{"id":732,"date":"2023-07-21T14:33:23","date_gmt":"2023-07-21T14:33:23","guid":{"rendered":"https:\/\/chemuza.org\/tr\/kalsiyum-nitrit-cano22\/"},"modified":"2023-07-21T14:33:23","modified_gmt":"2023-07-21T14:33:23","slug":"kalsiyum-nitrit-cano22","status":"publish","type":"post","link":"https:\/\/chemuza.org\/tr\/kalsiyum-nitrit-cano22\/","title":{"rendered":"Kalsiyum nitrit \u2013 ca(no2)2, 13780-06-8"},"content":{"rendered":"

Kalsiyum nitrit (Ca(NO2)2), betonda korozyon \u00f6nleyici olarak yayg\u0131n olarak kullan\u0131lan kimyasal bir bile\u015fiktir. \u00c7elik donat\u0131lar\u0131n korozyonunu \u00f6nlemeye yard\u0131mc\u0131 olur.<\/p>\n

\n\n\n\n\n\n\n\n
IUPAC’\u0131n ad\u0131<\/td>\n Kalsiyum dinitrit<\/td>\n<\/tr>\n
Molek\u00fcler form\u00fcl<\/td>\n Ca(NO2)2<\/td>\n<\/tr>\n
CAS numaras\u0131<\/td>\n 13780-06-8<\/td>\n<\/tr>\n
E\u015f anlaml\u0131<\/td>\n Kalsiyum nitrit dihidrat, nitr\u00f6z asit, kalsiyum tuzu, nitrik asit, kalsiyum tuzu, dihidrat vb.<\/td>\n<\/tr>\n
InChI<\/td>\n InChI=1S\/Ca.2HNO2\/c;2 2-1-3\/h;2<\/em> (H,2,3)<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n

Kalsiyum nitritin \u00f6zellikleri<\/strong><\/h2>\n

Kalsiyum nitrit form\u00fcl\u00fc<\/h3>\n

Kalsiyum nitritin kimyasal form\u00fcl\u00fc Ca(NO2)2’dir. Bu form\u00fcl, bile\u015fi\u011fin her kalsiyum katyonu i\u00e7in iki nitrit anyonu i\u00e7erdi\u011fini g\u00f6sterir. Form\u00fcl, bile\u015fi\u011fin bile\u015fiminin belirlenmesinde ve bile\u015fikteki her bir elementin miktar\u0131n\u0131n belirlenmesinde \u00f6nemlidir.<\/p>\n

Kalsiyum Nitrit Molar K\u00fctle<\/h3>\n

Kalsiyum dinitrit olarak da bilinen Ca(NO2)2’nin molar k\u00fctlesi yakla\u015f\u0131k 132,09 g\/mol’d\u00fcr. Kalsiyum katyonlar\u0131 ve nitrit anyonlar\u0131ndan olu\u015fan iyonik bir bile\u015fiktir. Molar k\u00fctle, bile\u015fi\u011fi olu\u015fturan elementlerin (bu durumda kalsiyum, nitrojen ve oksijendir) atomik k\u00fctlelerinin eklenmesiyle hesaplan\u0131r.<\/p>\n

Kalsiyum nitritin kaynama noktas\u0131<\/h3>\n

Ca(NO2)2’nin kaynama noktas\u0131 yakla\u015f\u0131k 400\u00b0C’dir (752\u00b0F). Bu y\u00fcksek kaynama noktas\u0131, bile\u015fikteki Ca2+ ve NO2- iyonlar\u0131 aras\u0131nda bulunan g\u00fc\u00e7l\u00fc iyonik ba\u011flardan kaynaklanmaktad\u0131r. Ca(NO2)2 \u0131s\u0131t\u0131ld\u0131\u011f\u0131nda termal bozunmaya u\u011frar ve nitrojen dioksit ve oksijen a\u00e7\u0131\u011fa \u00e7\u0131kar.<\/p>\n

Kalsiyum nitrit Erime noktas\u0131<\/h3>\n

Ca(NO2)2’nin erime noktas\u0131 yakla\u015f\u0131k 132\u00b0C’dir (270\u00b0F). Bu erime noktas\u0131, erime noktas\u0131 801\u00b0C (1,474\u00b0F) olan sodyum klor\u00fcr gibi di\u011fer iyonik bile\u015fiklerle kar\u015f\u0131la\u015ft\u0131r\u0131ld\u0131\u011f\u0131nda nispeten d\u00fc\u015f\u00fckt\u00fcr. Ca(NO2)2’nin d\u00fc\u015f\u00fck erime noktas\u0131, Ca2+ ve NO2- iyonlar\u0131 aras\u0131nda bulunan nispeten zay\u0131f iyonik ba\u011flara ba\u011flanabilir.<\/p>\n

Kalsiyum nitritin yo\u011funlu\u011fu g\/mL<\/h3>\n

Ca(NO2)2’nin yo\u011funlu\u011fu yakla\u015f\u0131k 2,32 g\/mL’dir. Bu de\u011fer Ca(NO2)2’nin nispeten yo\u011fun bir bile\u015fik oldu\u011funu g\u00f6sterir. Yo\u011funluk, bile\u015fi\u011fin k\u00fctlesinin hacmine b\u00f6l\u00fcnmesiyle hesaplan\u0131r. Ca(NO2)2’nin y\u00fcksek yo\u011funlu\u011fu nispeten a\u011f\u0131r kalsiyum katyonlar\u0131n\u0131n varl\u0131\u011f\u0131na ba\u011flanabilir.<\/p>\n

Kalsiyum Nitrit Molek\u00fcl A\u011f\u0131rl\u0131\u011f\u0131<\/h3>\n

Ca(NO2)2’nin molek\u00fcler a\u011f\u0131rl\u0131\u011f\u0131 yakla\u015f\u0131k 132,09 g\/mol’d\u00fcr. Bu de\u011fer, bile\u015fi\u011fi olu\u015fturan elementlerin atom a\u011f\u0131rl\u0131klar\u0131n\u0131n eklenmesiyle hesaplan\u0131r. Molek\u00fcl a\u011f\u0131rl\u0131\u011f\u0131, bile\u015fi\u011fin belirli say\u0131da mol\u00fcn\u00fc elde etmek i\u00e7in gereken Ca(NO2)2 miktar\u0131n\u0131n belirlenmesinde \u00f6nemlidir. <\/p>\n

\n
\"Kalsiyum<\/figure>\n<\/div>\n

Kalsiyum nitritin yap\u0131s\u0131<\/h3>\n

Ca(NO2)2’nin yap\u0131s\u0131 Ca2+ ve NO2-‘den olu\u015fur. Ca2+ iyonlar\u0131 kristal kafesin merkezinde bulunurken, NO2- iyonlar\u0131 onlar\u0131 \u00e7evreler. Kristal kafes, Ca2+ ve NO2- iyonlar\u0131 aras\u0131ndaki g\u00fc\u00e7l\u00fc iyonik ba\u011flarla bir arada tutulur.<\/p>\n

Kalsiyum nitritin \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011f\u00fc<\/h3>\n

Ca(NO2)2 su ve alkolde \u00e7\u00f6z\u00fcn\u00fcr. Suda \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011f\u00fc nispeten y\u00fcksektir; oda s\u0131cakl\u0131\u011f\u0131nda yakla\u015f\u0131k 61 g\/100 ml su \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011f\u00fc vard\u0131r. Alkoldeki \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011f\u00fc sudakinden daha d\u00fc\u015f\u00fckt\u00fcr. Ca(NO2)2’nin \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011f\u00fc, beton \u00fcretimi gibi \u00e7e\u015fitli uygulamalardaki kullan\u0131m\u0131n\u0131n belirlenmesinde \u00f6nemlidir.<\/p>\n

\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n
D\u0131\u015f g\u00f6r\u00fcn\u00fc\u015f<\/td>\n Beyaz ila hafif sar\u0131 kristal toz veya kat\u0131<\/td>\n<\/tr>\n
Spesifik yer \u00e7ekimi<\/td>\n 2.32<\/td>\n<\/tr>\n
Renk<\/td>\n Renksizden beyaza<\/td>\n<\/tr>\n
Koku<\/td>\n Kokusuz<\/td>\n<\/tr>\n
Molar k\u00fctle<\/td>\n 132,09 gr\/mol<\/td>\n<\/tr>\n
Yo\u011funluk<\/td>\n 2,32 gr\/ml<\/td>\n<\/tr>\n
F\u00fczyon noktas\u0131<\/td>\n 132\u00b0C (270\u00b0F)<\/td>\n<\/tr>\n
Kaynama noktas\u0131<\/td>\n Yakla\u015f\u0131k 400\u00b0C’de (752\u00b0F) ayr\u0131\u015f\u0131r<\/td>\n<\/tr>\n
Fla\u015f noktas\u0131<\/td>\n Uygulanamaz<\/td>\n<\/tr>\n
sudaki \u00e7\u00f6z\u00fcn\u00fcrl\u00fck<\/td>\n \u00c7\u00f6z\u00fcn\u00fcr<\/td>\n<\/tr>\n
\u00e7\u00f6z\u00fcn\u00fcrl\u00fck<\/td>\n Su ve alkolde \u00e7\u00f6z\u00fcn\u00fcr<\/td>\n<\/tr>\n
Buhar bas\u0131nc\u0131<\/td>\n Uygulanamaz<\/td>\n<\/tr>\n
Buhar yo\u011funlu\u011fu<\/td>\n Uygulanamaz<\/td>\n<\/tr>\n
pKa<\/td>\n Uygulanamaz<\/td>\n<\/tr>\n
pH<\/td>\n Do\u011fal<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n

Kalsiyum Nitritin G\u00fcvenli\u011fi ve Tehlikeleri<\/strong><\/h2>\n

Ca(NO2)2 yutulmas\u0131, solunmas\u0131 veya cilt veya g\u00f6zlerle temas\u0131 halinde zararl\u0131 olabilir. Bu tahri\u015fe, yan\u0131klara ve solunum problemlerine neden olabilir. Bile\u015fik ayn\u0131 zamanda bir oksitleyici maddedir ve asitler ve metaller gibi di\u011fer kimyasallarla reaksiyona girerek tehlikeli maddeler olu\u015fturabilir. Ca(NO2)2 serin, kuru ve iyi havaland\u0131r\u0131lm\u0131\u015f bir alanda, uyumsuz malzemelerden uzakta saklanmal\u0131d\u0131r. Bile\u015fik kullan\u0131l\u0131rken eldiven ve g\u00f6zl\u00fck gibi ki\u015fisel koruyucu ekipmanlar giyilmelidir. Maruz kal\u0131nmas\u0131 durumunda derhal t\u0131bbi yard\u0131ma ba\u015fvurulmal\u0131 ve kirlenmi\u015f giysiler \u00e7\u0131kar\u0131lmal\u0131d\u0131r.<\/p>\n

\n\n\n\n\n\n\n\n\n\n
Tehlike sembolleri<\/td>\n Xn<\/td>\n<\/tr>\n
G\u00fcvenlik A\u00e7\u0131klamas\u0131<\/td>\n Cilt ve g\u00f6zlerle temas\u0131ndan ka\u00e7\u0131n\u0131n; ki\u015fisel koruyucu ekipman (KKD) kullan\u0131n; Maruz kalma durumunda derhal t\u0131bbi yard\u0131ma ba\u015fvurun.<\/td>\n<\/tr>\n
BM kimlik numaralar\u0131<\/td>\n BM 1454<\/td>\n<\/tr>\n
HS kodu<\/td>\n 2834.29.90<\/td>\n<\/tr>\n
Tehlike s\u0131n\u0131f\u0131<\/td>\n 5.1<\/td>\n<\/tr>\n
Paketleme grubu<\/td>\n III<\/td>\n<\/tr>\n
Toksisite<\/td>\n Yutulmas\u0131 veya solunmas\u0131 halinde zararl\u0131d\u0131r; tahri\u015fe, yan\u0131klara ve solunum problemlerine neden olabilir<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n

Kalsiyum nitrit sentez y\u00f6ntemleri<\/strong><\/h2>\n

Nitrik asit<\/a> veya nitrojen oksitlerin kalsiyum karbonat<\/a> ile reaksiyonu, nitr\u00f6z asit veya nitrojen oksitlerin karbon hidroksit ile reaksiyonu dahil olmak \u00fczere Ca(NO2)2’yi \u00e7e\u015fitli y\u00f6ntemler sentezleyebilir. kalsiyum ve kalsiyum hidroksit<\/a> veya amonyum hidroksitin kalsiyum nitratla reaksiyonu.<\/p>\n

Yayg\u0131n bir y\u00f6ntem, kalsiyum nitrat \u00fcretmek i\u00e7in kalsiyum karbonat\u0131n<\/a> nitrik asitle<\/a> reaksiyona sokulmas\u0131d\u0131r. Daha sonra kalsiyum nitrat\u0131n kalsiyum hidroksit<\/a> ile reaksiyonu Ca(NO2)2 ve kalsiyum oksit yan \u00fcr\u00fcnlerinin olu\u015fumuyla sonu\u00e7lan\u0131r.<\/p>\n

Di\u011fer bir y\u00f6ntem ise nitrojen oksitlerin kalsiyum hidroksit<\/a> ile reaksiyona girerek Ca(NO2)2 ve kalsiyum nitrat \u00fcretmesini i\u00e7erir.<\/p>\n

Ba\u015fka bir y\u00f6ntemde, kalsiyum nitrat\u0131 kalsiyum hidroksit<\/a> veya amonyum hidroksit ile reaksiyona sokarak Ca(NO2)2 \u00fcretebilir ve bir yandan da yan \u00fcr\u00fcn olarak kalsiyum nitrat \u00fcretebilirsiniz.<\/p>\n

Kalsiyum Nitritin Kullan\u0131m Alanlar\u0131<\/strong><\/h2>\n

Ca(NO2)2’nin farkl\u0131 end\u00fcstrilerde \u00e7e\u015fitli uygulamalar\u0131 vard\u0131r:<\/p>\n

    \n
  1. Beton Sanayi: Beton yap\u0131lar\u0131n dayan\u0131kl\u0131l\u0131\u011f\u0131n\u0131 ve mukavemetini artt\u0131rmak amac\u0131yla betona katk\u0131 maddesi olarak kullan\u0131l\u0131r. Donat\u0131 \u00e7eli\u011fini klor\u00fcrlerin ve di\u011fer agresif iyonlar\u0131n neden oldu\u011fu korozyondan koruyan bir korozyon \u00f6nleyici g\u00f6revi g\u00f6r\u00fcr.<\/li>\n
  2. Tar\u0131m: Bitkilere azot ve kalsiyum kayna\u011f\u0131 sa\u011flamak amac\u0131yla tar\u0131mda g\u00fcbre olarak kullan\u0131l\u0131r. Ayr\u0131ca toprak kalitesini iyile\u015ftirmek ve bitki b\u00fcy\u00fcmesini te\u015fvik etmek i\u00e7in toprak d\u00fczenleyici olarak da kullan\u0131l\u0131r.<\/li>\n
  3. Kimya end\u00fcstrisi: Kimyasal reaksiyonlarda indirgeyici madde olarak ve ayr\u0131ca kalsiyum nitrat ve kalsiyum amonyum nitrat gibi di\u011fer kimyasallar\u0131n sentezinde \u00f6nc\u00fc olarak kullan\u0131l\u0131r.<\/li>\n
  4. At\u0131k Su Ar\u0131tma: Kirletici maddeleri uzakla\u015ft\u0131rmak ve sudaki zararl\u0131 maddelerin konsantrasyonunu azaltmak i\u00e7in at\u0131k su ar\u0131tma kimyasal\u0131 olarak kullan\u0131l\u0131r.<\/li>\n
  5. G\u0131da end\u00fcstrisi: Et, bal\u0131k ve di\u011fer g\u0131da \u00fcr\u00fcnlerinde bakteri ve di\u011fer mikroorganizmalar\u0131n b\u00fcy\u00fcmesini \u00f6nlemek amac\u0131yla g\u0131da koruyucu olarak kullan\u0131l\u0131r.<\/li>\n<\/ol>\n

    Sorular:<\/strong><\/h2>\n

    S: Kalsiyum nitritin form\u00fcl\u00fc nedir?<\/h3>\n

    C: Kalsiyum nitritin kimyasal form\u00fcl\u00fc Ca(NO2)2’dir.<\/p>\n

    S: Betonda her y\u0131l ne kadar kalsiyum nitrit kullan\u0131l\u0131yor?<\/h3>\n

    C: Her y\u0131l betonda kullan\u0131lan Ca(NO2)2 miktar\u0131, spesifik uygulamaya ve pazar talebine ba\u011fl\u0131 olarak de\u011fi\u015fir. Ancak d\u00fcnya \u00e7ap\u0131nda her y\u0131l birka\u00e7 bin ton Ca(NO2)2’nin beton katk\u0131 maddesi olarak kullan\u0131ld\u0131\u011f\u0131 tahmin edilmektedir.<\/p>\n

    Soru: Kalsiyum nitrit suda \u00e7\u00f6z\u00fcn\u00fcr m\u00fc?<\/h3>\n

    C: Evet, Ca(NO2)2 suda \u00e7\u00f6z\u00fcn\u00fcr. 20\u00b0C’de yakla\u015f\u0131k 167 g\/L \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011fe sahiptir.<\/p>\n

    S: Kalsiyum nitrit bir tuz mudur?<\/h3>\n

    C: Evet, Ca(NO2)2 tuzdur. Kalsiyum katyonlar\u0131 (Ca2+) ve nitrit anyonlar\u0131ndan (NO2-) olu\u015fan iyonik bir bile\u015fik.<\/p>\n

    S: A\u015fa\u011f\u0131daki \u00e7\u00f6z\u00fcmler nas\u0131l haz\u0131rlan\u0131r? 1,25 l 0,775 m Ca(NO2)2 \u00e7\u00f6zeltisi<\/h3>\n

    C: 1,25 L’lik 0,775 M’lik Ca(NO2)2 \u00e7\u00f6zeltisi haz\u0131rlamak i\u00e7in, yakla\u015f\u0131k 187,5 g Ca(NO2)2’yi, 1,25 L’lik nihai hacim elde etmeye yetecek kadar suda \u00e7\u00f6zmeniz gerekir. Bu, \u015fu form\u00fcl kullan\u0131larak hesaplanabilir: form\u00fcl form\u00fcl: \u00e7\u00f6z\u00fcnen maddenin gram\u0131 = Molarite x hacim (litre cinsinden) x \u00e7\u00f6z\u00fcnen maddenin molar k\u00fctlesi.<\/p>\n

    S: Kalsiyum nitritin iyonik bile\u015fik form\u00fcl\u00fc nedir?<\/h3>\n

    A: Ca(NO2)2’nin iyonik bile\u015fik form\u00fcl\u00fc Ca(NO2)2’dir. Bir kalsiyum iyonu (Ca2+) ve iki nitrit iyonundan (NO2-) olu\u015fur.<\/p>\n","protected":false},"excerpt":{"rendered":"

    Kalsiyum nitrit (Ca(NO2)2), betonda korozyon \u00f6nleyici olarak yayg\u0131n olarak kullan\u0131lan kimyasal bir bile\u015fiktir. \u00c7elik donat\u0131lar\u0131n korozyonunu \u00f6nlemeye yard\u0131mc\u0131 olur. IUPAC’\u0131n ad\u0131 Kalsiyum dinitrit Molek\u00fcler form\u00fcl Ca(NO2)2 CAS numaras\u0131 13780-06-8 E\u015f anlaml\u0131 Kalsiyum nitrit dihidrat, nitr\u00f6z asit, kalsiyum tuzu, nitrik asit, kalsiyum tuzu, dihidrat vb. InChI InChI=1S\/Ca.2HNO2\/c;2 2-1-3\/h;2 (H,2,3) Kalsiyum nitritin \u00f6zellikleri Kalsiyum nitrit form\u00fcl\u00fc Kalsiyum … Devam\u0131n\u0131 oku<\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[5],"tags":[],"yoast_head":"\nKalsiyum Nitrit - Ca(NO2)2, 13780-06-8<\/title>\n<meta name=\"description\" content=\"Kalsiyum nitrit (Ca(NO2)2), betonda korozyon \u00f6nleyici olarak yayg\u0131n olarak kullan\u0131lan kimyasal bir bile\u015fiktir. 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