{"id":649,"date":"2023-07-22T03:11:27","date_gmt":"2023-07-22T03:11:27","guid":{"rendered":"https:\/\/chemuza.org\/tr\/sodyum-silikat-na2sio3\/"},"modified":"2023-07-22T03:11:27","modified_gmt":"2023-07-22T03:11:27","slug":"sodyum-silikat-na2sio3","status":"publish","type":"post","link":"https:\/\/chemuza.org\/tr\/sodyum-silikat-na2sio3\/","title":{"rendered":"Sodyum silikat \u2013 na2sio3, 6834-92-0"},"content":{"rendered":"

Sodyum silikat (Na2SiO3), sodyum, silikon ve oksijenden olu\u015fan bir bile\u015fiktir. Deterjan, yap\u0131\u015ft\u0131r\u0131c\u0131 ve silika jel \u00fcretimi de dahil olmak \u00fczere bir\u00e7ok kullan\u0131m alan\u0131 vard\u0131r.<\/p>\n

\n\n\n\n\n\n\n\n
IUPAC Ad\u0131<\/td>\n Sodyum metasilikat<\/td>\n<\/tr>\n
Molek\u00fcler form\u00fcl<\/td>\n Na2SiO3<\/td>\n<\/tr>\n
CAS numaras\u0131<\/td>\n 6834-92-0<\/td>\n<\/tr>\n
E\u015f anlaml\u0131<\/td>\n Su cam\u0131, s\u0131v\u0131 cam, \u00e7\u00f6z\u00fcn\u00fcr cam, sodyum ortosilikat, sodyum silikat cam\u0131, sodyum metasilikat<\/td>\n<\/tr>\n
InChI<\/td>\n InChI=1S\/2Na.O3Si\/c;;1-4(2)3\/q2*+1;-2<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n

Sodyum silikat\u0131n \u00f6zellikleri<\/strong><\/h2>\n

Sodyum Silikat Form\u00fcl\u00fc<\/h3>\n

Sodyum silikat\u0131n form\u00fcl\u00fc Na2SiO3’t\u00fcr; bu, bile\u015fi\u011fin her biriminin iki sodyum atomu, bir silikon atomu ve \u00fc\u00e7 oksijen atomu i\u00e7erdi\u011fini g\u00f6sterir. Sodyum silikat ayr\u0131ca polimer anyonundaki SiO2 birimlerinin say\u0131s\u0131na ba\u011fl\u0131 olarak Na2O\u00b7nSiO2 ve Na2SiO4 gibi di\u011fer form\u00fcllerle de bilinir. Sodyum silikat\u0131n form\u00fcl\u00fc, kimyasal \u00f6zelliklerini anlamak ve molar k\u00fctlesi ile molek\u00fcler a\u011f\u0131rl\u0131\u011f\u0131n\u0131 hesaplamak i\u00e7in \u00e7ok \u00f6nemlidir.<\/p>\n

Sodyum Silikat Molar K\u00fctlesi<\/h3>\n

Na2SiO3’\u00fcn molar k\u00fctlesi yakla\u015f\u0131k 122,06 g\/mol’d\u00fcr. Bu, bile\u015fikte mevcut olan sodyum (22,99 g\/mol), silikon (28,09 g\/mol) ve oksijenin (16,00 g\/mol) atomik k\u00fctlelerinin eklenmesiyle hesaplan\u0131r. Molar k\u00fctle, Na2SiO3 i\u00e7in \u00e7ok \u00f6nemli bir \u00f6zelliktir \u00e7\u00fcnk\u00fc bir reaksiyonda ihtiya\u00e7 duyulan bile\u015fik miktar\u0131n\u0131n belirlenmesine yard\u0131mc\u0131 olur.<\/p>\n

Sodyum silikat\u0131n kaynama noktas\u0131<\/h3>\n

Na2SiO3’\u00fcn kaynama noktas\u0131 tek bir de\u011fer de\u011fil, bir s\u0131cakl\u0131k aral\u0131\u011f\u0131d\u0131r. End\u00fcstriyel uygulamalarda yayg\u0131n olarak kullan\u0131lan Na2SiO3 \u00e7\u00f6zeltilerinin kaynama aral\u0131\u011f\u0131 100 ila 110\u00b0C aras\u0131ndad\u0131r. Na2SiO3’\u00fcn kaynama noktas\u0131 konsantrasyonu, safl\u0131\u011f\u0131 ve yabanc\u0131 maddelerin varl\u0131\u011f\u0131 gibi fakt\u00f6rlere ba\u011fl\u0131d\u0131r.<\/p>\n

Sodyum Silikat\u0131n Erime Noktas\u0131<\/h3>\n

Na2SiO3 normal \u015fartlarda kat\u0131 bir bile\u015fik halinde bulunmad\u0131\u011f\u0131ndan belirgin bir erime noktas\u0131na sahip de\u011fildir. Genellikle toz, gran\u00fcl veya topaklar halinde kat\u0131 halde bulunur. Na2SiO3’\u00fcn bu kat\u0131 formlar\u0131, bile\u015fimlerine ve haz\u0131rlama y\u00f6ntemlerine ba\u011fl\u0131 olarak de\u011fi\u015fen farkl\u0131 erime noktalar\u0131na sahiptir.<\/p>\n

Sodyum silikat\u0131n yo\u011funlu\u011fu g\/mL<\/h3>\n

Na2SiO3 \u00e7\u00f6zeltilerinin yo\u011funlu\u011fu, konsantrasyonlar\u0131na ba\u011fl\u0131 olarak de\u011fi\u015fir. %20 konsantrasyonlu Na2SiO3 \u00e7\u00f6zeltilerinin yo\u011funlu\u011fu yakla\u015f\u0131k 1,14 g\/mL iken %40 konsantrasyonlu Na2SiO3 \u00e7\u00f6zeltilerinin yo\u011funlu\u011fu yakla\u015f\u0131k 1,34 g\/mL’dir. Kat\u0131 Na2SiO3’\u00fcn yo\u011funlu\u011fu, safl\u0131\u011f\u0131na ve par\u00e7ac\u0131k boyutuna ba\u011fl\u0131 olarak 2,3 g\/mL ila 2,6 g\/mL aras\u0131nda de\u011fi\u015febilir.<\/p>\n

Sodyum Silikat Molek\u00fcl A\u011f\u0131rl\u0131\u011f\u0131 <\/h3>\n
\n
\"Sodyum<\/figure>\n<\/div>\n

A\u011f\u0131rl\u0131k form\u00fcl\u00fc olarak da bilinen Na2SiO3’\u00fcn molek\u00fcler a\u011f\u0131rl\u0131\u011f\u0131, bile\u015fikte bulunan t\u00fcm atomlar\u0131n atom a\u011f\u0131rl\u0131klar\u0131n\u0131n toplam\u0131d\u0131r. Na2SiO3’\u00fcn molek\u00fcler a\u011f\u0131rl\u0131\u011f\u0131 yakla\u015f\u0131k 122,06 g\/mol’d\u00fcr. Bir bile\u015fi\u011fin molek\u00fcler a\u011f\u0131rl\u0131\u011f\u0131n\u0131n bilinmesi, belirli bir reaksiyon i\u00e7in gerekli olan bile\u015fik miktar\u0131n\u0131n belirlenmesi a\u00e7\u0131s\u0131ndan \u00f6nemlidir.<\/p>\n

Sodyum silikat\u0131n yap\u0131s\u0131<\/h3>\n

Sodyum silikat, sodyum katyonlar\u0131 ve polimer silikat anyonlar\u0131ndan olu\u015fan inorganik bir bile\u015fiktir. Sodyum silikat\u0131n yap\u0131s\u0131, bile\u015fimine ve haz\u0131rlama y\u00f6ntemine ba\u011fl\u0131 olarak de\u011fi\u015febilir. Genellikle Na2O.nSiO2 form\u00fcl\u00fcyle temsil edilir; burada n, polimer anyonundaki SiO2 birimlerinin say\u0131s\u0131n\u0131 temsil eder. Polimer silikat anyonlar\u0131, silikon atomlar\u0131n\u0131n oksijen atomlar\u0131yla tetrahedral olarak koordine edildi\u011fi \u00fc\u00e7 boyutlu bir a\u011f yap\u0131s\u0131na sahiptir.<\/p>\n

\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n
D\u0131\u015f g\u00f6r\u00fcn\u00fc\u015f<\/td>\n Renksiz veya beyaz kat\u0131, s\u0131v\u0131 veya toz<\/td>\n<\/tr>\n
Spesifik yer \u00e7ekimi<\/td>\n 1.4-1.6<\/td>\n<\/tr>\n
Renk<\/td>\n Renksiz<\/td>\n<\/tr>\n
Koku<\/td>\n Kokusuz<\/td>\n<\/tr>\n
Molar k\u00fctle<\/td>\n 122,06 gr\/mol<\/td>\n<\/tr>\n
Yo\u011funluk<\/td>\n 1,14-1,34 g\/mL (\u00e7\u00f6zelti); 2,3-2,6 g\/mL (kat\u0131)<\/td>\n<\/tr>\n
F\u00fczyon noktas\u0131<\/td>\n Belirgin bir erime noktas\u0131 yok<\/td>\n<\/tr>\n
Kaynama noktas\u0131<\/td>\n 100-110\u00b0C (\u00e7\u00f6zelti)<\/td>\n<\/tr>\n
Fla\u015f noktas\u0131<\/td>\n Uygulanamaz<\/td>\n<\/tr>\n
sudaki \u00e7\u00f6z\u00fcn\u00fcrl\u00fck<\/td>\n \u00c7\u00f6z\u00fcn\u00fcr<\/td>\n<\/tr>\n
\u00e7\u00f6z\u00fcn\u00fcrl\u00fck<\/td>\n Suda ve etanolde \u00e7\u00f6z\u00fcn\u00fcr; metanol ve asetonda az \u00e7\u00f6z\u00fcn\u00fcr<\/td>\n<\/tr>\n
Buhar bas\u0131nc\u0131<\/td>\n Uygulanamaz<\/td>\n<\/tr>\n
Buhar yo\u011funlu\u011fu<\/td>\n Uygulanamaz<\/td>\n<\/tr>\n
pKa<\/td>\n ~9.8<\/td>\n<\/tr>\n
pH<\/td>\n 11-12 (\u00e7\u00f6z\u00fcm)<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n

Sodyum silikat\u0131n g\u00fcvenli\u011fi ve tehlikeleri<\/strong><\/h2>\n

Na2SiO3 do\u011fru \u015fekilde kullan\u0131lmazsa tehlikeli olabilir. Temas halinde ciddi cilt ve g\u00f6z tahri\u015fine neden olabilen yak\u0131c\u0131 bir bile\u015fiktir. Na2SiO3 tozunun veya bu\u011fusunun solunmas\u0131 solunum yolu tahri\u015fine ve akci\u011fer hasar\u0131na neden olabilir. Na2SiO3 \u00e7\u00f6zeltileri de olduk\u00e7a alkalidir ve ciltte veya mukozada kimyasal yan\u0131klara neden olabilir. Na2SiO3 ile \u00e7al\u0131\u015f\u0131rken eldiven ve g\u00f6z korumas\u0131 gibi uygun ki\u015fisel koruyucu ekipman giyilmelidir. Cilt veya g\u00f6zle temas\u0131 halinde derhal su ile durulanmas\u0131 gerekir. Na2SiO3 ayr\u0131ca serin, kuru ve iyi havaland\u0131r\u0131lm\u0131\u015f bir alanda, uyumsuz malzemelerden uzakta saklanmal\u0131d\u0131r.<\/p>\n

\n\n\n\n\n\n\n\n\n\n
Tehlike sembolleri<\/td>\n A\u015f\u0131nd\u0131r\u0131c\u0131, Tahri\u015f Edici<\/td>\n<\/tr>\n
G\u00fcvenlik A\u00e7\u0131klamas\u0131<\/td>\n \u00c7ocuklar\u0131n eri\u015femeyece\u011fi yerlerde saklay\u0131n. G\u00f6z, cilt ve giysilerle temas\u0131ndan ka\u00e7\u0131n\u0131n. Koruyucu eldiven\/koruyucu k\u0131yafet\/g\u00f6z koruyucu\/y\u00fcz koruyucu kullan\u0131n. DER\u0130 \u0130LE TEMAS HAL\u0130NDE \u0130SE: Bol su ile y\u0131kay\u0131n. G\u00d6Z \u0130LE TEMASI HAL\u0130NDE: Su ile birka\u00e7 dakika dikkatlice durulay\u0131n. Varsa ve yap\u0131lmas\u0131 kolaysa kontakt lensleri \u00e7\u0131kar\u0131n. Durulamaya devam edin. YUTULMASI HAL\u0130NDE: A\u011fz\u0131n\u0131z\u0131 \u00e7alkalay\u0131n. Kusturmaya \u00c7ALI\u015eMAYIN. Kendinizi iyi hissetmiyorsan\u0131z ZEH\u0130R MERKEZ\u0130N\u0130 veya doktoru aray\u0131n.<\/td>\n<\/tr>\n
BM kimlik numaralar\u0131<\/td>\n UN2922, UN1824<\/td>\n<\/tr>\n
HS kodu<\/td>\n 2839.90.90<\/td>\n<\/tr>\n
Tehlike s\u0131n\u0131f\u0131<\/td>\n 8<\/td>\n<\/tr>\n
Paketleme grubu<\/td>\n III<\/td>\n<\/tr>\n
Toksisite<\/td>\n LD50 (oral, s\u0131\u00e7an) = 1,280 mg\/kg; LC50 (soluma, s\u0131\u00e7an) >2,28 mg\/L\/4 saat<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n

Sodyum silikat sentezi i\u00e7in y\u00f6ntemler<\/strong><\/h2>\n

Na2SiO3’\u00fc sentezlemek i\u00e7in \u00e7e\u015fitli y\u00f6ntemler mevcuttur.<\/p>\n

Yayg\u0131n bir y\u00f6ntem, silikan\u0131n y\u00fcksek s\u0131cakl\u0131klarda sodyum karbonatla<\/a> kayna\u015ft\u0131r\u0131lmas\u0131d\u0131r; bu, yan \u00fcr\u00fcnler olarak Na2SiO3 ve karbondioksit \u00fcretir.<\/p>\n

Ba\u015fka bir y\u00f6ntem, sodyum hidroksitin silika ile y\u00fcksek bas\u0131n\u00e7l\u0131 bir kapta y\u00fcksek s\u0131cakl\u0131klarda reaksiyona sokulmas\u0131n\u0131 i\u00e7erir. \u0130stenilen konsantrasyonu elde etmek i\u00e7in y\u00fcksek konsantrasyonlu Na2SiO3 \u00e7\u00f6zeltisini suyla seyreltin.<\/p>\n

\u00dc\u00e7\u00fcnc\u00fc bir y\u00f6ntem, silika jelinin bir sodyum hidroksit<\/a> \u00e7\u00f6zeltisi i\u00e7inde \u00e7\u00f6z\u00fclmesini, ard\u0131ndan reaksiyonun h\u0131zland\u0131r\u0131lmas\u0131 i\u00e7in kar\u0131\u015f\u0131m\u0131n \u0131s\u0131t\u0131lmas\u0131n\u0131 ve kar\u0131\u015ft\u0131r\u0131lmas\u0131n\u0131 i\u00e7erir. Bu y\u00f6ntem berrak, renksiz bir Na2SiO3 \u00e7\u00f6zeltisi \u00fcretir.<\/p>\n

Mikrodalga radyasyonu, Na2SiO3 sentezleyerek reaktanlar\u0131 \u0131s\u0131tabilir.<\/p>\n

Bu y\u00f6ntemler, geleneksel sentez y\u00f6ntemlerine g\u00f6re daha y\u00fcksek safl\u0131kta ve verimde Na2SiO3 \u00fcretir.<\/p>\n

Ek olarak, baz\u0131 \u00e7al\u0131\u015fmalarda pirin\u00e7 kabu\u011fu k\u00fcl\u00fc ve \u015feker kam\u0131\u015f\u0131 k\u00fcspesi k\u00fcl\u00fc gibi yenilenebilir kaynaklar\u0131n Na2SiO3 sentezi i\u00e7in silika kayna\u011f\u0131 olarak kullan\u0131lmas\u0131 ara\u015ft\u0131r\u0131lm\u0131\u015f ve b\u00f6ylece daha s\u00fcrd\u00fcr\u00fclebilir bir \u00fcretim yakla\u015f\u0131m\u0131 sa\u011flanm\u0131\u015ft\u0131r.<\/p>\n

Sodyum silikat\u0131n kullan\u0131m alanlar\u0131<\/strong><\/h2>\n

Na2SiO3, \u00e7e\u015fitli end\u00fcstrilerde bir\u00e7ok uygulamaya sahip \u00e7ok y\u00f6nl\u00fc bir bile\u015fiktir. Na2SiO3’\u00fcn yayg\u0131n kullan\u0131mlar\u0131ndan baz\u0131lar\u0131 \u015funlard\u0131r:<\/p>\n

    \n
  1. Yap\u0131\u015ft\u0131r\u0131c\u0131lar ve Ba\u011flay\u0131c\u0131lar: Karton, oluklu kutu ve kontrplak gibi \u00e7e\u015fitli uygulamalarda ba\u011flay\u0131c\u0131 olarak kullan\u0131l\u0131r.<\/li>\n
  2. Deterjanlar ve Sabunlar: \u00c7ama\u015f\u0131r deterjanlar\u0131nda alkalin tampon ve yeniden tortu \u00f6nleyici madde olarak kullan\u0131l\u0131r.<\/li>\n
  3. Su Ar\u0131tma: Su ar\u0131tmada p\u0131ht\u0131la\u015ft\u0131r\u0131c\u0131 ve korozyon \u00f6nleyici olarak kullan\u0131l\u0131r.<\/li>\n
  4. Yap\u0131l\u0131\u015f\u0131: Beton sertle\u015ftirici ve toprak stabilizat\u00f6r\u00fc olarak da kullan\u0131l\u0131r.<\/li>\n
  5. Seramik: Seramik \u00fcretiminde ba\u011flay\u0131c\u0131 olarak kullan\u0131l\u0131r.<\/li>\n
  6. Tekstil ve ka\u011f\u0131t: Ka\u011f\u0131t \u00fcretiminde ha\u015f\u0131l maddesi ve tekstilde alev geciktirici olarak kullan\u0131l\u0131r.<\/li>\n
  7. Otomotiv: Otomotiv end\u00fcstrisinde s\u0131zd\u0131rmazl\u0131k ve so\u011futucu katk\u0131 maddesi olarak kullan\u0131l\u0131r.<\/li>\n
  8. Tar\u0131m: Bitki b\u00fcy\u00fcmesini iyile\u015ftirmek i\u00e7in yaprak spreyi olarak ve toprak s\u0131k\u0131\u015fmas\u0131n\u0131 azaltmak ve su tutmay\u0131 artt\u0131rmak i\u00e7in toprak d\u00fczenleyici olarak kullan\u0131l\u0131r.<\/li>\n
  9. Yang\u0131ndan korunma: Ah\u015fap, kuma\u015f ve ka\u011f\u0131t gibi \u00e7e\u015fitli malzemelerde alev geciktirici olarak kullan\u0131l\u0131r.<\/li>\n
  10. Ki\u015fisel Bak\u0131m: Baz\u0131 di\u015f macunlar\u0131 ve deodorantlarda ba\u011flay\u0131c\u0131 ve viskozite kontrol maddesi olarak kullan\u0131l\u0131r.<\/li>\n<\/ol>\n

    Sorular:<\/strong><\/h2>\n

    S: Sodyum silikat zehirli midir?<\/h3>\n

    C: Na2SiO3 b\u00fcy\u00fck miktarlarda yutuldu\u011funda veya solundu\u011funda toksik olabilir. G\u00f6zleri, cildi ve solunum sistemini tahri\u015f edebilir. Bununla birlikte, uygun ki\u015fisel koruyucu ekipman\u0131n kullan\u0131lmas\u0131 gibi g\u00fcvenlik kurallar\u0131na uygun olarak kullan\u0131ld\u0131\u011f\u0131nda, Na2SiO3’\u00fcn kullan\u0131m\u0131 genellikle g\u00fcvenlidir.<\/p>\n

    S: Na2SiO3 nas\u0131l iyile\u015ftirilir?<\/h3>\n

    C: Na2SiO3, karbondioksite maruz b\u0131rak\u0131larak sertle\u015ftirilir, bu da s\u0131v\u0131 Na2SiO3’\u00fcn sert, cam benzeri bir madde halinde kat\u0131la\u015fmas\u0131na neden olur. K\u00fcrlenme s\u00fcresi, Na2SiO3 \u00e7\u00f6zeltisinin konsantrasyonunun yan\u0131 s\u0131ra k\u00fcrleme ortam\u0131n\u0131n s\u0131cakl\u0131\u011f\u0131na ve nemine ba\u011fl\u0131d\u0131r. Tipik olarak Na2SiO3’\u00fcn tamamen sertle\u015fmesi birka\u00e7 g\u00fcn s\u00fcrer.<\/p>\n

    S: Sodyum silikatla i\u015flenmi\u015f betonun \u00fczerini boyayabilir misiniz?<\/h3>\n

    C: Evet, Na2SiO3 ile i\u015flem g\u00f6rm\u00fc\u015f betonun \u00fczerini boyamak m\u00fcmk\u00fcnd\u00fcr ancak y\u00fczeyin uygun \u015fekilde haz\u0131rlanmas\u0131 gerekir. Boya uygulanmadan \u00f6nce Na2SiO3 tamamen k\u00fcrlenmeli, daha sonra y\u00fczey temizlenmeli ve uygun bir astar ile astarlanmal\u0131d\u0131r.<\/p>\n

    S: Yak\u0131n\u0131mdaki sodyum silikat nereden sat\u0131n al\u0131n\u0131r?<\/h3>\n

    C: Na2SiO3 kimyasal tedarik\u00e7ilerden, end\u00fcstriyel tedarik\u00e7ilerden ve \u00e7evrimi\u00e7i perakendecilerden sat\u0131n al\u0131nabilir. Tedarik\u00e7inin sayg\u0131n olmas\u0131n\u0131 ve Na2SiO3’\u00fcn y\u00fcksek kalitede ve ama\u00e7lanan uygulamaya uygun olmas\u0131n\u0131 sa\u011flamak \u00f6nemlidir. Na2SiO3 sat\u0131n al\u0131rken ve kullan\u0131rken uygun kullan\u0131m ve g\u00fcvenlik kurallar\u0131na uymak da \u00f6nemlidir.<\/p>\n","protected":false},"excerpt":{"rendered":"

    Sodyum silikat (Na2SiO3), sodyum, silikon ve oksijenden olu\u015fan bir bile\u015fiktir. Deterjan, yap\u0131\u015ft\u0131r\u0131c\u0131 ve silika jel \u00fcretimi de dahil olmak \u00fczere bir\u00e7ok kullan\u0131m alan\u0131 vard\u0131r. IUPAC Ad\u0131 Sodyum metasilikat Molek\u00fcler form\u00fcl Na2SiO3 CAS numaras\u0131 6834-92-0 E\u015f anlaml\u0131 Su cam\u0131, s\u0131v\u0131 cam, \u00e7\u00f6z\u00fcn\u00fcr cam, sodyum ortosilikat, sodyum silikat cam\u0131, sodyum metasilikat InChI InChI=1S\/2Na.O3Si\/c;;1-4(2)3\/q2*+1;-2 Sodyum silikat\u0131n \u00f6zellikleri Sodyum … Devam\u0131n\u0131 oku<\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[5],"tags":[],"yoast_head":"\nSodyum silikat - Na2SiO3, 6834-92-0<\/title>\n<meta name=\"description\" content=\"Sodyum silikat (Na2SiO3), sodyum, silikon ve oksijenden olu\u015fan bir bile\u015fiktir. 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