{"id":932,"date":"2023-07-20T03:32:09","date_gmt":"2023-07-20T03:32:09","guid":{"rendered":"https:\/\/chemuza.org\/cn\/3-%e5%b7%b1%e9%86%87-c6h14o\/"},"modified":"2023-07-20T03:32:09","modified_gmt":"2023-07-20T03:32:09","slug":"3-%e5%b7%b1%e9%86%87-c6h14o","status":"publish","type":"post","link":"https:\/\/chemuza.org\/cn\/3-%e5%b7%b1%e9%86%87-c6h14o\/","title":{"rendered":"3-\u5df1\u9187 \u2013 c6h14o, 623-37-0"},"content":{"rendered":"<p>3-\u5df1\u9187\u662f\u4e00\u79cd\u65e0\u8272\u6db2\u4f53\u9152\u7cbe\uff0c\u5177\u6709\u4ee4\u4eba\u6109\u5feb\u7684\u6c14\u5473\u3002\u5b83\u7528\u4e8e\u751f\u4ea7\u9999\u6c34\u3001\u9999\u6599\u5e76\u7528\u4f5c\u6eb6\u5242\u3002<\/p>\n<figure class=\"wp-block-table\">\n<table>\n<tbody>\n<tr>\n<td>\u56fd\u9645\u7eaf\u7cb9\u548c\u5e94\u7528\u5316\u5b66\u8054\u5408\u4f1a\u540d\u79f0<\/td>\n<td>3-\u5df1\u9187<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u5f0f<\/td>\n<td>C6H14O<\/td>\n<\/tr>\n<tr>\n<td> CAS \u53f7<\/td>\n<td>623-37-0<\/td>\n<\/tr>\n<tr>\n<td>\u540c\u4e49\u8bcd<\/td>\n<td>3-\u5df1\u9187\uff0c3-\u5df1\u9187\uff0cCH3(CH2)3CH2OH<\/td>\n<\/tr>\n<tr>\n<td>\u4e59\u9170\u80c6\u78b1<\/td>\n<td>InChI=1S\/C6H14O\/c1-2-3-4-5-6-7\/h7H,2-6H2,1H3<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n<h2 class=\"wp-block-heading\"> <strong>3-\u5df1\u9187\u7684\u6027\u8d28<\/strong><\/h2>\n<h3 class=\"wp-block-heading\">3-\u5df1\u9187\u7ed3\u6784\u5f0f<\/h3>\n<p>3-\u5df1\u9187\u7684\u5206\u5b50\u5f0f\u4e3aC6H14O\u3002\u5b83\u4ee3\u8868\u5206\u5b50\u4e2d\u539f\u5b50\u7684\u6392\u5217\u3002 \u201cC\u201d\u4ee3\u8868\u78b3\uff0c\u201cH\u201d\u4ee3\u8868\u6c22\uff0c\u201cO\u201d\u4ee3\u8868\u6c27\u3002\u6570\u5b576\u8868\u793a\u5206\u5b50\u4e2d\u67096\u4e2a\u78b3\u539f\u5b50\uff0c\u800c\u6570\u5b5714\u8868\u793a\u5b58\u572814\u4e2a\u6c22\u539f\u5b50\u3002\u6700\u540e\uff0c\u201cO\u201d\u8868\u793a\u5316\u5408\u7269\u4e2d\u5b58\u5728\u6c27\u539f\u5b50\u3002<\/p>\n<h3 class=\"wp-block-heading\"> 3-\u5df1\u9187 \u6469\u5c14\u8d28\u91cf<\/h3>\n<p>3-\u5df1\u9187\u7684\u6469\u5c14\u8d28\u91cf\u662f\u901a\u8fc7\u5c06\u5176\u5f0f\u4e2d\u6240\u6709\u539f\u5b50\u7684\u539f\u5b50\u8d28\u91cf\u76f8\u52a0\u8ba1\u7b97\u5f97\u51fa\u7684\u3002\u5bf9\u4e8e 3-\u5df1\u9187 (C6H14O)\uff0c\u6469\u5c14\u8d28\u91cf\u53ef\u4ee5\u786e\u5b9a\u4e3a 6 \u4e2a\u78b3\u539f\u5b50 (12.01 g\/mol) + 14 \u4e2a\u6c22\u539f\u5b50 (1.008 g\/mol) + 1 \u4e2a\u6c27\u539f\u5b50 (16.00 g\/mol)\uff0c\u8fd9\u7ed9\u51fa\u4e86\u6469\u5c14\u8d28\u91cf\u7ea6\u4e3a102.18 g\/mol\u3002<\/p>\n<h3 class=\"wp-block-heading\"> 3-\u5df1\u9187\u7684\u6cb8\u70b9<\/h3>\n<p>3-\u5df1\u9187\u7684\u6cb8\u70b9\u662f\u5b83\u4ece\u6db2\u4f53\u53d8\u6210\u6c14\u4f53\u7684\u6e29\u5ea6\u3002 3-\u5df1\u9187\u7684\u6cb8\u70b9\u7ea6\u4e3a 156-157\u00b0C (312-315\u00b0F)\u3002\u8fd9\u79cd\u7279\u6027\u5728\u5404\u79cd\u5de5\u4e1a\u5e94\u7528\u4e2d\u90fd\u5f88\u91cd\u8981\uff0c\u4f8b\u5982\u84b8\u998f\u8fc7\u7a0b\uff0c\u5176\u4e2d\u6839\u636e\u6cb8\u70b9\u5206\u79bb\u4e0d\u540c\u7684\u7269\u8d28\u3002<\/p>\n<h3 class=\"wp-block-heading\"> 3-\u5df1\u9187\u7194\u70b9<\/h3>\n<p>3-\u5df1\u9187\u7684\u7194\u70b9\u662f\u5b83\u4ece\u56fa\u4f53\u8f6c\u53d8\u4e3a\u6db2\u4f53\u7684\u6e29\u5ea6\u3002 3-\u5df1\u9187\u7684\u7194\u70b9\u7ea6\u4e3a -43\u00b0C (-45\u00b0F)\u3002\u5f53\u8003\u8651\u5316\u5408\u7269\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u884c\u4e3a\u65f6\uff0c\u8fd9\u4e00\u7279\u6027\u975e\u5e38\u91cd\u8981\u3002<\/p>\n<h3 class=\"wp-block-heading\"> 3-\u5df1\u9187\u7684\u5bc6\u5ea6 g\/mL<\/h3>\n<p> 3-\u5df1\u9187\u7684\u5bc6\u5ea6\u662f\u6307\u5355\u4f4d\u4f53\u79ef\u5185\u8be5\u7269\u8d28\u7684\u8d28\u91cf\u3002 3-\u5df1\u9187\u7684\u5bc6\u5ea6\u7ea6\u4e3a0.81 g\/mL\u3002\u8fd9\u4e00\u7279\u6027\u53ef\u4ee5\u6df1\u5165\u4e86\u89e3\u5316\u5408\u7269\u7684\u81f4\u5bc6\u6027\u6216\u6d53\u5ea6\uff0c\u4ece\u800c\u4fc3\u8fdb\u5404\u79cd\u5b9e\u9645\u5e94\u7528\uff0c\u4f8b\u5982\u786e\u5b9a\u6eb6\u5242\u7684\u9002\u7528\u6027\u6216\u4e86\u89e3\u5176\u5728\u6df7\u5408\u7269\u4e2d\u7684\u884c\u4e3a\u3002<\/p>\n<h3 class=\"wp-block-heading\"> 3-\u5df1\u9187\u5206\u5b50\u91cf<\/h3>\n<p>3-\u5df1\u9187\u7684\u5206\u5b50\u91cf\u662f\u5176\u5f0f\u4e2d\u6240\u6709\u539f\u5b50\u7684\u539f\u5b50\u91cf\u4e4b\u548c\u3002 3-\u5df1\u9187\u7684\u5206\u5b50\u5f0f\u4e3aC6H14O\uff0c\u5206\u5b50\u91cf\u7ea6\u4e3a102.18 g\/mol\u3002\u8be5\u503c\u5728\u5316\u5b66\u8ba1\u7b97\u4e2d\u81f3\u5173\u91cd\u8981\uff0c\u7279\u522b\u662f\u5bf9\u4e8e\u786e\u5b9a\u53cd\u5e94\u7684\u5316\u5b66\u8ba1\u91cf\u548c\u6469\u5c14\u6bd4\u3002<\/p>\n<h3 class=\"wp-block-heading\"> 3-\u5df1\u9187\u7684\u7ed3\u6784<\/h3>\n<div class=\"wp-block-image\">\n<figure class=\"alignright size-large\"><img decoding=\"async\" src=\"https:\/\/chemuza.org\/wp-content\/uploads\/2023\/08\/3-hexanol.jpg\" alt=\"3-\u5df1\u9187\" srcset=\"\" sizes=\"\"><\/figure>\n<\/div>\n<p> 3-\u5df1\u9187\u7684\u7ed3\u6784\u7531\u516d\u4e2a\u78b3\u539f\u5b50\u94fe\u7ec4\u6210\uff0c\u7b2c\u4e09\u4e2a\u78b3\u539f\u5b50\u4e0a\u8fde\u63a5\u6709\u4e00\u4e2a-OH\uff08\u7f9f\u57fa\uff09\u57fa\u56e2\u3002\u53ef\u7528CH3(CH2)3CH2OH\u8868\u793a\u3002\u8be5\u7ed3\u6784\u5b9a\u4e49\u4e86\u5176\u5316\u5b66\u6027\u8d28\u53ca\u5176\u4e0e\u5176\u4ed6\u5316\u5408\u7269\u76f8\u4e92\u4f5c\u7528\u65f6\u7684\u884c\u4e3a\u3002<\/p>\n<h3 class=\"wp-block-heading\"> 3-\u5df1\u9187\u7684\u6eb6\u89e3\u5ea6<\/h3>\n<p>Hexan-3-ol\u90e8\u5206\u6eb6\u4e8e\u6c34\uff0c\u8fd9\u610f\u5473\u7740\u5b83\u53ef\u4ee5\u4e00\u5b9a\u7a0b\u5ea6\u5730\u6eb6\u89e3\u3002\u7136\u800c\uff0c\u7531\u4e8e\u5176\u758f\u6c34\u6027\uff08\u62d2\u6c34\u6027\uff09\uff0c\u5176\u6eb6\u89e3\u5ea6\u53d7\u5230\u9650\u5236\u3002\u8f83\u6613\u6eb6\u4e8e\u4e59\u9187\u3001\u4e59\u919a\u7b49\u6709\u673a\u6eb6\u5242\u3002 3-\u5df1\u9187\u7684\u6eb6\u89e3\u5ea6\u7279\u6027\u5f71\u54cd\u5176\u5728\u5404\u4e2a\u884c\u4e1a\u7684\u5e94\u7528\uff0c\u5305\u62ec\u5236\u836f\u548c\u5316\u5b66\u5408\u6210\u3002<\/p>\n<figure class=\"wp-block-table\">\n<table>\n<tbody>\n<tr>\n<td>\u5916\u8c8c<\/td>\n<td>\u65e0\u8272<\/td>\n<\/tr>\n<tr>\n<td>\u6bd4\u91cd<\/td>\n<td>0.81\u514b\/\u6beb\u5347<\/td>\n<\/tr>\n<tr>\n<td>\u989c\u8272<\/td>\n<td>\u4e0d\u9002\u7528<\/td>\n<\/tr>\n<tr>\n<td>\u95fb<\/td>\n<td>\u4ee4\u4eba\u6109\u5feb\u7684<\/td>\n<\/tr>\n<tr>\n<td>\u6469\u5c14\u8d28\u91cf<\/td>\n<td>102.18 \u514b\/\u6469\u5c14<\/td>\n<\/tr>\n<tr>\n<td>\u5bc6\u5ea6<\/td>\n<td>0.81\u514b\/\u6beb\u5347<\/td>\n<\/tr>\n<tr>\n<td>\u878d\u5408\u70b9<\/td>\n<td>-43\u2103<\/td>\n<\/tr>\n<tr>\n<td>\u6cb8\u70b9<\/td>\n<td>156-157\u2103<\/td>\n<\/tr>\n<tr>\n<td>\u95ea\u70b9<\/td>\n<td>\u4e0d\u9002\u7528<\/td>\n<\/tr>\n<tr>\n<td>\u6c34\u4e2d\u6eb6\u89e3\u5ea6<\/td>\n<td>\u90e8\u5206\u6eb6\u89e3<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u5ea6<\/td>\n<td>\u66f4\u6613\u6eb6\u4e8e\u4e59\u9187\u3001\u4e59\u919a\u7b49\u6709\u673a\u6eb6\u5242<\/td>\n<\/tr>\n<tr>\n<td>\u84b8\u6c7d\u538b\u529b<\/td>\n<td>\u4e0d\u9002\u7528<\/td>\n<\/tr>\n<tr>\n<td>\u84b8\u6c14\u5bc6\u5ea6<\/td>\n<td>\u4e0d\u9002\u7528<\/td>\n<\/tr>\n<tr>\n<td>\u9178\u5ea6<\/td>\n<td>\u4e0d\u9002\u7528<\/td>\n<\/tr>\n<tr>\n<td>\u9178\u78b1\u5ea6<\/td>\n<td>\u4e0d\u9002\u7528<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n<h2 class=\"wp-block-heading\"><strong>3-\u5df1\u9187\u7684\u5b89\u5168\u6027\u548c\u5371\u9669\u6027<\/strong><\/h2>\n<p>3-\u5df1\u9187\u5177\u6709\u4e00\u5b9a\u7684\u5b89\u5168\u8003\u8651\u548c\u5371\u9669\u3002\u8c28\u614e\u5904\u7406\u8fd9\u79cd\u5316\u5408\u7269\u975e\u5e38\u91cd\u8981\u3002\u76f4\u63a5\u63a5\u89e6 3-\u5df1\u9187\u53ef\u80fd\u4f1a\u523a\u6fc0\u76ae\u80a4\u548c\u773c\u775b\u3002\u5927\u91cf\u6444\u5165\u6216\u5438\u5165\u53ef\u80fd\u4f1a\u5bf9\u547c\u5438\u7cfb\u7edf\u548c\u6d88\u5316\u7cfb\u7edf\u9020\u6210\u4e0d\u826f\u5f71\u54cd\u3002\u4f7f\u7528 3-\u5df1\u9187\u65f6\uff0c\u5fc5\u987b\u4f7f\u7528\u9002\u5f53\u7684\u4e2a\u4eba\u9632\u62a4\u88c5\u5907 (PPE)\uff0c\u4ee5\u5c3d\u91cf\u51cf\u5c11\u63a5\u89e6\u98ce\u9669\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u8be5\u7269\u8d28\u6613\u71c3\uff0c\u56e0\u6b64\u5fc5\u987b\u5c06\u5176\u5b58\u653e\u5728\u901a\u98ce\u826f\u597d\u7684\u5730\u65b9\uff0c\u8fdc\u79bb\u70ed\u6e90\u548c\u660e\u706b\u3002\u5e94\u6839\u636e\u5f53\u5730\u6cd5\u89c4\u91c7\u53d6\u9002\u5f53\u7684\u5904\u7f6e\u65b9\u6cd5\uff0c\u4ee5\u907f\u514d\u73af\u5883\u6c61\u67d3\u3002<\/p>\n<figure class=\"wp-block-table\">\n<table>\n<tbody>\n<tr>\n<td>\u5371\u9669\u7b26\u53f7<\/td>\n<td>\u5192\u9669<\/td>\n<\/tr>\n<tr>\n<td>\u5b89\u5168\u8bf4\u660e<\/td>\n<td>\u529e\u7406\u62bc\u91d1\u3002\u907f\u514d\u76f4\u63a5\u63a5\u89e6\u3002<\/td>\n<\/tr>\n<tr>\n<td>\u8054\u5408\u56fd\u8bc6\u522b\u53f7<\/td>\n<td>\u8054\u5408\u56fd3275<\/td>\n<\/tr>\n<tr>\n<td>\u6d77\u5173\u7f16\u7801<\/td>\n<td>2905.19.10<\/td>\n<\/tr>\n<tr>\n<td>\u5371\u9669\u7b49\u7ea7<\/td>\n<td>3<\/td>\n<\/tr>\n<tr>\n<td>\u5305\u88c5\u7ec4\u522b<\/td>\n<td>\u4e09\u3001<\/td>\n<\/tr>\n<tr>\n<td>\u6bd2\u6027<\/td>\n<td>\u4f4e\u6bd2<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n<h2 class=\"wp-block-heading\"><strong>3-\u5df1\u9187\u7684\u5408\u6210\u65b9\u6cd5<\/strong><\/h2>\n<p>\u6709\u591a\u79cd\u5408\u62103-\u5df1\u9187\u7684\u65b9\u6cd5\u3002\u4e00\u79cd\u5e38\u89c1\u7684\u65b9\u6cd5\u662f\u5229\u7528 1-\u5df1\u70ef\u7684\u787c\u6c22\u5316-\u6c27\u5316\u53cd\u5e94\u3002<\/p>\n<p>\u8981\u5408\u6210 3-\u5df1\u9187\uff0c\u8bf7\u5728<a href=\"https:\/\/chemuza.org\/cn\/\u56db\u6c22\u544b\u5583-thf-c4h8o\/\">\u56db\u6c22\u544b\u5583 (THF)<\/a>\u7b49\u6eb6\u5242\u5b58\u5728\u4e0b\uff0c\u4f7f 1-\u5df1\u70ef\u4e0e\u787c\u70f7 (BH3) \u53cd\u5e94\u3002\u8be5\u53cd\u5e94\u5f62\u6210\u76f8\u5e94\u7684\u787c\u4e2d\u95f4\u4f53\uff0c\u7136\u540e\u7528\u8fc7<a href=\"https:\/\/chemuza.org\/cn\/\u8fc7\u6c27\u5316\u6c22-h2o2\/\">\u6c27\u5316\u6c22<\/a>(H2O2) \u6216<a href=\"https:\/\/chemuza.org\/cn\/\u6c22\u6c27\u5316\u94a0-\u70e7\u78b1-naoh\/\">\u6c22\u6c27\u5316\u94a0 (NaOH)<\/a>\u8fdb\u884c\u6c27\u5316\uff0c\u4ece\u800c\u5f62\u6210 3-\u5df1\u9187\u3002<\/p>\n<p>\u53e6\u4e00\u79cd\u65b9\u6cd5\u6d89\u53ca\u4f7f\u7528<a href=\"https:\/\/chemuza.org\/cn\/\u787c\u6c22\u5316\u94a0-nabh4\/\">\u787c\u6c22\u5316\u94a0 (NaBH4)<\/a>\u6216\u6c22\u5316\u94dd\u9502 (LiAlH4) \u7b49\u8fd8\u539f\u5242\u8fd8\u539f 3-\u5df1\u916e\u3002\u8be5\u53cd\u5e94\u5c06 3-\u5df1\u916e\u7684\u7fb0\u57fa\u8f6c\u5316\u4e3a\u7f9f\u57fa\uff0c\u4ece\u800c\u5f62\u6210 3-\u5df1\u9187\u3002<\/p>\n<p>\u901a\u8fc7\u9541 (Mg) \u4e0e\u5364\u4ee3\u70f7\uff08\u4f8b\u5982 1-\u6eb4\u5df1\u70f7\uff09\u53cd\u5e94\uff0c\u901a\u8fc7\u683c\u6c0f\u53cd\u5e94\u751f\u6210 3-\u5df1\u9187\u3002\u8be5\u53cd\u5e94\u4ea7\u751f\u76f8\u5e94\u7684\u683c\u6c0f\u8bd5\u5242\uff0c\u7136\u540e\u4e0e\u7532\u919b\uff08HCHO\uff09\u53cd\u5e94\u751f\u62103-\u5df1\u9187\u3002<\/p>\n<p>\u5df1\u9187\u6c27\u5316\u751f\u6210\u76f8\u5e94\u7684\u919b\uff0c\u8fd8\u539f\u5f97\u52303-\u5df1\u9187\u3002\u4f7f\u7528 NaBH4 \u7b49\u8fd8\u539f\u5242\u6216\u50ac\u5316\u6c22\u5316\u8fd8\u539f\u919b\uff0c\u5f62\u6210 3-\u5df1\u9187\u3002<\/p>\n<p>\u8fd9\u4e9b\u4e0d\u540c\u7684\u5408\u6210\u65b9\u6cd5\u63d0\u4f9b\u4e86\u83b7\u5f97 3-\u5df1\u9187\u7684\u4e0d\u540c\u9014\u5f84\uff0c\u4ece\u800c\u53ef\u4ee5\u6839\u636e\u7279\u5b9a\u9700\u6c42\u548c\u53ef\u7528\u539f\u6750\u6599\u8fdb\u884c\u7075\u6d3b\u6027\u548c\u9002\u5e94\u6027\u8c03\u6574\u3002\u4ed4\u7ec6\u9009\u62e9\u9002\u5f53\u7684\u65b9\u6cd5\u5bf9\u4e8e\u786e\u4fdd\u9ad8\u6548\u4e14\u53d7\u63a7\u7684 3-\u5df1\u9187\u5408\u6210\u81f3\u5173\u91cd\u8981\u3002<\/p>\n<h2 class=\"wp-block-heading\"> <strong>3-\u5df1\u9187\u7684\u7528\u9014<\/strong><\/h2>\n<p>Hexan-3-ol \u7531\u4e8e\u5176\u591a\u529f\u80fd\u7279\u6027\u800c\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u3002\u4ee5\u4e0b\u662f Hexan-3-ol \u7684\u4e00\u4e9b\u4e3b\u8981\u7528\u9014\uff1a<\/p>\n<ul>\n<li> 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