{"id":523,"date":"2023-07-22T20:26:21","date_gmt":"2023-07-22T20:26:21","guid":{"rendered":"https:\/\/chemuza.org\/tr\/nitrojen-florur\/"},"modified":"2023-07-22T20:26:21","modified_gmt":"2023-07-22T20:26:21","slug":"nitrojen-florur","status":"publish","type":"post","link":"https:\/\/chemuza.org\/tr\/nitrojen-florur\/","title":{"rendered":"Azot flor\u00fcr \u2013 nf, 13967-06-1"},"content":{"rendered":"

Azot flor\u00fcr, nitrojen ve flordan olu\u015fan olduk\u00e7a reaktif bir kimyasal bile\u015fiktir. Yar\u0131 iletken end\u00fcstrisinde plazma a\u015f\u0131nd\u0131rma ve temizleme i\u015flemleri i\u00e7in kullan\u0131l\u0131r.<\/p>\n

\n\n\n\n\n\n\n\n
IUPAC Ad\u0131<\/td>\n Azot flor\u00fcr<\/td>\n<\/tr>\n
Molek\u00fcler form\u00fcl<\/td>\n NF<\/td>\n<\/tr>\n
CAS numaras\u0131<\/td>\n 13967-06-1<\/td>\n<\/tr>\n
E\u015f anlaml\u0131<\/td>\n Azot monoflor\u00fcr, nitrojen (II) flor\u00fcr, nitrojen flor\u00fcr (NF), UN 2451, EINECS 232-013-4<\/td>\n<\/tr>\n
InChI<\/td>\n InChI=1S\/FN\/c1-2<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n
Azot Flor\u00fcr molar k\u00fctlesi<\/h6>\n

Azot flor\u00fcr\u00fcn (NF) molar k\u00fctlesi 33.005 g\/mol’d\u00fcr. Azot ve flor aras\u0131ndaki elektronegatiflik fark\u0131ndan dolay\u0131 \u00e7ok reaktif, hafif, renksiz bir gazd\u0131r. Molar k\u00fctlesi, s\u0131ras\u0131yla 14.007 g\/mol ve 18.998 g\/mol olan nitrojen ve florin atomik k\u00fctlelerinden kaynaklan\u0131r. Molek\u00fcl\u00fcn k\u00fc\u00e7\u00fck boyutu, onu plazma a\u015f\u0131nd\u0131rma ve temizleme i\u015flemleri i\u00e7in kullan\u0131ld\u0131\u011f\u0131 yar\u0131 iletken end\u00fcstrisinde kullan\u0131m i\u00e7in ideal bir aday haline getirir.<\/p>\n

Azot flor\u00fcr\u00fcn kaynama noktas\u0131<\/h6>\n

Azot flor\u00fcr\u00fcn kaynama noktas\u0131 -129,6\u00b0C’dir (-201,3\u00b0F). Bu s\u0131cakl\u0131kta gaz halinden s\u0131v\u0131 hale ge\u00e7er. Azot flor\u00fcr\u00fcn, esas olarak Van der Waals kuvvetleri olan zay\u0131f molek\u00fcller aras\u0131 kuvvetleri nedeniyle d\u00fc\u015f\u00fck kaynama noktas\u0131na sahiptir. Bu d\u00fc\u015f\u00fck kaynama noktas\u0131, onu dikkatli kullan\u0131lmas\u0131 gereken u\u00e7ucu ve \u00e7ok reaktif bir bile\u015fik haline getirir.<\/p>\n

Azot flor\u00fcr\u00fcn erime noktas\u0131<\/h6>\n

Azot flor\u00fcr\u00fcn erime noktas\u0131 -206,5\u00b0C’dir (-339,7\u00b0F). Bu s\u0131cakl\u0131kta kat\u0131 halden s\u0131v\u0131 hale ge\u00e7er. D\u00fc\u015f\u00fck erime noktas\u0131, esas olarak Van der Waals kuvvetleri olan molek\u00fcller aras\u0131ndaki zay\u0131f molek\u00fcller aras\u0131 kuvvetlerden kaynaklanmaktad\u0131r. Nitrojen flor\u00fcr\u00fcn d\u00fc\u015f\u00fck erime noktas\u0131 da onu \u00e7ok reaktif ve u\u00e7ucu hale getirir.<\/p>\n

Nitrojen flor\u00fcr\u00fcn yo\u011funlu\u011fu g\/ml<\/h6>\n

Nitrojen flor\u00fcr\u00fcn yo\u011funlu\u011fu standart s\u0131cakl\u0131k ve bas\u0131n\u00e7ta (STP) 1,49 g\/mL’dir. Bu yo\u011funluk, molek\u00fcl\u00fcn k\u00fc\u00e7\u00fck boyutu ve iki atomun varl\u0131\u011f\u0131 nedeniyle di\u011fer gazlarla kar\u015f\u0131la\u015ft\u0131r\u0131ld\u0131\u011f\u0131nda nispeten y\u00fcksektir. Nitrojen flor\u00fcr\u00fcn y\u00fcksek yo\u011funlu\u011fu, onu plazma a\u015f\u0131nd\u0131rma ve temizleme i\u015flemleri i\u00e7in kullan\u0131ld\u0131\u011f\u0131 yar\u0131 iletken end\u00fcstrisinde kullan\u0131m i\u00e7in ideal bir aday haline getirir.<\/p>\n

Azot flor\u00fcr\u00fcn molek\u00fcler a\u011f\u0131rl\u0131\u011f\u0131<\/h6>\n

Azot flor\u00fcr\u00fcn molek\u00fcler a\u011f\u0131rl\u0131\u011f\u0131 33.005 g\/mol’d\u00fcr. Bu de\u011fer, s\u0131ras\u0131yla 14,007 g\/mol ve 18,998 g\/mol olan nitrojen ve florin atomik k\u00fctlelerinin toplam\u0131ndan elde edilir. Molek\u00fcl\u00fcn k\u00fc\u00e7\u00fck boyutu ve nispeten d\u00fc\u015f\u00fck molek\u00fcler a\u011f\u0131rl\u0131\u011f\u0131, onu yar\u0131 iletken end\u00fcstrisinde kullan\u0131m i\u00e7in ideal bir aday haline getiriyor.<\/p>\n

Azot flor\u00fcr\u00fcn yap\u0131s\u0131 <\/h6>\n
\n
\"nitrojen<\/figure>\n<\/div>\n

NF, merkezde nitrojen atomu ve her iki u\u00e7ta da flor atomu bulunan do\u011frusal bir molek\u00fcler yap\u0131ya sahiptir. Azot ve flor atomlar\u0131 aras\u0131ndaki ba\u011f kovalent bir ba\u011fd\u0131r ve molek\u00fcl, iki atom aras\u0131ndaki elektronegatiflik fark\u0131ndan dolay\u0131 polar bir yap\u0131ya sahiptir. Molek\u00fcl\u00fcn bir dipol momenti vard\u0131r, bu da onu olduk\u00e7a reaktif hale getirir ve di\u011fer molek\u00fcllerle kimyasal ba\u011flar olu\u015fturma olas\u0131l\u0131\u011f\u0131n\u0131 art\u0131r\u0131r.<\/p>\n

Azot Flor\u00fcr Form\u00fcl\u00fc<\/h6>\n

Azot flor\u00fcr\u00fcn kimyasal form\u00fcl\u00fc NF’dir. Bu form\u00fcl, molek\u00fcl\u00fcn bir nitrojen atomu ve bir flor atomundan olu\u015ftu\u011funu g\u00f6sterir. Molek\u00fcl, iki atom aras\u0131ndaki elektronegatiflik fark\u0131ndan dolay\u0131 do\u011frusal bir yap\u0131ya ve kutupsal bir yap\u0131ya sahiptir. NF form\u00fcl\u00fc, plazma a\u015f\u0131nd\u0131rma ve temizleme i\u015flemleri i\u00e7in kullan\u0131ld\u0131\u011f\u0131 yar\u0131 iletken end\u00fcstrisinde yayg\u0131n olarak kullan\u0131l\u0131r.<\/p>\n

\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n
D\u0131\u015f g\u00f6r\u00fcn\u00fc\u015f<\/td>\n Renksiz gaz veya soluk sar\u0131 s\u0131v\u0131<\/td>\n<\/tr>\n
Spesifik yer \u00e7ekimi<\/td>\n 1,49 (STP’de)<\/td>\n<\/tr>\n
Renk<\/td>\n Renksiz<\/td>\n<\/tr>\n
Koku<\/td>\n D\u00f6n\u00fcm<\/td>\n<\/tr>\n
Molar k\u00fctle<\/td>\n 33.005 gr\/mol<\/td>\n<\/tr>\n
Yo\u011funluk<\/td>\n 1,49 g\/mL (STP’de)<\/td>\n<\/tr>\n
F\u00fczyon noktas\u0131<\/td>\n -206,5\u00b0C (-339,7\u00b0F)<\/td>\n<\/tr>\n
Kaynama noktas\u0131<\/td>\n -129,6\u00b0C (-201,3\u00b0F)<\/td>\n<\/tr>\n
Fla\u015f noktas\u0131<\/td>\n Uygulanamaz<\/td>\n<\/tr>\n
sudaki \u00e7\u00f6z\u00fcn\u00fcrl\u00fck<\/td>\n Suyla reaksiyona girer<\/td>\n<\/tr>\n
\u00e7\u00f6z\u00fcn\u00fcrl\u00fck<\/td>\n Organik \u00e7\u00f6z\u00fcc\u00fclerde \u00e7\u00f6z\u00fcn\u00fcr<\/td>\n<\/tr>\n
Buhar bas\u0131nc\u0131<\/td>\n 25\u00b0C’de 298,5 kPa<\/td>\n<\/tr>\n
Buhar yo\u011funlu\u011fu<\/td>\n 1,44 (hava = 1)<\/td>\n<\/tr>\n
pKa<\/td>\n Uygulanamaz<\/td>\n<\/tr>\n
pH<\/td>\n Uygulanamaz<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n
Nitrojen flor\u00fcr\u00fcn g\u00fcvenli\u011fi ve tehlikeleri<\/strong><\/h5>\n

Nitrojen flor\u00fcr (NF), olduk\u00e7a reaktif ve toksik yap\u0131s\u0131 nedeniyle \u00f6nemli bir g\u00fcvenlik riski olu\u015fturur. NF’ye maruz kalmak ciltte, g\u00f6zlerde ve solunum yollar\u0131nda ciddi yan\u0131klara ve tahri\u015fe neden olabilir. NF g\u00fc\u00e7l\u00fc bir oksidand\u0131r ve giysi, ka\u011f\u0131t veya ah\u015fap gibi organik malzemelerle temas etti\u011finde tutu\u015fabilir veya patlayabilir. Ayr\u0131ca su ve di\u011fer kimyasallarla \u015fiddetli reaksiyona girerek zehirli duman ve gazlar a\u00e7\u0131\u011fa \u00e7\u0131karabilir. Maruz kalma ve yaralanma riskini en aza indirmek i\u00e7in solunumsal NF ile \u00e7al\u0131\u015f\u0131rken koruyucu giysi kullan\u0131m\u0131, koruma ve uygun kullan\u0131m ve depolama prosed\u00fcrleri dahil uygun g\u00fcvenlik \u00f6nlemleri uygulanmal\u0131d\u0131r.<\/p>\n

\n\n\n\n\n\n\n\n\n\n\n\n\n
Tehlike sembolleri<\/td>\n Oksitleyici<\/td>\n<\/tr>\n
G\u00fcvenlik A\u00e7\u0131klamas\u0131<\/td>\n Yan\u0131c\u0131 maddelerden, \u0131s\u0131dan, k\u0131v\u0131lc\u0131mlardan ve a\u00e7\u0131k alevden uzak tutun.<\/td>\n<\/tr>\n
<\/td>\n Koruyucu k\u0131yafet, eldiven ve g\u00f6z\/y\u00fcz korumas\u0131 kullan\u0131n.<\/td>\n<\/tr>\n
<\/td>\n Yang\u0131n durumunda su, kuru kimyasal veya karbondioksitli s\u00f6nd\u00fcr\u00fcc\u00fcler kullan\u0131n.<\/td>\n<\/tr>\n
B\u0130R tan\u0131mlay\u0131c\u0131lar<\/td>\n UN2468 (gaz i\u00e7in), UN3263 (s\u0131v\u0131 i\u00e7in)<\/td>\n<\/tr>\n
HS kodu<\/td>\n 2811.22.00<\/td>\n<\/tr>\n
Tehlike s\u0131n\u0131f\u0131<\/td>\n 5.1 (oksitleyici maddeler)<\/td>\n<\/tr>\n
Paketleme grubu<\/td>\n II (gaz i\u00e7in), III (s\u0131v\u0131 i\u00e7in)<\/td>\n<\/tr>\n
Toksisite<\/td>\n NF son derece zehirlidir ve ciltte, g\u00f6zlerde, ciltte ciddi yan\u0131klara ve tahri\u015fe neden olabilir.<\/td>\n<\/tr>\n
<\/td>\n ve solunum yolu. Yutulmas\u0131 veya solunmas\u0131 \u00f6l\u00fcmc\u00fcl olabilir.<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n
Azot flor\u00fcr\u00fcn sentezi i\u00e7in y\u00f6ntemler<\/strong><\/h5>\n

Nitrojen monoflor\u00fcr \u00fcretiminde, bir flor atomunun nitrojen diflor\u00fcrden (NF2) radikal t\u00fcrler (H, O, N, CH3) taraf\u0131ndan ekstraksiyonu, uzun zincir yay\u0131lma s\u00fcresi i\u00e7in verimli bir \u015fekilde bir radikal \u00fcretir. Ancak nihai \u00fcr\u00fcn, ayr\u0131\u015fmas\u0131n\u0131 katalize eden radikal safs\u0131zl\u0131klar i\u00e7erir.<\/p>\n

Daha saf bir \u00fcr\u00fcn elde etmek i\u00e7in, daha az verimli fakat daha saf olan azid ayr\u0131\u015ft\u0131rma tekni\u011fi kullan\u0131labilir. Bu, atomik florinin hidrazoik asit ile reaksiyonu yoluyla yerinde olu\u015fturulabilen florin azidin \u015fok kaynakl\u0131 bozunmas\u0131n\u0131 NF ve N2’ye i\u00e7erir.<\/p>\n

NF \u00fcretimi s\u0131ras\u0131nda, uygun koruyucu ekipman ve k\u0131yafetlerin kullan\u0131lmas\u0131 ve tehlikeli maddelere ve kimyasallara maruz kalmay\u0131 en aza indirmek i\u00e7in yeterli havaland\u0131rman\u0131n sa\u011flanmas\u0131 da dahil olmak \u00fczere uygun g\u00fcvenlik \u00f6nlemlerinin uygulanmas\u0131 \u00f6nemlidir.<\/p>\n

Azot flor\u00fcr\u00fcn kullan\u0131m alanlar\u0131<\/strong><\/h5>\n

Azot flor\u00fcr\u00fcn (NF) \u00e7e\u015fitli end\u00fcstrilerde \u00e7e\u015fitli uygulamalar\u0131 vard\u0131r.<\/p>\n

NF esas olarak yar\u0131 iletkenlerin ve elektronik \u00fcr\u00fcnlerin \u00fcretiminde silikon nitr\u00fcr ve di\u011fer malzemelerin ince filmlerinin y\u00fczeyler \u00fczerine biriktirilmesinde florlama maddesi olarak kullan\u0131l\u0131r.<\/p>\n

Havac\u0131l\u0131k ve uzay end\u00fcstrisi, y\u00fcksek oksitleyici g\u00fcc\u00fc ve d\u00fc\u015f\u00fck molek\u00fcler a\u011f\u0131rl\u0131\u011f\u0131 nedeniyle NF’yi roket yak\u0131t\u0131 olarak kullan\u0131yor ve bu da onu verimli bir yak\u0131t haline getiriyor. Ayr\u0131ca yanmay\u0131 iyile\u015ftirmek ve itmeyi artt\u0131rmak i\u00e7in roket yak\u0131t\u0131nda katk\u0131 maddesi olarak da kullan\u0131l\u0131r.<\/p>\n

NF, t\u0131p end\u00fcstrisinde baz\u0131 farmas\u00f6tiklerin sentezinde ve laboratuvar deneylerinde reaktif olarak rol oynar. Ayr\u0131ca g\u00fc\u00e7l\u00fc oksitleyici \u00f6zellikleri nedeniyle t\u0131bbi ekipmanlar i\u00e7in sterilizasyon maddesi olarak da g\u00f6rev yapar.<\/p>\n

\u00d6zel cam ve seramik \u00fcretiminde, malzemenin erime noktas\u0131n\u0131 d\u00fc\u015f\u00fcrmek ve \u00f6zelliklerini iyile\u015ftirmek i\u00e7in eritici madde olarak NF kullan\u0131l\u0131r.<\/p>\n

Ancak NF’nin olduk\u00e7a reaktif ve toksik do\u011fas\u0131 \u00f6nemli g\u00fcvenlik riskleri ta\u015f\u0131r. Bu nedenle, maruz kalma ve yaralanma riskini en aza indirmek i\u00e7in NF ile \u00e7al\u0131\u015f\u0131rken koruyucu ekipman kullan\u0131m\u0131 ve uygun kullan\u0131m prosed\u00fcrleri dahil olmak \u00fczere uygun g\u00fcvenlik \u00f6nlemlerinin uygulanmas\u0131 \u00f6nemlidir.<\/p>\n","protected":false},"excerpt":{"rendered":"

Azot flor\u00fcr, nitrojen ve flordan olu\u015fan olduk\u00e7a reaktif bir kimyasal bile\u015fiktir. Yar\u0131 iletken end\u00fcstrisinde plazma a\u015f\u0131nd\u0131rma ve temizleme i\u015flemleri i\u00e7in kullan\u0131l\u0131r. IUPAC Ad\u0131 Azot flor\u00fcr Molek\u00fcler form\u00fcl NF CAS numaras\u0131 13967-06-1 E\u015f anlaml\u0131 Azot monoflor\u00fcr, nitrojen (II) flor\u00fcr, nitrojen flor\u00fcr (NF), UN 2451, EINECS 232-013-4 InChI InChI=1S\/FN\/c1-2 Azot Flor\u00fcr molar k\u00fctlesi Azot flor\u00fcr\u00fcn (NF) molar … Devam\u0131n\u0131 oku<\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[5],"tags":[],"yoast_head":"\nAzot Flor\u00fcr - NF, 13967-06-1<\/title>\n<meta name=\"description\" content=\"Azot flor\u00fcr, nitrojen ve flordan olu\u015fan olduk\u00e7a reaktif bir kimyasal bile\u015fiktir. 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