{"id":461,"date":"2023-07-23T05:51:55","date_gmt":"2023-07-23T05:51:55","guid":{"rendered":"https:\/\/chemuza.org\/ja\/%e5%a1%a9%e5%8c%96%e3%82%a2%e3%82%bb%e3%83%81%e3%83%ab-c2h3clo\/"},"modified":"2023-07-23T05:51:55","modified_gmt":"2023-07-23T05:51:55","slug":"%e5%a1%a9%e5%8c%96%e3%82%a2%e3%82%bb%e3%83%81%e3%83%ab-c2h3clo","status":"publish","type":"post","link":"https:\/\/chemuza.org\/ja\/%e5%a1%a9%e5%8c%96%e3%82%a2%e3%82%bb%e3%83%81%e3%83%ab-c2h3clo\/","title":{"rendered":"\u5869\u5316\u30a2\u30bb\u30c1\u30eb \u2013 c2h3clo\u300175-36-5"},"content":{"rendered":"<p>\u5869\u5316\u30a2\u30bb\u30c1\u30eb\u307e\u305f\u306f C2H3ClO \u306f\u3001\u523a\u6fc0\u81ed\u306e\u3042\u308b\u7121\u8272\u306e\u767a\u7159\u6db2\u4f53\u3067\u3059\u3002\u4e3b\u306b\u6709\u6a5f\u5408\u6210\u306e\u8a66\u85ac\u3068\u3057\u3066\u3001\u307e\u305f\u533b\u85ac\u54c1\u3084\u67d3\u6599\u306e\u88fd\u9020\u3067\u306f\u30a2\u30bb\u30c1\u30eb\u5316\u5264\u3068\u3057\u3066\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002<\/p>\n<figure class=\"wp-block-table\">\n<table>\n<tbody>\n<tr>\n<td> UPAC\u540d<\/td>\n<td>\u5869\u5316\u30a2\u30bb\u30c1\u30eb<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u5f0f<\/td>\n<td>C2H3ClO<\/td>\n<\/tr>\n<tr>\n<td> CAS\u756a\u53f7<\/td>\n<td>75-36-5<\/td>\n<\/tr>\n<tr>\n<td>\u540c\u7fa9\u8a9e<\/td>\n<td>\u5869\u5316\u30a8\u30bf\u30ce\u30a4\u30eb\u3001\u5869\u5316\u9162\u9178\u3001\u5869\u5316\u9162\u9178\u3001\u30af\u30ed\u30ed\u30a2\u30bb\u30c1\u30eb\u30af\u30ed\u30ea\u30c9\u3001AcCl<\/td>\n<\/tr>\n<tr>\n<td>\u30a4\u30f3\u30c1\u30c1<\/td>\n<td>InChI=1S\/C2H3ClO\/c1-2(3)4\/h1H3<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n<h2 class=\"wp-block-heading\"><strong>\u5869\u5316\u30a2\u30bb\u30c1\u30eb\u306e\u6027\u8cea<\/strong><\/h2>\n<h3 class=\"wp-block-heading\">\u5869\u5316\u30a2\u30bb\u30c1\u30eb \u30e2\u30eb\u8cea\u91cf<\/h3>\n<p>\u5316\u5b66\u5f0f C2H3ClO \u306e\u5869\u5316\u30a2\u30bb\u30c1\u30eb\u306e\u30e2\u30eb\u8cea\u91cf\u306f\u7d04 78.50 g\/mol \u3067\u3059\u3002\u3053\u308c\u306f\u3001\u5206\u5b50\u5185\u306e\u5404\u539f\u5b50\u306e\u539f\u5b50\u8cea\u91cf\u3001\u3064\u307e\u308a\u70ad\u7d20 (12.01 g\/mol)\u3001\u6c34\u7d20 (1.01 g\/mol)\u3001\u5869\u7d20 (35.45 g\/mol)\u3001\u9178\u7d20 (16.00 g\/mol) \u3092\u52a0\u7b97\u3059\u308b\u3053\u3068\u306b\u3088\u3063\u3066\u8a08\u7b97\u3055\u308c\u307e\u3059\u3002\u5869\u5316\u30a2\u30bb\u30c1\u30eb\u306e\u30e2\u30eb\u8cea\u91cf\u306f\u3001\u5316\u5b66\u53cd\u5fdc\u306b\u304a\u3051\u308b\u53cd\u5fdc\u7269\u3068\u751f\u6210\u7269\u306e\u91cf\u3092\u6c7a\u5b9a\u3059\u308b\u305f\u3081\u306e\u5316\u5b66\u91cf\u8ad6\u7684\u8a08\u7b97\u306b\u304a\u3044\u3066\u91cd\u8981\u3067\u3059\u3002<\/p>\n<h3 class=\"wp-block-heading\">\u5869\u5316\u30a2\u30bb\u30c1\u30eb\u306e\u6cb8\u70b9<\/h3>\n<p>\u5869\u5316\u30a2\u30bb\u30c1\u30eb\u306e\u6cb8\u70b9\u306f\u3001\u6a19\u6e96\u5927\u6c17\u5727\u3067 51.5\u00b0C (124.7\u00b0F) \u3067\u3059\u3002\u3053\u306e\u6cb8\u70b9\u304c\u4f4e\u3044\u3053\u3068\u3068\u3001\u53cd\u5fdc\u6027\u304c\u9ad8\u3044\u6027\u8cea\u304c\u3042\u308b\u305f\u3081\u3001\u5b9f\u9a13\u5ba4\u3067\u306f\u5869\u5316\u30a2\u30bb\u30c1\u30eb\u3092\u614e\u91cd\u306b\u53d6\u308a\u6271\u3046\u5fc5\u8981\u304c\u3042\u308a\u307e\u3059\u3002\u3053\u308c\u306f\u523a\u6fc0\u81ed\u306e\u3042\u308b\u7121\u8272\u306e\u767a\u7159\u6027\u6db2\u4f53\u3067\u3001\u30a8\u30bf\u30ce\u30fc\u30eb\u3084\u30a2\u30bb\u30c8\u30f3\u306a\u3069\u306e\u6975\u6027\u6eb6\u5a92\u306b\u3088\u304f\u6eb6\u3051\u307e\u3059\u3002<\/p>\n<h3 class=\"wp-block-heading\">\u5869\u5316\u30a2\u30bb\u30c1\u30eb\u306e\u878d\u70b9<\/h3>\n<p>C2H3ClO \u306e\u878d\u70b9\u306f\u3001\u6a19\u6e96\u5927\u6c17\u5727\u3067 -112.1\u00b0C (-169.8\u00b0F) \u3067\u3059\u3002\u3053\u306e\u305f\u3081\u3001\u63ee\u767a\u6027\u304c\u9ad8\u304f\u53cd\u5fdc\u6027\u306e\u9ad8\u3044\u5316\u5408\u7269\u3068\u306a\u308b\u305f\u3081\u3001\u614e\u91cd\u306a\u53d6\u308a\u6271\u3044\u3068\u4fdd\u7ba1\u304c\u5fc5\u8981\u306b\u306a\u308a\u307e\u3059\u3002<\/p>\n<h3 class=\"wp-block-heading\">\u5869\u5316\u30a2\u30bb\u30c1\u30eb\u306e\u5bc6\u5ea6 g\/mL<\/h3>\n<p>\u5869\u5316\u30a2\u30bb\u30c1\u30eb\u306e\u5bc6\u5ea6\u306f 25\u00b0C (77\u00b0F) \u3067 1.104 g\/mL \u3067\u3059\u3002\u3053\u308c\u306f\u3001C2H3ClO \u306f\u6c34\u3088\u308a\u3082\u5bc6\u5ea6\u304c\u9ad8\u304f\u3001\u6c34\u306b\u6c88\u3080\u3053\u3068\u3092\u610f\u5473\u3057\u307e\u3059\u3002 C2H3ClO \u306e\u5bc6\u5ea6\u306f\u3001\u6240\u5b9a\u306e\u4f53\u7a4d\u306b\u3069\u308c\u3060\u3051\u306e\u7269\u8cea\u3092\u4fdd\u7ba1\u3067\u304d\u308b\u304b\u3001\u307e\u305f\u7269\u8cea\u306e\u53d6\u308a\u6271\u3044\u3068\u4fdd\u7ba1\u306b\u5fc5\u8981\u306a\u9069\u5207\u306a\u5b89\u5168\u5bfe\u7b56\u3092\u6c7a\u5b9a\u3059\u308b\u4e0a\u3067\u91cd\u8981\u3067\u3059\u3002<\/p>\n<h3 class=\"wp-block-heading\">\u5869\u5316\u30a2\u30bb\u30c1\u30eb\u306e\u5206\u5b50\u91cf<\/h3>\n<p>C2H3ClO \u306e\u5206\u5b50\u91cf\u306f 78.50 g\/mol \u3067\u3059\u3002\u3053\u306e\u5024\u306f\u3001\u5316\u5b66\u53cd\u5fdc\u306b\u5fc5\u8981\u306a C2H3ClO \u306e\u91cf\u3092\u6c7a\u5b9a\u3057\u305f\u308a\u3001\u7570\u306a\u308b\u6e2c\u5b9a\u5358\u4f4d\u9593\u3067\u5909\u63db\u3057\u305f\u308a\u3059\u308b\u305f\u3081\u306b\u91cd\u8981\u3067\u3059\u3002 <\/p>\n<div class=\"wp-block-image\">\n<figure class=\"alignright size-large is-resized\"><img decoding=\"async\" loading=\"lazy\" src=\"https:\/\/chemuza.org\/wp-content\/uploads\/2023\/08\/acetyl-cl.jpg\" alt=\"\u5869\u5316\u30a2\u30bb\u30c1\u30eb\" width=\"164\" height=\"105\" srcset=\"\" sizes=\"\"><\/figure>\n<\/div>\n<h3 class=\"wp-block-heading\">\u5869\u5316\u30a2\u30bb\u30c1\u30eb\u306e\u69cb\u9020<\/h3>\n<p>\u5869\u5316\u30a2\u30bb\u30c1\u30eb\u306f\u4e09\u89d2\u5f62\u306e\u5e73\u9762\u5206\u5b50\u69cb\u9020\u3092\u6301\u3061\u3001\u4e2d\u5fc3\u306e\u70ad\u7d20\u539f\u5b50\u304c\u4ed6\u306e 3 \u3064\u306e\u539f\u5b50\u306b\u56f2\u307e\u308c\u3066\u5e73\u9762\u7684\u306a\u4e09\u89d2\u5f62\u306e\u914d\u7f6e\u306b\u306a\u3063\u3066\u3044\u307e\u3059\u3002\u3053\u306e\u5206\u5b50\u306b\u306f\u3001\u70ad\u7d20\u539f\u5b50\u3068\u9178\u7d20\u539f\u5b50\u306e\u9593\u306b C=O \u4e8c\u91cd\u7d50\u5408\u304c\u3042\u308a\u3001\u70ad\u7d20\u539f\u5b50\u3068\u5869\u7d20\u539f\u5b50\u306e\u9593\u306b\u5358\u7d50\u5408\u304c\u3042\u308a\u307e\u3059\u3002 C2H3ClO \u306e\u5206\u5b50\u69cb\u9020\u306b\u3088\u308a\u3001C2H3ClO \u306b\u7279\u6709\u306e\u53cd\u5fdc\u6027\u3068\u5316\u5b66\u7684\u7279\u6027\u304c\u4e0e\u3048\u3089\u308c\u307e\u3059\u3002<\/p>\n<h3 class=\"wp-block-heading\">\u5869\u5316\u30a2\u30bb\u30c1\u30eb\u306e\u914d\u5408<\/h3>\n<p>\u5869\u5316\u30a2\u30bb\u30c1\u30eb\u306e\u5316\u5b66\u5f0f\u306f C2H3ClO \u3067\u3001\u3053\u308c\u306f\u5206\u5b50\u5185\u306e\u539f\u5b50\u306e\u6570\u3068\u7a2e\u985e\u3092\u8868\u3057\u307e\u3059\u3002\u3053\u306e\u5f0f\u306f\u3001\u5316\u5b66\u53cd\u5fdc\u306b\u304a\u3051\u308b\u5316\u5b66\u91cf\u8ad6\u8a08\u7b97\u3084\u5b9f\u9a13\u5ba4\u3067\u306e\u5316\u5408\u7269\u306e\u7279\u5b9a\u306b\u91cd\u8981\u3067\u3059\u3002 C2H3ClO \u306f\u3001\u4e3b\u306b\u6709\u6a5f\u5408\u6210\u306e\u8a66\u85ac\u3068\u3057\u3066\u3001\u307e\u305f\u533b\u85ac\u54c1\u3084\u67d3\u6599\u306e\u88fd\u9020\u3067\u306f\u30a2\u30bb\u30c1\u30eb\u5316\u5264\u3068\u3057\u3066\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002<\/p>\n<figure class=\"wp-block-table\">\n<table>\n<tbody>\n<tr>\n<td>\u5916\u89b3<\/td>\n<td>\u7121\u8272\u306e\u6db2\u4f53<\/td>\n<\/tr>\n<tr>\n<td>\u6bd4\u91cd<\/td>\n<td>1.104 g\/ml\uff0825\u2103\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u8272<\/td>\n<td>\u7121\u8272<\/td>\n<\/tr>\n<tr>\n<td>\u5302\u3044<\/td>\n<td>\u30a8\u30fc\u30ab\u30fc<\/td>\n<\/tr>\n<tr>\n<td>\u30e2\u30eb\u8cea\u91cf<\/td>\n<td>78.50g\/\u30e2\u30eb<\/td>\n<\/tr>\n<tr>\n<td>\u5bc6\u5ea6<\/td>\n<td>1.104 g\/ml\uff0825\u2103\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u878d\u5408\u70b9<\/td>\n<td>-112.1\u2103<\/td>\n<\/tr>\n<tr>\n<td>\u6cb8\u70b9<\/td>\n<td>51.5\u2103<\/td>\n<\/tr>\n<tr>\n<td>\u30d5\u30e9\u30c3\u30b7\u30e5\u30c9\u30c3\u30c8<\/td>\n<td>-26\u2103<\/td>\n<\/tr>\n<tr>\n<td>\u6c34\u3078\u306e\u6eb6\u89e3\u5ea6<\/td>\n<td>\u6c34\u3068\u6fc0\u3057\u304f\u53cd\u5fdc\u3059\u308b<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027<\/td>\n<td>\u307b\u3068\u3093\u3069\u306e\u6709\u6a5f\u6eb6\u5a92\u306b\u53ef\u6eb6<\/td>\n<\/tr>\n<tr>\n<td>\u84b8\u6c17\u5727<\/td>\n<td>25\u2103\u306769.7mmHg<\/td>\n<\/tr>\n<tr>\n<td>\u84b8\u6c17\u5bc6\u5ea6<\/td>\n<td>2.7 (\u7a7a\u6c17=1)<\/td>\n<\/tr>\n<tr>\n<td> pKa<\/td>\n<td> -6.3<\/td>\n<\/tr>\n<tr>\n<td> pH<\/td>\n<td>\u975e\u5e38\u306b\u9178\u6027<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n<h2 class=\"wp-block-heading\"><strong>\u5869\u5316\u30a2\u30bb\u30c1\u30eb\u306e\u5b89\u5168\u6027\u3068\u5371\u967a\u6027<\/strong><\/h2>\n<p>C2H3ClO \u306f\u53cd\u5fdc\u6027\u304c\u9ad8\u304f\u3001\u4eba\u9593\u306e\u5065\u5eb7\u3068\u5b89\u5168\u306b\u91cd\u5927\u306a\u30ea\u30b9\u30af\u3092\u3082\u305f\u3089\u3059\u5371\u967a\u306a\u7269\u8cea\u3067\u3059\u3002\u3053\u308c\u306f\u8150\u98df\u6027\u3067\u6709\u6bd2\u306a\u7269\u8cea\u3067\u3042\u308a\u3001\u66b4\u9732\u3055\u308c\u308b\u3068\u91cd\u5ea6\u306e\u76ae\u819a\u306e\u706b\u50b7\u3001\u76ee\u306e\u640d\u50b7\u3001\u547c\u5438\u5668\u3078\u306e\u708e\u75c7\u3092\u5f15\u304d\u8d77\u3053\u3059\u53ef\u80fd\u6027\u304c\u3042\u308a\u307e\u3059\u3002\u5869\u5316\u30a2\u30bb\u30c1\u30eb\u306f\u6c34\u3068\u6fc0\u3057\u304f\u53cd\u5fdc\u3057\u3066\u3001\u547c\u5438\u5668\u3078\u306e\u523a\u6fc0\u7269\u3067\u3042\u308b\u5869\u9178\u30ac\u30b9\u3092\u751f\u6210\u3059\u308b\u3053\u3068\u3082\u3042\u308a\u307e\u3059\u3002 C2H3ClO \u306e\u53d6\u308a\u6271\u3044\u306b\u306f\u7d30\u5fc3\u306e\u6ce8\u610f\u3092\u6255\u3044\u3001\u9069\u5207\u306a\u500b\u4eba\u7528\u4fdd\u8b77\u5177\u3092\u7740\u7528\u3057\u3001\u63db\u6c17\u306e\u826f\u3044\u5834\u6240\u3067\u306e\u307f\u4f7f\u7528\u3059\u308b\u3053\u3068\u304c\u91cd\u8981\u3067\u3059\u3002\u4e8b\u6545\u3092\u9632\u6b62\u3057\u3001\u3053\u306e\u7269\u8cea\u3092\u5b89\u5168\u306b\u53d6\u308a\u6271\u3046\u305f\u3081\u306b\u306f\u3001\u9069\u5207\u306a\u4fdd\u7ba1\u3001\u30e9\u30d9\u30eb\u8cbc\u4ed8\u3001\u8f38\u9001\u3082\u4e0d\u53ef\u6b20\u3067\u3059\u3002<\/p>\n<figure class=\"wp-block-table\">\n<table>\n<tbody>\n<tr>\n<td>\u30cf\u30b6\u30fc\u30c9\u30b7\u30f3\u30dc\u30eb<\/td>\n<td>\u8150\u98df\u6027\u3001\u6709\u6bd2\u6027<\/td>\n<\/tr>\n<tr>\n<td>\u30bb\u30ad\u30e5\u30ea\u30c6\u30a3\u306e\u8aac\u660e<\/td>\n<td>\u84b8\u6c17\u3092\u5438\u3044\u8fbc\u307e\u306a\u3044\u3067\u304f\u3060\u3055\u3044\u3002\u4fdd\u8b77\u624b\u888b\u3068\u76ee\/\u9854\u306e\u4fdd\u8b77\u5177\u3092\u7740\u7528\u3057\u3066\u304f\u3060\u3055\u3044\u3002\u706b\u707d\u304c\u767a\u751f\u3057\u305f\u5834\u5408\u306f\u3001CO2\u3001\u7c89\u672b\u6d88\u706b\u5668\u3001\u307e\u305f\u306f\u6ce1\u6d88\u706b\u5668\u3092\u4f7f\u7528\u3057\u3066\u304f\u3060\u3055\u3044\u3002<\/td>\n<\/tr>\n<tr>\n<td> AN\u8b58\u5225\u5b50<\/td>\n<td>UN1717<\/td>\n<\/tr>\n<tr>\n<td> HS\u30b3\u30fc\u30c9<\/td>\n<td>2915.90.9000<\/td>\n<\/tr>\n<tr>\n<td>\u5371\u967a\u7b49\u7d1a<\/td>\n<td>8<\/td>\n<\/tr>\n<tr>\n<td>\u68b1\u5305\u30b0\u30eb\u30fc\u30d7<\/td>\n<td>\u2161<\/td>\n<\/tr>\n<tr>\n<td>\u6bd2\u6027<\/td>\n<td>\u975e\u5e38\u306b\u6709\u6bd2\u3067\u8150\u98df\u6027\u304c\u3042\u308a\u307e\u3059\u3002\u91cd\u7be4\u306a\u76ae\u819a\u3084\u76ee\u306e\u706b\u50b7\u3092\u5f15\u304d\u8d77\u3053\u3057\u307e\u3059\u3002\u5438\u3044\u8fbc\u3093\u3060\u308a\u98f2\u307f\u8fbc\u3093\u3060\u308a\u3059\u308b\u3068\u81f4\u547d\u7684\u306a\u5371\u967a\u304c\u3042\u308a\u307e\u3059\u3002<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n<h2 class=\"wp-block-heading\"><strong><br \/>\u5869\u5316\u30a2\u30bb\u30c1\u30eb\u306e\u5408\u6210\u65b9\u6cd5<\/strong><\/h2>\n<p>C2H3ClO \u306f\u3001\u9162\u9178\u3068\u5869\u5316\u30c1\u30aa\u30cb\u30eb\u3001\u4e09\u5869\u5316\u30ea\u30f3\u3001\u307e\u305f\u306f\u4e94\u5869\u5316\u30ea\u30f3<a href=\"https:\/\/chemuza.org\/ja\/\u6c37\u9162\u9178\/\">\u3092<\/a>\u53cd\u5fdc\u3055\u305b\u308b\u3053\u3068\u306b\u3088\u3063\u3066\u751f\u6210\u3055\u308c\u307e\u3059\u3002\u3053\u308c\u3089\u306e\u65b9\u6cd5\u306b\u306f\u3001\u53cd\u5fdc\u6027\u304c\u9ad8\u304f\u5371\u967a\u306a\u8a66\u85ac\u304c\u4f7f\u7528\u3055\u308c\u308b\u305f\u3081\u3001\u7d30\u5fc3\u306e\u6ce8\u610f\u3092\u6255\u3063\u3066\u4f7f\u7528\u3059\u308b\u5fc5\u8981\u304c\u3042\u308a\u307e\u3059\u3002<\/p>\n<p> C2H3ClO \u3092\u5408\u6210\u3059\u308b\u6700\u3082\u4e00\u822c\u7684\u306a\u65b9\u6cd5\u306b\u306f\u3001<a 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href=\"https:\/\/chemuza.org\/ja\/\u6c37\u9162\u9178\/\">\u9162\u9178<\/a>\u3068\u4e09\u5869\u5316\u30ea\u30f3\u307e\u305f\u306f\u4e94\u5869\u5316\u30ea\u30f3\u3068\u306e\u53cd\u5fdc\u304c\u542b\u307e\u308c\u307e\u3059\u3002\u3053\u306e\u65b9\u6cd5\u3067\u306f\u3001\u9162\u9178\u3068\u4e09\u5869\u5316\u30ea\u30f3\u307e\u305f\u306f\u4e94\u5869\u5316\u30ea\u30f3\u3092\u6df7\u5408\u3057\u3001\u52a0\u71b1\u3057\u3066\u53cd\u5fdc\u3092\u958b\u59cb\u3057\u307e\u3059\u3002\u3053\u306e\u53cd\u5fdc\u306b\u3088\u308a\u3001\u526f\u751f\u6210\u7269\u3068\u3057\u3066 C2H3ClO 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c2h3clo\u300175-36-5\">\u7d9a\u304d\u3092\u8aad\u3080<\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[5],"tags":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v21.4 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>\u5869\u5316\u30a2\u30bb\u30c1\u30eb - C2H3ClO\u300175-36-5<\/title>\n<meta name=\"description\" content=\"\u5869\u5316\u30a2\u30bb\u30c1\u30eb\u307e\u305f\u306f C2H3ClO \u306f\u3001\u523a\u6fc0\u81ed\u306e\u3042\u308b\u7121\u8272\u306e\u767a\u7159\u6db2\u4f53\u3067\u3059\u3002\u4e3b\u306b\u6709\u6a5f\u5408\u6210\u306e\u8a66\u85ac\u3068\u3057\u3066\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" 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