{"id":740,"date":"2023-07-21T13:23:38","date_gmt":"2023-07-21T13:23:38","guid":{"rendered":"https:\/\/chemuza.org\/tr\/potasyum-tiyosulfat-k2s2o3\/"},"modified":"2023-07-21T13:23:38","modified_gmt":"2023-07-21T13:23:38","slug":"potasyum-tiyosulfat-k2s2o3","status":"publish","type":"post","link":"https:\/\/chemuza.org\/tr\/potasyum-tiyosulfat-k2s2o3\/","title":{"rendered":"Potasyum tiyos\u00fclfat \u2013 k2s2o3, 10294-66-3"},"content":{"rendered":"

Potasyum tiyos\u00fclfat (K2S2O3), foto\u011fraf\u00e7\u0131l\u0131kta indirgeyici madde olarak ve y\u00fczme havuzlar\u0131nda kloru n\u00f6tralize etmek i\u00e7in kullan\u0131lan kimyasal bir bile\u015fiktir. Beyaz kristal bir g\u00f6r\u00fcn\u00fcme sahiptir ve suda \u00e7\u00f6z\u00fcn\u00fcr.<\/p>\n

\n\n\n\n\n\n\n\n
IUPAC Ad\u0131<\/td>\n Potasyum tiyos\u00fclfat<\/td>\n<\/tr>\n
Molek\u00fcler form\u00fcl<\/td>\n K2S2O3<\/td>\n<\/tr>\n
CAS numaras\u0131<\/td>\n 10294-66-3<\/td>\n<\/tr>\n
E\u015f anlaml\u0131<\/td>\n Potasyum hipos\u00fclfit, potasyum tiyos\u00fclfat, potasyum tiyos\u00fclfat pentahidrat, potasyum tiyos\u00fclfat pentahidrat, potasyum s\u00fclf\u00fcrotiyoat, potasyum s\u00fclf\u00fcrotiyoik asit<\/td>\n<\/tr>\n
InChI<\/td>\n InChI=1S\/2K.H2O3S2\/c;;1-4(2)3\/h;;(H2,1,2,3)\/q2*+1;\/p-2<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n

Potasyum tiyos\u00fclfat\u0131n \u00f6zellikleri<\/strong><\/h2>\n

Potasyum Tiyos\u00fclfat Form\u00fcl\u00fc<\/h3>\n

Potasyum tiyos\u00fclfat\u0131n (K2S2O3) kimyasal form\u00fcl\u00fc, bile\u015fikte bulunan atomlar\u0131n say\u0131s\u0131n\u0131 ve t\u00fcr\u00fcn\u00fc g\u00f6sterir. Form\u00fcl iki potasyum atomu, iki k\u00fck\u00fcrt atomu ve \u00fc\u00e7 oksijen atomundan olu\u015fur. Potasyum atomlar\u0131 pozitif y\u00fcke sahipken, k\u00fck\u00fcrt ve oksijen atomlar\u0131 negatif y\u00fcke sahiptir.<\/p>\n

Potasyum Tiyos\u00fclfat Molar K\u00fctlesi<\/h3>\n

K2S2O3’\u00fcn molar k\u00fctlesi 190,33 g\/mol’d\u00fcr. Molar k\u00fctle, bir maddenin bir mol\u00fcn\u00fcn k\u00fctlesidir ve kimyasal form\u00fcldeki t\u00fcm atomlar\u0131n atomik k\u00fctlelerinin eklenmesiyle hesaplan\u0131r. K2S2O3 durumunda form\u00fcl iki potasyum atomu, iki k\u00fck\u00fcrt atomu ve \u00fc\u00e7 oksijen atomundan olu\u015fur.<\/p>\n

Potasyum tiyos\u00fclfat\u0131n kaynama noktas\u0131<\/h3>\n

K2S2O3 kaynama noktas\u0131na ula\u015fmadan ayr\u0131\u015ft\u0131\u011f\u0131 i\u00e7in kaynama noktas\u0131 yoktur. S\u0131cakl\u0131k yakla\u015f\u0131k 100\u00b0C’ye ula\u015ft\u0131\u011f\u0131nda ve k\u00fck\u00fcrt dioksit a\u00e7\u0131\u011fa \u00e7\u0131kt\u0131\u011f\u0131nda ayr\u0131\u015fma meydana gelir. Bu nedenle bile\u015fik genellikle y\u00fcksek s\u0131cakl\u0131k uygulamalar\u0131nda kullan\u0131lmaz.<\/p>\n

Potasyum Tiyos\u00fclfat Erime Noktas\u0131<\/h3>\n

K2S2O3’\u00fcn erime noktas\u0131 48,3\u00b0C’dir. Bu s\u0131cakl\u0131k di\u011fer kimyasal bile\u015fiklerle kar\u015f\u0131la\u015ft\u0131r\u0131ld\u0131\u011f\u0131nda nispeten d\u00fc\u015f\u00fckt\u00fcr. Bu s\u0131cakl\u0131\u011fa \u0131s\u0131t\u0131ld\u0131\u011f\u0131nda kat\u0131 K2S2O3 s\u0131v\u0131 hale gelecektir.<\/p>\n

Potasyum tiyos\u00fclfat\u0131n yo\u011funlu\u011fu g\/mL<\/h3>\n

K2S2O3’\u00fcn yo\u011funlu\u011fu 1,667 g\/mL’dir. Yo\u011funluk, belirli bir hacimde bulunan k\u00fctle miktar\u0131n\u0131n bir \u00f6l\u00e7\u00fcs\u00fcd\u00fcr. Bu de\u011fer, bir mililitre K2S2O3’\u00fcn k\u00fctlesinin 1.667 gram oldu\u011fu anlam\u0131na gelir.<\/p>\n

Potasyum Tiyos\u00fclfat Molek\u00fcl A\u011f\u0131rl\u0131\u011f\u0131<\/h3>\n

K2S2O3’\u00fcn molek\u00fcler a\u011f\u0131rl\u0131\u011f\u0131 190,33 g\/mol’d\u00fcr. Molek\u00fcl a\u011f\u0131rl\u0131\u011f\u0131, bile\u015fikteki t\u00fcm atomlar\u0131n atom a\u011f\u0131rl\u0131klar\u0131n\u0131n toplam\u0131d\u0131r. Genellikle bir maddenin molleri ve gramlar\u0131 aras\u0131nda d\u00f6n\u00fc\u015f\u00fcm yapmak i\u00e7in kullan\u0131l\u0131r.<\/p>\n

Potasyum tiyos\u00fclfat\u0131n yap\u0131s\u0131 <\/h3>\n
\n
\"Potasyum<\/figure>\n<\/div>\n

K2S2O3’\u00fcn yap\u0131s\u0131 iki potasyum atomu, iki k\u00fck\u00fcrt atomu ve \u00fc\u00e7 oksijen atomundan olu\u015fur. K\u00fck\u00fcrt atomlar\u0131 birbirine \u00e7ift ba\u011fla ba\u011flan\u0131rken, di\u011fer k\u00fck\u00fcrt atomu oksijen atomlar\u0131ndan birine ba\u011flan\u0131r. Potasyum atomlar\u0131 geri kalan oksijen atomlar\u0131na ba\u011flan\u0131r.<\/p>\n

Potasyum tiyos\u00fclfat\u0131n \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011f\u00fc<\/h3>\n

K2S2O3, 20\u00b0C’de 432 g\/L \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011f\u00fcyle suda olduk\u00e7a \u00e7\u00f6z\u00fcn\u00fcr. Bu onu su ar\u0131t\u0131m\u0131nda ve fotografik sabitleme maddesi olarak etkili bir bile\u015fik haline getirir. Ancak etanol veya aseton gibi organik \u00e7\u00f6z\u00fcc\u00fclerde \u00e7\u00f6z\u00fcnmez.<\/p>\n

\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n
D\u0131\u015f g\u00f6r\u00fcn\u00fc\u015f<\/td>\n Beyaz kristal kat\u0131<\/td>\n<\/tr>\n
Spesifik yer \u00e7ekimi<\/td>\n 1.667<\/td>\n<\/tr>\n
Renk<\/td>\n Renksizden beyaza<\/td>\n<\/tr>\n
Koku<\/td>\n Kokusuz<\/td>\n<\/tr>\n
Molar k\u00fctle<\/td>\n 190,33 gr\/mol<\/td>\n<\/tr>\n
Yo\u011funluk<\/td>\n 1.667 g\/mL<\/td>\n<\/tr>\n
F\u00fczyon noktas\u0131<\/td>\n 48,3\u00b0C<\/td>\n<\/tr>\n
Kaynama noktas\u0131<\/td>\n Kaynamadan \u00f6nce par\u00e7alan\u0131r<\/td>\n<\/tr>\n
Fla\u015f noktas\u0131<\/td>\n Uygulanamaz<\/td>\n<\/tr>\n
sudaki \u00e7\u00f6z\u00fcn\u00fcrl\u00fck<\/td>\n \u00c7ok \u00e7\u00f6z\u00fcn\u00fcr (20\u00b0C’de 432 g\/L)<\/td>\n<\/tr>\n
\u00e7\u00f6z\u00fcn\u00fcrl\u00fck<\/td>\n Organik \u00e7\u00f6z\u00fcc\u00fclerde \u00e7\u00f6z\u00fcnmez<\/td>\n<\/tr>\n
Buhar bas\u0131nc\u0131<\/td>\n Uygulanamaz<\/td>\n<\/tr>\n
Buhar yo\u011funlu\u011fu<\/td>\n Uygulanamaz<\/td>\n<\/tr>\n
pKa<\/td>\n Uygulanamaz<\/td>\n<\/tr>\n
pH<\/td>\n 6,0 \u2013 9,0 (%5 sulu \u00e7\u00f6zelti)<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n

Potasyum tiyos\u00fclfat\u0131n g\u00fcvenli\u011fi ve tehlikeleri<\/strong><\/h2>\n

Uygun \u00f6nlemler al\u0131nd\u0131\u011f\u0131nda K2S2O3’\u00fcn ta\u015f\u0131nmas\u0131 ve kullan\u0131lmas\u0131 genellikle g\u00fcvenli kabul edilir. Ancak bu bile\u015fikle ilgili baz\u0131 potansiyel tehlikelerin fark\u0131nda olmak \u00f6nemlidir. K2S2O3 tozuna veya buhar\u0131na maruz kalmak g\u00f6zlerde, ciltte ve solunum sisteminde tahri\u015fe neden olabilir. Bile\u015fi\u011fin yutulmas\u0131 ayr\u0131ca bulant\u0131, kusma ve ishale neden olabilir. Ek olarak bile\u015fikle temas, baz\u0131 ki\u015filerde dermatite veya cilt hassasiyetine neden olabilir. Herhangi bir kimyasalda oldu\u011fu gibi, K2S2O3 ile \u00e7al\u0131\u015f\u0131rken maruz kalman\u0131n \u00f6nlenmesi ve kaza riskinin azalt\u0131lmas\u0131 i\u00e7in uygun g\u00fcvenlik protokollerinin takip edilmesi \u00f6nemlidir.<\/p>\n

\n\n\n\n\n\n\n\n\n\n
Tehlike sembolleri<\/td>\n XI<\/td>\n<\/tr>\n
G\u00fcvenlik A\u00e7\u0131klamas\u0131<\/td>\n S22 \u2013 Tozu solumay\u0131n. S24\/25 \u2013 Cilt ve g\u00f6zlerle temas\u0131ndan ka\u00e7\u0131n\u0131n. S37\/39 \u2013 Uygun eldiven ve g\u00f6z\/y\u00fcz korumas\u0131 kullan\u0131n.<\/td>\n<\/tr>\n
BM kimlik numaralar\u0131<\/td>\n BM 3077<\/td>\n<\/tr>\n
HS kodu<\/td>\n 2832.10.00<\/td>\n<\/tr>\n
Tehlike s\u0131n\u0131f\u0131<\/td>\n 9 \u2013 \u00c7e\u015fitli tehlikeli maddeler<\/td>\n<\/tr>\n
Paketleme grubu<\/td>\n III<\/td>\n<\/tr>\n
Toksisite<\/td>\n LD50 (oral, s\u0131\u00e7an): 2.500 mg\/kg<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n

Potasyum tiyos\u00fclfat\u0131n sentezi i\u00e7in y\u00f6ntemler<\/strong><\/h2>\n

K2S2O3, bir alkali metal hidroksit varl\u0131\u011f\u0131nda k\u00fck\u00fcrt\u00fcn potasyum s\u00fclfit ile reaksiyonu dahil olmak \u00fczere \u00e7e\u015fitli y\u00f6ntemlerle sentezlenebilir.<\/p>\n

Ba\u015fka bir y\u00f6ntem, potasyum hidroksitin<\/a> k\u00fck\u00fcrt ve k\u00fck\u00fcrt dioksit gaz\u0131 ile reaksiyonunu i\u00e7erir. Bu reaksiyon, yan \u00fcr\u00fcnler olarak K2S2O3 ve potasyum s\u00fclfat<\/a> \u00fcretir.<\/p>\n

Alternatif bir sentez y\u00f6ntemi, potasyum s\u00fclfitin sulu bir \u00e7\u00f6zelti i\u00e7inde sodyum tiyos\u00fclfat<\/a> ile reaksiyonunu i\u00e7erir. Ortaya \u00e7\u0131kan \u00e7\u00f6kelti filtrelenebilir ve saf K2S2O3 elde etmek i\u00e7in y\u0131kanabilir.<\/p>\n

Laboratuvarda K2S2O3 haz\u0131rlamak i\u00e7in potasyum hidroksit<\/a> k\u00fck\u00fcrt ile reaksiyona sokulabilir, ard\u0131ndan kar\u0131\u015f\u0131ma k\u00fck\u00fcrt dioksit gaz\u0131 eklenebilir. Ortaya \u00e7\u0131kan \u00fcr\u00fcn, yeniden kristalle\u015ftirme yoluyla daha da safla\u015ft\u0131r\u0131labilen beyaz kristalli bir kat\u0131d\u0131r.<\/p>\n

Potasyum Tiyos\u00fclfat\u0131n Kullan\u0131m Alanlar\u0131<\/strong><\/h2>\n

K2S2O3’\u00fcn \u00e7e\u015fitli end\u00fcstrilerde bir\u00e7ok \u00f6nemli kullan\u0131m\u0131 vard\u0131r. \u0130\u015fte en yayg\u0131n uygulamalar\u0131ndan baz\u0131lar\u0131:<\/p>\n

    \n
  1. Foto\u011fraf\u00e7\u0131l\u0131k: Potasyum tiyos\u00fclfat, foto\u011fraf i\u015flemede kullan\u0131lmayan g\u00fcm\u00fc\u015f halojen\u00fcrleri \u00e7\u0131karmak ve g\u00f6r\u00fcnt\u00fc solmas\u0131n\u0131 \u00f6nlemek i\u00e7in sabitleme maddesi olarak kullan\u0131l\u0131r.<\/li>\n
  2. Tar\u0131m: Potasyum tiyos\u00fclfat, bitkilere b\u00fcy\u00fcme ve geli\u015fme i\u00e7in \u00f6nemli besin maddeleri olan k\u00fck\u00fcrt ve potasyum sa\u011flamak amac\u0131yla g\u00fcbre olarak kullan\u0131l\u0131r.<\/li>\n
  3. Su Ar\u0131tma: Potasyum tiyos\u00fclfat, y\u00fczme havuzu ve spa suyundan klorun uzakla\u015ft\u0131r\u0131lmas\u0131n\u0131n yan\u0131 s\u0131ra end\u00fcstriyel at\u0131k su ar\u0131t\u0131m\u0131nda klorun etkilerini n\u00f6tralize etmek i\u00e7in kullan\u0131l\u0131r.<\/li>\n
  4. Analitik Kimya: Potasyum tiyos\u00fclfat, analitik kimyada iyot ve di\u011fer oksitleyici maddelerin konsantrasyonunu belirlemek i\u00e7in indirgeyici bir madde olarak kullan\u0131l\u0131r.<\/li>\n
  5. T\u0131bbi Tedaviler: Potasyum tiyos\u00fclfat, siyan\u00fcr zehirlenmesinin tedavisi gibi baz\u0131 t\u0131bbi tedavilerde kullan\u0131lm\u0131\u015ft\u0131r.<\/li>\n
  6. End\u00fcstriyel Uygulamalar: Potasyum tiyos\u00fclfat, elektrokaplama, deri tabaklama ve ya\u011f \u00e7\u0131karma gibi \u00e7e\u015fitli end\u00fcstriyel uygulamalarda kullan\u0131l\u0131r.<\/li>\n<\/ol>\n

    Sorular:<\/strong><\/h2>\n

    S: Bir \u015feyin potasyum tiyos\u00fclfat indirgeyici madde olup olmad\u0131\u011f\u0131n\u0131 nas\u0131l belirlersiniz?<\/h3>\n

    C: K2S2O3 bir indirgeyici maddedir \u00e7\u00fcnk\u00fc di\u011fer molek\u00fcllere veya iyonlara elektron ba\u011f\u0131\u015flayarak oksidasyon durumlar\u0131n\u0131 azaltma yetene\u011fine sahiptir.<\/p>\n

    S: Potasyum tiyos\u00fclfat\u0131 indirgeyici madde yapan nedir?<\/h3>\n

    C: K2S2O3, s\u00fclfattan daha d\u00fc\u015f\u00fck oksidasyon durumuna sahip bir k\u00fck\u00fcrt atomuna sahiptir, bu da di\u011fer molek\u00fcllere veya iyonlara elektron ba\u011f\u0131\u015flamas\u0131na ve indirgeyici madde olarak g\u00f6rev yapmas\u0131na olanak tan\u0131r.<\/p>\n

    S: Potasyum tiyos\u00fclfat ye\u015fil sebzeleri yakar m\u0131?<\/h3>\n

    C: Hay\u0131r, K2S2O3 ye\u015fillikleri yakmaz. Beyaz kristal bir kat\u0131d\u0131r ve ye\u015fil renk g\u00f6stermez.<\/p>\n

    S: AgCl’nin 1,0 M K2S2O3’teki molar \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011f\u00fc nedir?<\/h3>\n

    C: AgCl’nin 1,0 M K2S2O3 i\u00e7indeki molar \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011f\u00fc s\u0131cakl\u0131k ve iyon kuvveti gibi \u00e7e\u015fitli fakt\u00f6rlere ba\u011fl\u0131d\u0131r. Ek bilgi olmadan kesin bir de\u011fer belirlenemez.<\/p>\n

    S: 2’deki (K2S2O3) K’nin y\u00fck veya y\u00fckseltgenme say\u0131s\u0131 nedir?<\/h3>\n

    C: 2’deki (K2S2O3) K’nin y\u00fck veya y\u00fckseltgenme say\u0131s\u0131 +1’dir.<\/p>\n

    S: K2S2O3’teki S’nin oksidasyon durumu nedir?<\/h3>\n

    C: S’nin K2S2O3’teki oksidasyon durumu +2’dir.<\/p>\n

    Soru: 4 mol K2S2O3’te ka\u00e7 molek\u00fcl vard\u0131r?<\/h3>\n

    C: 4 mol K2S2O3’te yakla\u015f\u0131k 4 x 6,022 x 10^23 molek\u00fcl K2S2O3 bulunur, bu da 2,409 x 10^24 molek\u00fcle e\u015fde\u011ferdir.<\/p>\n

    Soru: 4 mol K2S2O3 ne kadard\u0131r?<\/h3>\n

    C: 4 mol K2S2O3’\u00fcn k\u00fctlesi, K2S2O3’\u00fcn (190,31 g\/mol) molar k\u00fctlesinin 4 ile \u00e7arp\u0131lmas\u0131yla hesaplanabilir, bu da 761,24 grama e\u015fittir. Dolay\u0131s\u0131yla 4 mol K2S2O3 761,24 grama e\u015fittir.<\/p>\n","protected":false},"excerpt":{"rendered":"

    Potasyum tiyos\u00fclfat (K2S2O3), foto\u011fraf\u00e7\u0131l\u0131kta indirgeyici madde olarak ve y\u00fczme havuzlar\u0131nda kloru n\u00f6tralize etmek i\u00e7in kullan\u0131lan kimyasal bir bile\u015fiktir. Beyaz kristal bir g\u00f6r\u00fcn\u00fcme sahiptir ve suda \u00e7\u00f6z\u00fcn\u00fcr. IUPAC Ad\u0131 Potasyum tiyos\u00fclfat Molek\u00fcler form\u00fcl K2S2O3 CAS numaras\u0131 10294-66-3 E\u015f anlaml\u0131 Potasyum hipos\u00fclfit, potasyum tiyos\u00fclfat, potasyum tiyos\u00fclfat pentahidrat, potasyum tiyos\u00fclfat pentahidrat, potasyum s\u00fclf\u00fcrotiyoat, potasyum s\u00fclf\u00fcrotiyoik asit InChI InChI=1S\/2K.H2O3S2\/c;;1-4(2)3\/h;;(H2,1,2,3)\/q2*+1;\/p-2 … Devam\u0131n\u0131 oku<\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[5],"tags":[],"yoast_head":"\nPotasyum tiyos\u00fclfat - K2S2O3, 10294-66-3<\/title>\n<meta name=\"description\" content=\"Potasyum tiyos\u00fclfat (K2S2O3), foto\u011fraf\u00e7\u0131l\u0131kta indirgeyici bir madde olarak ve y\u00fczmede kloru n\u00f6tralize etmek i\u00e7in kullan\u0131lan kimyasal bir bile\u015fiktir.\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/chemuza.org\/tr\/potasyum-tiyosulfat-k2s2o3\/\" \/>\n<meta property=\"og:locale\" content=\"tr_TR\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Potasyum tiyos\u00fclfat - 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