{"id":458,"date":"2023-07-23T06:24:23","date_gmt":"2023-07-23T06:24:23","guid":{"rendered":"https:\/\/chemuza.org\/ja\/hsbf6%e3%83%95%e3%83%ab%e3%82%aa%e3%83%ad%e3%82%a2%e3%83%b3%e3%83%81%e3%83%a2%e3%83%b3%e9%85%b8\/"},"modified":"2023-07-23T06:24:23","modified_gmt":"2023-07-23T06:24:23","slug":"hsbf6%e3%83%95%e3%83%ab%e3%82%aa%e3%83%ad%e3%82%a2%e3%83%b3%e3%83%81%e3%83%a2%e3%83%b3%e9%85%b8","status":"publish","type":"post","link":"https:\/\/chemuza.org\/ja\/hsbf6%e3%83%95%e3%83%ab%e3%82%aa%e3%83%ad%e3%82%a2%e3%83%b3%e3%83%81%e3%83%a2%e3%83%b3%e9%85%b8\/","title":{"rendered":"\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178 \u2013 hsbf6"},"content":{"rendered":"

\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306f\u3001\u77e5\u3089\u308c\u3066\u3044\u308b\u4e2d\u3067\u6700\u3082\u5f37\u529b\u306a\u8d85\u9178\u306e 1 \u3064\u3067\u3001\u30cf\u30e1\u30c3\u30c8\u9178\u5ea6\u95a2\u6570\u306f -21 \u3067\u3059\u3002\u30d5\u30c3\u5316\u6c34\u7d20\u3068\u4e94\u30d5\u30c3\u5316\u30a2\u30f3\u30c1\u30e2\u30f3\u306e\u6df7\u5408\u7269\u3067\u3059\u3002<\/p>\n

\n\n\n\n\n\n\n\n
IUPAC\u540d<\/td>\n\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178(V)<\/td>\n<\/tr>\n
\u5206\u5b50\u5f0f<\/td>\nH[SbF6]<\/td>\n<\/tr>\n
CAS\u756a\u53f7<\/td>\n16950-06-4<\/td>\n<\/tr>\n
\u540c\u7fa9\u8a9e<\/td>\n\u516d\u30d5\u30c3\u5316\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u6c34\u7d20(V)\u3001\u516d\u30d5\u30c3\u5316\u30a2\u30f3\u30c1\u30e2\u30f3\u6c34\u548c\u7269\u3001\u30d5\u30c3\u5316\u6c34\u7d20\u30a2\u30f3\u30c1\u30e2\u30f3\u3001\u4e94\u30d5\u30c3\u5316\u30a2\u30f3\u30c1\u30e2\u30f3\u3092\u542b\u3080\u30d5\u30c3\u5316\u6c34\u7d20\u9178(1:1)<\/td>\n<\/tr>\n
\u30a4\u30f3\u30c1\u30c1<\/td>\nInChI=1S\/F6Sb.H\/h1H;\/q+1;\/p-1<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n
\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306epH<\/h6>\n

\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306f\u8d85\u9178\u3067\u3042\u308a\u3001pH \u306f -14 \u672a\u6e80\u3067\u3059\u3002\u3053\u308c\u306f\u3001pH \u30b9\u30b1\u30fc\u30eb\u306f\u6eb6\u6db2\u4e2d\u306e\u6c34\u7d20\u30a4\u30aa\u30f3 (H+) \u306e\u6fc3\u5ea6\u3092\u6e2c\u5b9a\u3059\u308b\u3082\u306e\u3067\u3042\u308a\u3001\u8d85\u9178\u306b\u306f\u7d14\u6c34\u3088\u308a\u3082 H+ \u30a4\u30aa\u30f3\u306e\u6fc3\u5ea6\u304c\u9ad8\u3044\u305f\u3081\u3067\u3059\u3002<\/p>\n

\u5f93\u6765\u306e pH \u30e1\u30fc\u30bf\u30fc\u306f\u3001\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306e\u3088\u3046\u306a\u5f37\u9178\u3092\u6271\u3046\u3088\u3046\u306b\u8a2d\u8a08\u3055\u308c\u3066\u3044\u306a\u3044\u305f\u3081\u3001\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306e pH \u3092\u6b63\u78ba\u306b\u6e2c\u5b9a\u3067\u304d\u307e\u305b\u3093\u3002\u4ee3\u308f\u308a\u306b\u3001\u79d1\u5b66\u8005\u306f\u30cf\u30e1\u30c3\u30c8\u306e\u9178\u6027\u5ea6\u95a2\u6570\u3092\u4f7f\u7528\u3057\u3066\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306e\u9178\u6027\u5ea6\u3092\u6e2c\u5b9a\u3057\u307e\u3059\u3002\u30cf\u30e1\u30c3\u30c8\u9178\u6027\u5ea6\u95a2\u6570\u306f\u3001\u53c2\u7167\u5316\u5408\u7269\u306e\u30d7\u30ed\u30c8\u30f3\u5316\u5ea6\u3092\u4f7f\u7528\u3057\u3066\u8d85\u9178\u306e\u9178\u6027\u5ea6\u3092\u6bd4\u8f03\u3057\u307e\u3059\u3002\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306e\u30cf\u30e1\u30c3\u30c8\u9178\u5ea6\u95a2\u6570\u306f -21 \u3067\u3001\u3053\u308c\u306f\u53ef\u80fd\u306a\u9650\u308a\u6700\u3082\u8ca0\u306e\u5024\u3067\u3042\u308a\u3001\u65e2\u77e5\u306e\u8d85\u9178\u306e\u4e2d\u3067\u6700\u3082\u5f37\u529b\u306a\u3082\u306e\u306e 1 \u3064\u3067\u3042\u308b\u3053\u3068\u3092\u793a\u3057\u3066\u3044\u307e\u3059\u3002 <\/p>\n

\n
\"\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\"<\/figure>\n<\/div>\n
\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306e\u69cb\u9020:<\/h6>\n

\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306f\u3001\u6c34\u7d20\u30a4\u30aa\u30f3 (H+) \u3068\u30d8\u30ad\u30b5\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178 (V) \u30a4\u30aa\u30f3 ([SbF6]^-) \u304b\u3089\u306a\u308b\u5206\u5b50\u69cb\u9020\u3092\u6301\u3063\u3066\u3044\u307e\u3059\u3002 SbF6 \u30a4\u30aa\u30f3\u306f\u30eb\u30a4\u30b9\u9178\u3068\u3057\u3066\u4f5c\u7528\u3057\u3001H+ \u30a4\u30aa\u30f3\u306f\u30d6\u30ec\u30f3\u30b9\u30c6\u30c3\u30c9\u9178\u3068\u3057\u3066\u4f5c\u7528\u3057\u307e\u3059\u3002\u3053\u306e\u5316\u5408\u7269\u306f\u3001\u6c34\u7d20\u539f\u5b50\u3068\u30d5\u30c3\u7d20\u539f\u5b50\u306e\u96fb\u6c17\u9670\u6027\u5ea6\u306e\u9055\u3044\u306b\u3088\u308a\u6975\u6027\u304c\u9ad8\u304f\u306a\u308a\u307e\u3059\u3002\u30a2\u30f3\u30c1\u30e2\u30f3\u3068\u30d5\u30c3\u5316\u7269\u306e\u7d50\u5408\u306f\u5171\u6709\u7d50\u5408\u3067\u3059\u304c\u3001\u6c34\u7d20\u3068\u30d5\u30c3\u5316\u7269\u306e\u7d50\u5408\u306f\u6975\u6027\u5171\u6709\u7d50\u5408\u3067\u3059\u3002<\/p>\n

\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306e\u30e2\u30eb\u8cea\u91cf:<\/h6>\n

\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306e\u30e2\u30eb\u8cea\u91cf\u306f 216.74 g\/mol \u3067\u3059\u3002\u3053\u308c\u306f\u3001\u30d5\u30c3\u5316\u6c34\u7d20 (HF) \u3068\u4e94\u30d5\u30c3\u5316\u30a2\u30f3\u30c1\u30e2\u30f3 (SbF5) \u304b\u3089\u69cb\u6210\u3055\u308c\u308b\u3001\u53cd\u5fdc\u6027\u304c\u9ad8\u304f\u8150\u98df\u6027\u306e\u9ad8\u3044\u8d85\u9178\u3067\u3059\u3002\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306e\u5206\u5b50\u91cf\u304c\u5927\u304d\u3044\u306e\u306f\u3001\u305d\u306e\u5206\u5b50\u69cb\u9020\u4e2d\u306b\u30a2\u30f3\u30c1\u30e2\u30f3\u306e\u91cd\u539f\u5b50\u304c\u5b58\u5728\u3059\u308b\u3053\u3068\u306b\u8d77\u56e0\u3059\u308b\u3068\u8003\u3048\u3089\u308c\u307e\u3059\u3002<\/p>\n

\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306e\u6cb8\u70b9:<\/h6>\n

HSbF6 \u306f\u53cd\u5fdc\u6027\u304c\u9ad8\u304f\u4e0d\u5b89\u5b9a\u306a\u5316\u5408\u7269\u3067\u3042\u308b\u305f\u3081\u3001\u5b9a\u7fa9\u3055\u308c\u305f\u6cb8\u70b9\u304c\u3042\u308a\u307e\u305b\u3093\u3002 -10\u2103\u4ee5\u4e0a\u306e\u6e29\u5ea6\u3067\u5206\u89e3\u3057\u3001\u30d5\u30c3\u5316\u6c34\u7d20\u30ac\u30b9\u306e\u6709\u6bd2\u306a\u30d5\u30e5\u30fc\u30e0\u3092\u653e\u51fa\u3057\u307e\u3059\u3002\u305d\u306e\u6cb8\u70b9\u306f\u7d04 20 \uff5e 30\u00b0C \u3068\u63a8\u5b9a\u3055\u308c\u3066\u3044\u307e\u3059\u304c\u3001\u3053\u308c\u306f HSbF6 \u306e\u7279\u6027\u3092\u8aac\u660e\u3059\u308b\u306e\u306b\u6709\u7528\u306a\u30d1\u30e9\u30e1\u30fc\u30bf\u30fc\u3067\u306f\u3042\u308a\u307e\u305b\u3093\u3002<\/p>\n

\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306e\u878d\u70b9:<\/h6>\n

HSbF6 \u306f\u53cd\u5fdc\u6027\u304c\u9ad8\u3044\u305f\u3081\u3001\u660e\u78ba\u306b\u5b9a\u7fa9\u3055\u308c\u305f\u878d\u70b9\u304c\u3042\u308a\u307e\u305b\u3093\u3002\u6db2\u4f53\u72b6\u614b\u3067\u306e\u307f\u5b58\u5728\u3067\u304d\u3001\u4f4e\u6e29\u306b\u51b7\u5374\u3059\u308b\u3068\u6025\u901f\u306b\u5206\u89e3\u3057\u307e\u3059\u3002 -90\u2103\u4ed8\u8fd1\u3067\u5206\u89e3\u3057\u3001\u30d5\u30c3\u5316\u6c34\u7d20\u3068\u4e94\u30d5\u30c3\u5316\u30a2\u30f3\u30c1\u30e2\u30f3\u306e\u6709\u6bd2\u306a\u30d5\u30e5\u30fc\u30e0\u3092\u653e\u51fa\u3059\u308b\u3068\u63a8\u5b9a\u3055\u308c\u3066\u3044\u307e\u3059\u3002<\/p>\n

\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306e\u5bc6\u5ea6 g\/ml:<\/h6>\n

HSbF6 \u306e\u5bc6\u5ea6\u306f 2.1 g\/mL \u3067\u3059\u3002\u3053\u306e\u9ad8\u5bc6\u5ea6\u306f\u3001\u305d\u306e\u5206\u5b50\u69cb\u9020\u4e2d\u306b\u91cd\u3044\u30a2\u30f3\u30c1\u30e2\u30f3\u539f\u5b50\u304c\u5b58\u5728\u3059\u308b\u3053\u3068\u306b\u8d77\u56e0\u3059\u308b\u3068\u8003\u3048\u3089\u308c\u307e\u3059\u3002\u3053\u308c\u306f\u8150\u98df\u6027\u3068\u53cd\u5fdc\u6027\u304c\u975e\u5e38\u306b\u9ad8\u3044\u5316\u5408\u7269\u3067\u3042\u308b\u305f\u3081\u3001\u53d6\u308a\u6271\u3044\u306b\u306f\u7d30\u5fc3\u306e\u6ce8\u610f\u304c\u5fc5\u8981\u3067\u3059\u3002 HSbF6 \u306f\u5bc6\u5ea6\u304c\u9ad8\u3044\u305f\u3081\u3001\u5b9f\u9a13\u5ba4\u3067\u306e\u53d6\u308a\u6271\u3044\u3082\u56f0\u96e3\u306b\u306a\u308a\u307e\u3059\u3002<\/p>\n

\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306e\u5206\u5b50\u91cf:<\/h6>\n

\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306e\u5206\u5b50\u91cf\u306f 236.76 g\/mol \u3067\u3059\u3002\u6c34\u7d20\u30a4\u30aa\u30f3 1 \u500b\u3001\u30a2\u30f3\u30c1\u30e2\u30f3\u30a4\u30aa\u30f3 1 \u500b\u3001\u30d5\u30c3\u5316\u7269\u30a4\u30aa\u30f3 6 \u500b\u3067\u69cb\u6210\u3055\u308c\u3066\u3044\u307e\u3059\u3002\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306e\u9ad8\u5206\u5b50\u91cf\u306f\u3001\u305d\u306e\u5206\u5b50\u69cb\u9020\u4e2d\u306b\u30a2\u30f3\u30c1\u30e2\u30f3\u306e\u91cd\u539f\u5b50\u304c\u5b58\u5728\u3059\u308b\u3053\u3068\u306b\u8d77\u56e0\u3059\u308b\u3068\u8003\u3048\u3089\u308c\u307e\u3059\u3002<\/p>\n

\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306e\u5f0f:<\/h6>\n

\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306e\u5316\u5b66\u5f0f\u306f H[SbF6] \u3067\u3059\u3002\u6c34\u7d20\u30a4\u30aa\u30f3 (H+) \u3068\u30d8\u30ad\u30b5\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178 (V) \u30a4\u30aa\u30f3 ([SbF6]^-) \u3067\u69cb\u6210\u3055\u308c\u307e\u3059\u3002 [SbF6]4- \u30a4\u30aa\u30f3\u306f\u3001\u4e94\u30d5\u30c3\u5316\u30a2\u30f3\u30c1\u30e2\u30f3 (SbF5) \u3068\u30d5\u30c3\u5316\u6c34\u7d20 (HF) \u306e\u53cd\u5fdc\u306b\u3088\u3063\u3066\u5f62\u6210\u3055\u308c\u307e\u3059\u3002\u3053\u306e\u5f0f\u306f\u3001\u5316\u5408\u7269\u306b\u5b58\u5728\u3059\u308b\u539f\u5b50\u306e\u6700\u3082\u5358\u7d14\u306a\u6574\u6570\u6bd4\u3092\u8868\u3057\u307e\u3059\u3002<\/p>\n

\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n
\u5916\u89b3<\/td>\n\u7121\u8272\uff5e\u6de1\u9ec4\u8272\u306e\u6db2\u4f53<\/td>\n<\/tr>\n
\u6bd4\u91cd<\/td>\n2.1g\/ml<\/td>\n<\/tr>\n
\u8272<\/td>\n\u7121\u8272\uff5e\u6de1\u9ec4\u8272<\/td>\n<\/tr>\n
\u5302\u3044<\/td>\n\u7121\u81ed<\/td>\n<\/tr>\n
\u30e2\u30eb\u8cea\u91cf<\/td>\n236.76 g\/\u30e2\u30eb<\/td>\n<\/tr>\n
\u5bc6\u5ea6<\/td>\n2.1g\/ml<\/td>\n<\/tr>\n
\u878d\u5408\u70b9<\/td>\n-90\u2103\u4ed8\u8fd1\u3067\u5206\u89e3\u3059\u308b<\/td>\n<\/tr>\n
\u6cb8\u70b9<\/td>\n-10\u2103\u4ee5\u4e0a\u3067\u5206\u89e3\u3059\u308b<\/td>\n<\/tr>\n
\u30d5\u30e9\u30c3\u30b7\u30e5\u30c9\u30c3\u30c8<\/td>\n\u9069\u7528\u3067\u304d\u306a\u3044<\/td>\n<\/tr>\n
\u6c34\u3078\u306e\u6eb6\u89e3\u5ea6<\/td>\n\u6c34\u3068\u6fc0\u3057\u304f\u53cd\u5fdc\u3059\u308b<\/td>\n<\/tr>\n
\u6eb6\u89e3\u6027<\/td>\n\u7121\u6c34HF\u3001SbF5\u3001SO2F2\u3001SO2ClF\u306b\u53ef\u6eb6<\/td>\n<\/tr>\n
\u84b8\u6c17\u5727<\/td>\n\u9069\u7528\u3067\u304d\u306a\u3044<\/td>\n<\/tr>\n
\u84b8\u6c17\u5bc6\u5ea6<\/td>\n\u9069\u7528\u3067\u304d\u306a\u3044<\/td>\n<\/tr>\n
PKa<\/td>\n -21 (\u30cf\u30e1\u30c3\u30c8\u9178\u5ea6\u95a2\u6570)<\/td>\n<\/tr>\n
pH<\/td>\n -14\u672a\u6e80<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n

\u6ce8: \u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306f\u53cd\u5fdc\u6027\u304c\u9ad8\u304f\u8150\u98df\u6027\u306e\u9ad8\u3044\u5316\u5408\u7269\u3067\u3042\u308b\u305f\u3081\u3001\u53d6\u308a\u6271\u3044\u306b\u306f\u7d30\u5fc3\u306e\u6ce8\u610f\u304c\u5fc5\u8981\u3067\u3059\u3002\u305d\u306e\u4e0d\u5b89\u5b9a\u306a\u6027\u8cea\u3068\u305d\u306e\u64cd\u4f5c\u306b\u5229\u7528\u3067\u304d\u308b\u65b9\u6cd5\u304c\u9650\u3089\u308c\u3066\u3044\u308b\u305f\u3081\u3001\u305d\u306e\u7269\u7406\u7684\u304a\u3088\u3073\u5316\u5b66\u7684\u7279\u6027\u3092\u6b63\u78ba\u306b\u6e2c\u5b9a\u3059\u308b\u3053\u3068\u306f\u56f0\u96e3\u3067\u3059\u3002\u3053\u306e\u8868\u306b\u8a18\u8f09\u3055\u308c\u3066\u3044\u308b\u5024\u306f\u5165\u624b\u53ef\u80fd\u306a\u6587\u732e\u306b\u57fa\u3065\u3044\u305f\u63a8\u5b9a\u5024\u3067\u3042\u308a\u3001\u6b63\u78ba\u3067\u306f\u306a\u3044\u5834\u5408\u304c\u3042\u308a\u307e\u3059\u3002<\/p>\n


\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306e\u5b89\u5168\u6027\u3068\u5371\u967a\u6027<\/strong><\/h5>\n

\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306f\u975e\u5e38\u306b\u5371\u967a\u3067\u8150\u98df\u6027\u306e\u9ad8\u3044\u7269\u8cea\u3067\u3042\u308a\u3001\u5065\u5eb7\u3068\u5b89\u5168\u306b\u91cd\u5927\u306a\u30ea\u30b9\u30af\u3092\u3082\u305f\u3089\u3057\u307e\u3059\u3002\u3053\u308c\u306f\u3001\u6c34\u3001\u6709\u6a5f\u5316\u5408\u7269\u3001\u3055\u3089\u306b\u306f\u4e00\u90e8\u306e\u91d1\u5c5e\u3068\u6fc0\u3057\u304f\u53cd\u5fdc\u3059\u308b\u5f37\u529b\u306a\u9178\u5316\u5264\u3067\u3059\u3002\u76ae\u819a\u3084\u76ee\u306b\u63a5\u89e6\u3059\u308b\u3068\u91cd\u5ea6\u306e\u706b\u50b7\u3084\u7d44\u7e54\u640d\u50b7\u3092\u5f15\u304d\u8d77\u3053\u3059\u53ef\u80fd\u6027\u304c\u3042\u308a\u3001\u84b8\u6c17\u3092\u5438\u5165\u3059\u308b\u3068\u547c\u5438\u56f0\u96e3\u3084\u80ba\u640d\u50b7\u3092\u5f15\u304d\u8d77\u3053\u3059\u53ef\u80fd\u6027\u304c\u3042\u308a\u307e\u3059\u3002<\/p>\n

\u8a13\u7df4\u3092\u53d7\u3051\u305f\u62c5\u5f53\u8005\u306f\u3001\u63db\u6c17\u304c\u826f\u304f\u9069\u5207\u306b\u8a2d\u5099\u304c\u6574\u3063\u305f\u5b9f\u9a13\u5ba4\u3067\u3001\u7279\u6b8a\u306a\u88c5\u7f6e\u3068\u9632\u8b77\u670d\u3092\u4f7f\u7528\u3057\u3066\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u3092\u53d6\u308a\u6271\u3046\u5fc5\u8981\u304c\u3042\u308a\u307e\u3059\u3002\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306f\u91cd\u50b7\u3084\u74b0\u5883\u7834\u58ca\u3092\u5f15\u304d\u8d77\u3053\u3059\u53ef\u80fd\u6027\u304c\u3042\u308b\u305f\u3081\u3001\u898f\u5236\u5f53\u5c40\u306f\u305d\u306e\u4f7f\u7528\u3092\u53b3\u3057\u304f\u898f\u5236\u3057\u3001\u5236\u9650\u3057\u3066\u3044\u307e\u3059\u3002<\/p>\n

\n\n\n\n\n\n\n\n\n\n
\u30cf\u30b6\u30fc\u30c9\u30b7\u30f3\u30dc\u30eb<\/td>\n\u8150\u98df\u6027<\/td>\n<\/tr>\n
\u30bb\u30ad\u30e5\u30ea\u30c6\u30a3\u306e\u8aac\u660e<\/td>\n\u84b8\u6c17\u3092\u5438\u3044\u8fbc\u307e\u306a\u3044\u3067\u304f\u3060\u3055\u3044\u3002\u624b\u888b\u3001\u8863\u985e\u3001\u76ee\/\u9854\u3092\u4fdd\u8b77\u3059\u308b\u3082\u306e\u3092\u7740\u7528\u3057\u3066\u304f\u3060\u3055\u3044\u3002\u76ae\u819a\u3001\u76ee\u3001\u8863\u985e\u3068\u306e\u63a5\u89e6\u3092\u907f\u3051\u3066\u304f\u3060\u3055\u3044\u3002\u5316\u5b66\u30d5\u30fc\u30c9\u306e\u4e0b\u3067\u306e\u307f\u4f7f\u7528\u3057\u3066\u304f\u3060\u3055\u3044\u3002<\/td>\n<\/tr>\n
\u56fd\u9023\u8b58\u5225\u756a\u53f7<\/td>\nUN3264<\/td>\n<\/tr>\n
HS\u30b3\u30fc\u30c9<\/td>\n28111990<\/td>\n<\/tr>\n
\u5371\u967a\u7b49\u7d1a<\/td>\n8 (\u8150\u98df\u6027\u7269\u8cea)<\/td>\n<\/tr>\n
\u68b1\u5305\u30b0\u30eb\u30fc\u30d7<\/td>\n\u2162<\/td>\n<\/tr>\n
\u6bd2\u6027<\/td>\n\u975e\u5e38\u306b\u6709\u6bd2\u3067\u8150\u98df\u6027\u304c\u3042\u308a\u307e\u3059\u3002\u76ae\u819a\u3084\u76ee\u306b\u63a5\u89e6\u3059\u308b\u3068\u91cd\u5ea6\u306e\u706b\u50b7\u3084\u7d44\u7e54\u640d\u50b7\u3092\u5f15\u304d\u8d77\u3053\u3059\u53ef\u80fd\u6027\u304c\u3042\u308a\u3001\u305d\u306e\u84b8\u6c17\u3092\u5438\u5165\u3059\u308b\u3068\u547c\u5438\u56f0\u96e3\u3084\u80ba\u640d\u50b7\u3092\u5f15\u304d\u8d77\u3053\u3059\u53ef\u80fd\u6027\u304c\u3042\u308a\u307e\u3059\u3002<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n

\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306e\u5408\u6210\u65b9\u6cd5<\/strong><\/h5>\n

\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178 (HSbF6) \u306f\u3001\u901a\u5e38\u3001\u30d5\u30c3\u5316\u6c34\u7d20 (HF) \u3068\u4e94\u30d5\u30c3\u5316\u30a2\u30f3\u30c1\u30e2\u30f3 (SbF5) \u3092\u30e2\u30eb\u6bd4 1:1 \u3067\u6df7\u5408\u3059\u308b\u3053\u3068\u306b\u3088\u3063\u3066\u5408\u6210\u3055\u308c\u307e\u3059\u3002\u53cd\u5fdc\u306f\u3001\u751f\u6210\u3059\u308b\u8d85\u9178\u306e\u5206\u89e3\u3092\u9632\u3050\u305f\u3081\u306b\u3001\u7121\u6c34\u6761\u4ef6\u4e0b\u304b\u3064\u4f4e\u6e29\u3067\u884c\u308f\u308c\u307e\u3059\u3002\u5168\u4f53\u7684\u306a\u53cd\u5fdc\u306f\u6b21\u306e\u3088\u3046\u306b\u8868\u3059\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002<\/p>\n

HF + SbF5 \u2192 HSbF6<\/p>\n

\u3053\u306e\u53cd\u5fdc\u306f\u767a\u71b1\u6027\u304c\u9ad8\u304f\u3001\u5927\u91cf\u306e\u71b1\u3092\u653e\u51fa\u3059\u308b\u53ef\u80fd\u6027\u304c\u3042\u308a\u307e\u3059\u3002\u3057\u305f\u304c\u3063\u3066\u3001\u901a\u5e38\u306f\u3001\u9069\u5207\u306a\u4fdd\u8b77\u624b\u6bb5\u3092\u4f7f\u7528\u3057\u3066\u3001\u5316\u5b66\u63db\u6c17\u30d5\u30fc\u30c9\u306a\u3069\u306e\u5341\u5206\u306b\u63db\u6c17\u3055\u308c\u5236\u5fa1\u3055\u308c\u305f\u74b0\u5883\u3067\u5b9f\u884c\u3055\u308c\u307e\u3059\u3002<\/p>\n

HSbF6 \u3092\u8abf\u88fd\u3059\u308b\u306b\u306f\u3001SbF5 \u3084\u4e8c\u30d5\u30c3\u5316\u4e8c\u9178\u5316\u786b\u9ec4 (SO2F2) \u306a\u3069\u306e\u9178\u5316\u5264\u306e\u5b58\u5728\u4e0b\u3067\u4e09\u30d5\u30c3\u5316\u30a2\u30f3\u30c1\u30e2\u30f3 (SbF3) \u3092 HF \u3068\u53cd\u5fdc\u3055\u305b\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002\u3053\u306e\u53cd\u5fdc\u306b\u306f\u7121\u6c34\u6761\u4ef6\u3068\u4f4e\u6e29\u304c\u5fc5\u8981\u3067\u3059\u3002\u53cd\u5fdc\u306f\u6b21\u306e\u3088\u3046\u306b\u8868\u73fe\u3067\u304d\u307e\u3059\u3002<\/p>\n

SbF3 + 3HF + SO2F2 \u2192 HSbF6 + SO2<\/p>\n

HSbF6 \u306f\u53cd\u5fdc\u6027\u304c\u9ad8\u304f\u4e0d\u5b89\u5b9a\u306a\u5316\u5408\u7269\u3067\u3042\u308b\u305f\u3081\u3001\u7279\u5225\u306a\u53d6\u308a\u6271\u3044\u3068\u4fdd\u7ba1\u304c\u5fc5\u8981\u3067\u3059\u3002\u901a\u5e38\u3001\u5206\u89e3\u3092\u9632\u3050\u305f\u3081\u3001\u5bc6\u5c01\u3055\u308c\u305f\u6c17\u5bc6\u5bb9\u5668\u306b\u5165\u308c\u3001\u7121\u6c34\u6761\u4ef6\u4e0b\u3067\u4f4e\u6e29\u3067\u4fdd\u7ba1\u3055\u308c\u307e\u3059\u3002 HSbF6 \u306f\u6bd2\u6027\u3068\u8150\u98df\u6027\u304c\u9ad8\u3044\u305f\u3081\u3001HSbF6 \u3092\u6271\u3046\u5834\u5408\u306f\u9069\u5207\u306a\u5b89\u5168\u5bfe\u7b56\u3068\u4fdd\u8b77\u5177\u304c\u4e0d\u53ef\u6b20\u3067\u3059\u3002<\/p>\n

\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306e\u7528\u9014<\/strong><\/h5>\n

\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178 (HSbF6) \u306f\u3001\u6700\u3082\u5f37\u529b\u306a\u65e2\u77e5\u306e\u8d85\u9178\u306e 1 \u3064\u3067\u3042\u308a\u3001\u5e45\u5e83\u3044\u7523\u696d\u304a\u3088\u3073\u7814\u7a76\u7528\u9014\u306b\u4f7f\u7528\u3055\u308c\u3066\u3044\u307e\u3059\u3002\u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306e\u7528\u9014\u306e\u4e00\u90e8\u3092\u6b21\u306b\u793a\u3057\u307e\u3059\u3002<\/p>\n

    \n
  1. HSbF6 \u306f\u3001\u30a2\u30eb\u30ad\u30eb\u5316\u3001\u7570\u6027\u5316\u3001\u91cd\u5408\u306a\u3069\u306e\u3055\u307e\u3056\u307e\u306a\u5316\u5b66\u53cd\u5fdc\u306b\u304a\u3044\u3066\u89e6\u5a92\u3068\u3057\u3066\u6a5f\u80fd\u3057\u307e\u3059\u3002<\/li>\n
  2. \u77f3\u6cb9\u5316\u5b66\u7523\u696d\u3067\u306f\u3001\u9ad8\u30aa\u30af\u30bf\u30f3\u4fa1\u30ac\u30bd\u30ea\u30f3\u3084\u305d\u306e\u4ed6\u306e\u70ad\u5316\u6c34\u7d20\u306e\u88fd\u9020\u306b HSbF6 \u304c\u4f7f\u7528\u3055\u308c\u3066\u3044\u307e\u3059\u3002<\/li>\n
  3. \u88fd\u85ac\u696d\u754c\u306e\u7814\u7a76\u8005\u306f\u3001\u6297\u30a6\u30a4\u30eb\u30b9\u85ac\u3084\u6297\u304c\u3093\u5264\u306a\u3069\u306e\u3055\u307e\u3056\u307e\u306a\u533b\u85ac\u54c1\u306e\u5408\u6210\u306b\u304a\u3051\u308b\u89e6\u5a92\u3068\u3057\u3066 HSbF6 \u3092\u4f7f\u7528\u3057\u3066\u3044\u307e\u3059\u3002<\/li>\n
  4. HSbF6 \u306f\u3001\u96fb\u5b50\u90e8\u54c1\u306e\u88fd\u9020\u306b\u4f7f\u7528\u3055\u308c\u308b\u30de\u30a4\u30af\u30ed\u30c1\u30c3\u30d7\u3084\u534a\u5c0e\u4f53\u306a\u3069\u306e\u96fb\u5b50\u90e8\u54c1\u306e\u30a8\u30c3\u30c1\u30f3\u30b0\u3084\u6d17\u6d44\u306b\u5fdc\u7528\u3055\u308c\u3066\u3044\u307e\u3059\u3002<\/li>\n
  5. \u79d1\u5b66\u8005\u306f\u3001\u65b0\u6750\u6599\u306e\u5408\u6210\u3084\u5316\u5b66\u53cd\u5fdc\u306e\u7814\u7a76\u306a\u3069\u3001\u5316\u5b66\u304a\u3088\u3073\u6750\u6599\u79d1\u5b66\u306e\u3055\u307e\u3056\u307e\u306a\u5206\u91ce\u3067\u7814\u7a76\u30c4\u30fc\u30eb\u3068\u3057\u3066 HSbF6 \u3092\u4f7f\u7528\u3057\u3066\u3044\u307e\u3059\u3002<\/li>\n<\/ol>\n

    HSbF6 \u306f\u53cd\u5fdc\u6027\u304c\u9ad8\u304f\u5371\u967a\u306a\u7269\u8cea\u3067\u3042\u308a\u3001\u7279\u6b8a\u306a\u53d6\u308a\u6271\u3044\u3068\u4fdd\u8b77\u63aa\u7f6e\u304c\u5fc5\u8981\u3067\u3059\u3002\u3053\u308c\u306f\u53b3\u3057\u304f\u898f\u5236\u3055\u308c\u3066\u304a\u308a\u3001\u8a2d\u5099\u306e\u6574\u3063\u305f\u7814\u7a76\u5ba4\u3067\u8a13\u7df4\u3092\u53d7\u3051\u305f\u62c5\u5f53\u8005\u306e\u307f\u304c\u4f7f\u7528\u3059\u308b\u5fc5\u8981\u304c\u3042\u308a\u307e\u3059\u3002 HSbF6 \u306b\u95a2\u9023\u3059\u308b\u6f5c\u5728\u7684\u306a\u5371\u967a\u6027\u306b\u3088\u308a\u3001HSbF6 \u306e\u4f7f\u7528\u306f\u3001\u4ed6\u306b\u4ee3\u66ff\u624b\u6bb5\u304c\u306a\u3044\u7279\u6b8a\u306a\u7528\u9014\u306b\u9650\u5b9a\u3055\u308c\u307e\u3059\u3002<\/p>\n

    \u8cea\u554f:<\/strong><\/h5>\n
    \u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306f\u30c0\u30a4\u30e4\u30e2\u30f3\u30c9\u3092\u6eb6\u89e3\u3067\u304d\u307e\u3059\u304b?<\/h6>\n

    HSbF6 \u306f\u305d\u306e\u5f37\u3044\u9178\u6027\u306e\u6027\u8cea\u306b\u3088\u308a\u30c0\u30a4\u30e4\u30e2\u30f3\u30c9\u3092\u6eb6\u89e3\u3059\u308b\u53ef\u80fd\u6027\u304c\u3042\u308a\u307e\u3059\u3002\u9069\u5207\u306a\u5b89\u5168\u5bfe\u7b56\u3068\u4fdd\u8b77\u5177\u3092\u5099\u3048\u305f\u8a2d\u5099\u306e\u6574\u3063\u305f\u5b9f\u9a13\u5ba4\u3067\u8a13\u7df4\u3092\u53d7\u3051\u305f\u5c02\u9580\u5bb6\u306f\u3001\u30c0\u30a4\u30e4\u30e2\u30f3\u30c9\u3068 HSbF6 \u306e\u9593\u306e\u975e\u5e38\u306b\u5371\u967a\u306a\u53cd\u5fdc\u3092\u5b9f\u884c\u3067\u304d\u307e\u3059\u3002\u3057\u304b\u3057\u3001\u3053\u308c\u306f\u30c0\u30a4\u30e4\u30e2\u30f3\u30c9\u306e\u52a0\u5de5\u3084\u5207\u65ad\u306b\u304a\u3044\u3066\u306f\u5b9f\u7528\u7684\u307e\u305f\u306f\u8cbb\u7528\u5bfe\u52b9\u679c\u306e\u9ad8\u3044\u65b9\u6cd5\u3067\u306f\u3042\u308a\u307e\u305b\u3093\u3002\u6a5f\u68b0\u5207\u65ad\u307e\u305f\u306f\u30ec\u30fc\u30b6\u30fc\u5207\u65ad\u306f\u3001\u52b9\u7387\u3068\u5b89\u5168\u6027\u306e\u305f\u3081\u3001\u3088\u308a\u4e00\u822c\u7684\u306b\u4f7f\u7528\u3055\u308c\u3066\u3044\u307e\u3059\u3002<\/p>\n

    \u30d5\u30eb\u30aa\u30ed\u30a2\u30f3\u30c1\u30e2\u30f3\u9178\u306f\u3069\u3053\u3067\u8cfc\u5165\u3067\u304d\u307e\u3059\u304b?<\/h6>\n

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