczere bir\u00e7ok kimyasal hesaplamada \u00f6nemli bir parametredir.<\/p>\n

Dimetil s\u00fclfoksitin kaynama noktas\u0131<\/h3>\n

DMSO’nun kaynama noktas\u0131 standart bas\u0131n\u00e7ta 189\u00b0C’dir (372,2\u00b0F). Molek\u00fclleri aras\u0131nda g\u00fc\u00e7l\u00fc dipol-dipol etkile\u015fimlerinin varl\u0131\u011f\u0131 nedeniyle nispeten y\u00fcksek bir kaynama noktas\u0131na sahiptir. Bu \u00f6zellik onu polimerlerin ve farmas\u00f6tiklerin \u00fcretimi gibi \u00e7e\u015fitli uygulamalarda faydal\u0131 k\u0131lar.<\/p>\n

Dimetils\u00fclfoksit Erime Noktas\u0131<\/h3>\n

DMSO’nun erime noktas\u0131 standart bas\u0131n\u00e7ta 18,5\u00b0C’dir (65,3\u00b0F). Oda s\u0131cakl\u0131\u011f\u0131nda s\u0131v\u0131 kalmas\u0131n\u0131 sa\u011flayan d\u00fc\u015f\u00fck erime noktas\u0131na sahip bir bile\u015fiktir. Bu \u00f6zellik onu \u00e7e\u015fitli uygulamalarda, \u00f6zellikle h\u00fccrelerin ve dokular\u0131n korunmas\u0131nda yararl\u0131 bir \u00e7\u00f6z\u00fcc\u00fc haline getirir.<\/p>\n

Dimetil s\u00fclfoksitin yo\u011funlu\u011fu g\/mL<\/h3>\n

DMSO’nun yo\u011funlu\u011fu standart s\u0131cakl\u0131k ve bas\u0131n\u00e7ta 1,10 g\/mL’dir. Nispeten yo\u011fun bir s\u0131v\u0131d\u0131r, suda ve di\u011fer bir\u00e7ok organik \u00e7\u00f6z\u00fcc\u00fcde \u00e7\u00f6z\u00fcn\u00fcr. Bu \u00f6zellik onu \u00e7ok \u00e7e\u015fitli kimyasal reaksiyonlar ve i\u015flemler i\u00e7in ideal bir \u00e7\u00f6z\u00fcc\u00fc haline getirir.<\/p>\n

Dimetils\u00fclfoksit Molek\u00fcl A\u011f\u0131rl\u0131\u011f\u0131<\/h3>\n

DMSO’nun molek\u00fcler a\u011f\u0131rl\u0131\u011f\u0131 78,13 g\/mol’d\u00fcr. Molek\u00fclde bulunan t\u00fcm atomlar\u0131n atom a\u011f\u0131rl\u0131klar\u0131n\u0131n toplam\u0131d\u0131r. Molek\u00fcl a\u011f\u0131rl\u0131\u011f\u0131 bir\u00e7ok kimyasal hesaplamada, \u00f6zellikle bir \u00e7\u00f6zeltinin konsantrasyonunun ve bir maddenin a\u011f\u0131rl\u0131\u011f\u0131n\u0131n belirlenmesinde \u00f6nemli bir parametredir.<\/p>\n

Dimetil s\u00fclfoksitin yap\u0131s\u0131 <\/h3>\n
\n
\"Dimetil<\/figure>\n<\/div>\n

DMSO’nun yap\u0131s\u0131, iki metil grubuna ba\u011fl\u0131 merkezi bir k\u00fck\u00fcrt atomu ve kovalent ba\u011flarla bir oksijen atomundan olu\u015fur. S\u00fclf\u00fcr atomunun bir \u00e7ift ba\u011flanmayan elektronu vard\u0131r ve bu da molek\u00fcl\u00fc olduk\u00e7a polar hale getirir. Bu yap\u0131, polar ve polar olmayan bile\u015fikleri \u00e7\u00f6zmesine olanak tan\u0131r ve bu da onu bir\u00e7ok organik reaksiyonda \u00e7ok y\u00f6nl\u00fc bir \u00e7\u00f6z\u00fcc\u00fc haline getirir.<\/p>\n

Dimetil s\u00fclfoksitin \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011f\u00fc<\/h3>\n

DMSO, su, etanol, aseton ve kloroform dahil bir\u00e7ok organik \u00e7\u00f6z\u00fcc\u00fcde y\u00fcksek oranda \u00e7\u00f6z\u00fcnebilen bir bile\u015fiktir. Y\u00fcksek \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011f\u00fc, geni\u015f bir yelpazedeki bile\u015fikleri \u00e7\u00f6zmesine olanak tan\u0131r ve bu da onu, farmas\u00f6tik ve polimer \u00fcretimi gibi \u00e7e\u015fitli uygulamalarda yararl\u0131 bir \u00e7\u00f6z\u00fcc\u00fc haline getirir.<\/p>\n

\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n
D\u0131\u015f g\u00f6r\u00fcn\u00fc\u015f<\/td>\n Renksiz s\u0131v\u0131<\/td>\n<\/tr>\n
Spesifik yer \u00e7ekimi<\/td>\n 25\u00b0C’de 1,10 g\/mL<\/td>\n<\/tr>\n
Renk<\/td>\n Renksiz<\/td>\n<\/tr>\n
Koku<\/td>\n Kokusuz<\/td>\n<\/tr>\n
Molar k\u00fctle<\/td>\n 78,13 gr\/mol<\/td>\n<\/tr>\n
Yo\u011funluk<\/td>\n 25\u00b0C’de 1,10 g\/mL<\/td>\n<\/tr>\n
F\u00fczyon noktas\u0131<\/td>\n 18,5\u00b0C<\/td>\n<\/tr>\n
Kaynama noktas\u0131<\/td>\n 189\u00b0C<\/td>\n<\/tr>\n
Fla\u015f noktas\u0131<\/td>\n 88\u00b0C<\/td>\n<\/tr>\n
sudaki \u00e7\u00f6z\u00fcn\u00fcrl\u00fck<\/td>\n kar\u0131\u015fabilir<\/td>\n<\/tr>\n
\u00e7\u00f6z\u00fcn\u00fcrl\u00fck<\/td>\n Bir\u00e7ok organik \u00e7\u00f6z\u00fcc\u00fcyle kar\u0131\u015fabilir<\/td>\n<\/tr>\n
Buhar bas\u0131nc\u0131<\/td>\n 25\u00b0C’de 0,003 mmHg<\/td>\n<\/tr>\n
Buhar yo\u011funlu\u011fu<\/td>\n 2,7 (hava=1)<\/td>\n<\/tr>\n
pKa<\/td>\n 35<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n

Dimetil s\u00fclfoksitin g\u00fcvenli\u011fi ve tehlikeleri<\/strong><\/h2>\n

Dimetil s\u00fclfoksit (DMSO), i\u015flenmesi ve kullan\u0131lmas\u0131 nispeten g\u00fcvenli bir bile\u015fik olarak kabul edilir. Ancak temas\u0131 halinde ciltte ve g\u00f6zde tahri\u015fe neden olabilece\u011finden dikkatli kullan\u0131lmal\u0131d\u0131r. DMSO buharlar\u0131n\u0131n solunmas\u0131 da solunum yolu tahri\u015fine neden olabilir. DMSO’yu kullan\u0131rken eldiven ve g\u00f6zl\u00fck gibi uygun ki\u015fisel koruyucu ekipmanlar\u0131n kullan\u0131lmas\u0131 \u00f6nemlidir. DMSO yan\u0131c\u0131d\u0131r ve a\u00e7\u0131k alevlerden ve tutu\u015fturucu kaynaklardan uzak tutulmal\u0131d\u0131r. DMSO’nun serin, kuru, iyi havaland\u0131r\u0131lm\u0131\u015f bir alanda uyumsuz maddelerden uzakta saklanmas\u0131 da \u00f6nemlidir.<\/p>\n

\n\n\n\n\n\n\n\n\n\n
Tehlike sembolleri<\/td>\n XI<\/td>\n<\/tr>\n
G\u00fcvenlik A\u00e7\u0131klamas\u0131<\/td>\n S24\/25, S26, S36<\/td>\n<\/tr>\n
BM kimlik numaralar\u0131<\/td>\n 1993<\/td>\n<\/tr>\n
HS kodu<\/td>\n 2930.90.90<\/td>\n<\/tr>\n
Tehlike s\u0131n\u0131f\u0131<\/td>\n 3<\/td>\n<\/tr>\n
Paketleme grubu<\/td>\n III<\/td>\n<\/tr>\n
Toksisite<\/td>\n LD50 (oral, s\u0131\u00e7an) = 14,5 g\/kg<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n

Dimetil s\u00fclfoksit sentez y\u00f6ntemleri<\/strong><\/h2>\n

\u00c7e\u015fitli y\u00f6ntemler dimetil s\u00fclfoksiti (DMSO) sentezleyebilir.<\/p>\n

Yayg\u0131n bir y\u00f6ntem, dimetil s\u00fclf\u00fcr\u00fcn, g\u00fcm\u00fc\u015f oksit veya nitrojen dioksit gibi bir kataliz\u00f6r varl\u0131\u011f\u0131nda oksijen veya hidrojen peroksit<\/a> ile oksitlenmesidir.<\/p>\n

Ba\u015fka bir y\u00f6ntem, dimetil s\u00fclf\u00fcr\u00fcn k\u00fck\u00fcrt trioksit ile reaksiyonunu ve ard\u0131ndan hidrolizi i\u00e7erir. DMSO, dimetil s\u00fclfat\u0131n sodyum s\u00fclfit<\/a> veya sodyum bis\u00fclfit<\/a> ile reaksiyona sokulmas\u0131yla sentezlenebilir.<\/p>\n

Daha yeni bir y\u00f6ntem, bir iyonik s\u0131v\u0131 kataliz\u00f6r kullan\u0131larak dimetil s\u00fclf\u00fcrden DMSO’nun do\u011frudan sentezini i\u00e7erir. Bu y\u00f6ntem, sert kimyasallar\u0131n veya y\u00fcksek s\u0131cakl\u0131klar\u0131n kullan\u0131lmas\u0131n\u0131 gerektirmedi\u011fi i\u00e7in daha \u00e7evre dostu olma avantaj\u0131na sahiptir.<\/p>\n

Kullan\u0131lan y\u00f6ntem ne olursa olsun, DMSO \u00fcr\u00fcn\u00fcn\u00fcn safl\u0131\u011f\u0131 \u00e7e\u015fitli uygulamalarda kullan\u0131lmas\u0131 a\u00e7\u0131s\u0131ndan \u00f6nemlidir. Y\u00fcksek safl\u0131kta DMSO elde etmek i\u00e7in insanlar s\u0131kl\u0131kla dam\u0131tma ve kristalle\u015ftirme gibi safla\u015ft\u0131rma ad\u0131mlar\u0131n\u0131 kullan\u0131r. DMSO’nun sentez ve safla\u015ft\u0131rma s\u0131ras\u0131nda dikkatli bir \u015fekilde i\u015flenmesi de \u00f6nemlidir \u00e7\u00fcnk\u00fc toksik olabilir ve uygun \u015fekilde kullan\u0131lmad\u0131\u011f\u0131 takdirde insan sa\u011fl\u0131\u011f\u0131 ve \u00e7evre i\u00e7in risk olu\u015fturabilir.<\/p>\n

Dimetil S\u00fclfoksitin Kullan\u0131m Alanlar\u0131<\/strong><\/h2>\n

Dimetil s\u00fclfoksit (DMSO), benzersiz \u00f6zellikleri nedeniyle \u00e7e\u015fitli end\u00fcstrilerde geni\u015f bir uygulama alan\u0131na sahiptir. DMSO’nun baz\u0131 yayg\u0131n kullan\u0131mlar\u0131 \u015funlard\u0131r:<\/p>\n

    \n
  1. \u0130la\u00e7 end\u00fcstrisi: \u0130la\u00e7 form\u00fclasyonlar\u0131nda solvent ve transdermal penetrasyon artt\u0131r\u0131c\u0131 olarak kullan\u0131l\u0131r. Ayr\u0131ca h\u00fccre ve dokular\u0131n dondurularak saklanmas\u0131nda da kullan\u0131l\u0131r.<\/li>\n
  2. Kimya end\u00fcstrisi: \u00c7e\u015fitli organik ve inorganik bile\u015fikler i\u00e7in \u00e7\u00f6z\u00fcc\u00fc olarak, reaksiyon ortam\u0131 olarak ve organik sentezlerde indirgeyici madde olarak kullan\u0131l\u0131r.<\/li>\n
  3. Polimer end\u00fcstrisi: Poli\u00fcretanlar ve poliakrilonitril dahil olmak \u00fczere \u00e7e\u015fitli polimerlerin sentezinde \u00e7\u00f6z\u00fcc\u00fc olarak kullan\u0131l\u0131r.<\/li>\n
  4. Biyolojik ara\u015ft\u0131rma: H\u00fccreler ve dokular i\u00e7in kriyoprotektan olarak, protein kristalizasyonu i\u00e7in reaktif olarak ve membran proteinleri i\u00e7in solvent olarak kullan\u0131l\u0131r.<\/li>\n
  5. Veterinerlik: Atlar ve k\u00f6pekler i\u00e7in topikal analjezik ve antiinflamatuar olarak kullan\u0131l\u0131r.<\/li>\n
  6. Tar\u0131m: Mantar ilac\u0131 ve herbisit olarak ve ayr\u0131ca bitki b\u00fcy\u00fcme d\u00fczenleyicisi olarak kullan\u0131l\u0131r.<\/li>\n
  7. Elektronik end\u00fcstrisi: Elektronik cihazlar\u0131n \u00fcretiminde solvent ve elektrolit olarak kullan\u0131l\u0131r.<\/li>\n
  8. Boya ve kaplama end\u00fcstrisi: Boya ve kaplama \u00fcretiminde solvent ve dispersan olarak da kullan\u0131l\u0131r.<\/li>\n<\/ol>\n

    Sorular:<\/strong><\/h2>\n

    S: Dimetil s\u00fclfoksit polar m\u0131d\u0131r?<\/h3>\n

    C: Evet, DMSO, olduk\u00e7a polar S=O ba\u011f\u0131 ve iki polar metil grubunun varl\u0131\u011f\u0131 nedeniyle polar bir \u00e7\u00f6z\u00fcc\u00fcd\u00fcr.<\/p>\n

    S: Dimetil s\u00fclfoksit iyonik mi yoksa kovalent mi?<\/h3>\n

    C: DMSO kovalent bir bile\u015fiktir \u00e7\u00fcnk\u00fc iyonlar aras\u0131nda elektron aktarmak yerine atomlar\u0131 aras\u0131nda payla\u015f\u0131lan elektronlardan olu\u015fur.<\/p>\n

    S: Dimetil s\u00fclfoksit ne i\u00e7in kullan\u0131l\u0131r?<\/h3>\n

    C: DMSO, ila\u00e7 end\u00fcstrisinde genellikle solvent ve transdermal penetrasyon artt\u0131r\u0131c\u0131 olarak kullan\u0131l\u0131r. Ayr\u0131ca kimya, polimer, biyolojik ara\u015ft\u0131rma, tar\u0131m ve elektronik end\u00fcstrilerinde de \u00e7e\u015fitli uygulamalara sahiptir.<\/p>\n

    S: Dimetil s\u00fclfoksit elektri\u011fi iletir mi?<\/h3>\n

    C: Hay\u0131r, DMSO iletken olmayan bir solventtir, yani elektri\u011fi iletmez.<\/p>\n

    S: Dimetil s\u00fclfoksitteki (C2H6SO) karbonun \u00fc\u00e7 anlaml\u0131 rakama yuvarlanm\u0131\u015f k\u00fctle y\u00fczdesi nedir?<\/h3>\n

    C: C2H6SO’nun molek\u00fcler a\u011f\u0131rl\u0131\u011f\u0131 78,13 g\/mol’d\u00fcr. Bir mol C2H6SO’daki karbon k\u00fctlesi 24,02 g\/mol’d\u00fcr. Bu nedenle dimetil s\u00fclfoksitteki karbonun k\u00fctle y\u00fczdesi %30,75’tir.<\/p>\n

    S: Dimetil s\u00fclfoksitteki karbonun k\u00fctlesi nedir?<\/h3>\n

    C: DMSO’nun molek\u00fcler a\u011f\u0131rl\u0131\u011f\u0131 78,13 g\/mol’d\u00fcr. Bir mol DMSO’daki karbon k\u00fctlesi 24,02 g\/mol’d\u00fcr. Bu nedenle DMSO’daki karbon k\u00fctlesi 24,02 gramd\u0131r.<\/p>\n

    S: DMSO solventi g\u00fcvenli midir?<\/h3>\n

    C: DMSO do\u011fru kullan\u0131ld\u0131\u011f\u0131nda genellikle g\u00fcvenlidir ancak do\u011fru \u015fekilde kullan\u0131lmad\u0131\u011f\u0131 takdirde ciltte tahri\u015fe, alerjik reaksiyonlara ve di\u011fer olumsuz etkilere neden olabilir. DMSO’yu kullan\u0131rken uygun g\u00fcvenlik \u00f6nlemlerini takip etmek \u00f6nemlidir.<\/p>\n

    Soru: A\u015fa\u011f\u0131daki alkil halojen\u00fcrlerden hangisi dimetil s\u00fclfoksit i\u00e7indeki NaN3 ile en yava\u015f reaksiyona girer?<\/h3>\n

    C: DMSO’da bir alkil halojen\u00fcr\u00fcn NaN3 ile reaksiyon h\u0131z\u0131, alkil grubunun ve ayr\u0131lan grubun do\u011fas\u0131na ba\u011fl\u0131d\u0131r. S\u00f6z konusu spesifik alkil halojen\u00fcrleri bilmeden hangisinin en yava\u015f reaksiyona girdi\u011fini belirlemek imkans\u0131zd\u0131r.<\/p>\n","protected":false},"excerpt":{"rendered":"

    Dimetil s\u00fclfoksit (DMSO), polar ve polar olmayan bile\u015fikleri \u00e7\u00f6zme yetene\u011fine sahip, renksiz bir s\u0131v\u0131d\u0131r. Yayg\u0131n olarak organik reaksiyonlarda \u00e7\u00f6z\u00fcc\u00fc olarak ve h\u00fccre korunmas\u0131nda kriyoprotektan olarak kullan\u0131l\u0131r. IUPAC Ad\u0131 Metils\u00fclfinilmetan Molek\u00fcler form\u00fcl C2H6OS CAS numaras\u0131 67-68-5 E\u015f anlaml\u0131 DMSO, metils\u00fclfoksit, dimetils\u00fclfoksit, s\u00fclfinilbis (metan), metan, s\u00fclfinilbis-, vb. InChI InChI=1S\/C2H6OS\/c1-4(2)3\/h1-2H3 Dimetil s\u00fclfoksitin \u00f6zellikleri Dimetil s\u00fclfoksit form\u00fcl\u00fc DMSO’nun kimyasal … Devam\u0131n\u0131 oku<\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[5],"tags":[],"yoast_head":"\nDimetil s\u00fclfoksit (DMSO) - C2H6OS, 67-68-5<\/title>\n<meta name=\"description\" content=\"Dimetil s\u00fclfoksit (DMSO), polar ve polar olmayan bile\u015fikleri \u00e7\u00f6zme yetene\u011fine sahip, renksiz bir s\u0131v\u0131d\u0131r. 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