{"id":494,"date":"2023-07-22T22:58:53","date_gmt":"2023-07-22T22:58:53","guid":{"rendered":"https:\/\/chemuza.org\/cn\/%e5%a8%81%e5%b0%94%e9%87%91%e6%a3%ae%e5%82%ac%e5%8c%96%e5%89%82\/"},"modified":"2023-07-22T22:58:53","modified_gmt":"2023-07-22T22:58:53","slug":"%e5%a8%81%e5%b0%94%e9%87%91%e6%a3%ae%e5%82%ac%e5%8c%96%e5%89%82","status":"publish","type":"post","link":"https:\/\/chemuza.org\/cn\/%e5%a8%81%e5%b0%94%e9%87%91%e6%a3%ae%e5%82%ac%e5%8c%96%e5%89%82\/","title":{"rendered":"\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242 \u2013 rhcl(pph3)2, 14694-95-2"},"content":{"rendered":"<p>Wilkinson \u50ac\u5316\u5242\u6216 RhCl(PPh3)2 \u662f\u4e00\u79cd\u975e\u5e38\u6d3b\u8dc3\u7684\u5747\u76f8\u50ac\u5316\u5242\uff0c\u7528\u4e8e\u6709\u673a\u5408\u6210\uff0c\u7279\u522b\u662f\u6c22\u5316\u53cd\u5e94\u3002\u5b83\u7531\u5e26\u6709\u81a6\u914d\u4f53\u7684\u94d1\u7edc\u5408\u7269\u7ec4\u6210\u3002<\/p>\n<figure class=\"wp-block-table\">\n<table>\n<tbody>\n<tr>\n<td>\u56fd\u9645\u7eaf\u7cb9\u548c\u5e94\u7528\u5316\u5b66\u8054\u5408\u4f1a\u540d\u79f0<\/td>\n<td>\u4e09\u6c2f\u4e09(\u4e09\u82ef\u57fa\u81a6)\u94d1(I)<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u5f0f<\/td>\n<td>C54H45ClP3Rh<\/td>\n<\/tr>\n<tr>\n<td> CAS \u53f7<\/td>\n<td>14694-95-2<\/td>\n<\/tr>\n<tr>\n<td>\u540c\u4e49\u8bcd<\/td>\n<td>\u4e09\u82ef\u81a6\u6c2f\u5316\u94d1\u7edc\u5408\u7269\u3001\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u3001RhCl(PPh3)3\u3001\u4e09\u82ef\u81a6\u6c2f\u5316\u94d1(I)\u7edc\u5408\u7269\u3001\u4e09\u82ef\u81a6\u6c2f\u5316\u94d1\u3001\u4e09\u82ef\u81a6\u6c2f\u5316\u94d1<\/td>\n<\/tr>\n<tr>\n<td>\u4e59\u9170\u80c6\u78b1<\/td>\n<td>InChI=1S\/2C18H15P.2ClH.Rh\/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9- 15-18;;;\/h21-15H;2*1H;\/q;;;;+3\/p-3<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n<h6 class=\"wp-block-heading\">\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u6469\u5c14\u8d28\u91cf<\/h6>\n<p>Wilkinson \u50ac\u5316\u5242\uff0c\u4e5f\u79f0\u4e3a RhCl(PPh3)2\uff0c\u6469\u5c14\u8d28\u91cf\u4e3a 925.08 g\/mol\u3002\u8be5\u503c\u6e90\u81ea\u7edc\u5408\u7269\u7ec4\u6210\u5143\u7d20\u7684\u539f\u5b50\u8d28\u91cf\u4e4b\u548c\uff0c\u5305\u62ec\u94d1\u3001\u6c2f\u3001\u78b3\u3001\u6c22\u548c\u78f7\u3002\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u7684\u6469\u5c14\u8d28\u91cf\u662f\u786e\u5b9a\u7279\u5b9a\u53cd\u5e94\u6240\u9700\u50ac\u5316\u5242\u91cf\u7684\u91cd\u8981\u53c2\u6570\u3002<\/p>\n<h6 class=\"wp-block-heading\">\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u7684\u6cb8\u70b9<\/h6>\n<p>\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u901a\u5e38\u7528\u4f5c\u5747\u76f8\u50ac\u5316\u5242\uff0c\u56e0\u6b64\u6ca1\u6709\u660e\u786e\u7684\u6cb8\u70b9\u3002\u7136\u800c\uff0c\u5176\u5206\u89e3\u6e29\u5ea6\u7ea6\u4e3a180\u00b0C\u3002\u5728\u8f83\u9ad8\u6e29\u5ea6\u4e0b\uff0c\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u53ef\u80fd\u5206\u89e3\u5e76\u5931\u53bb\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n<h6 class=\"wp-block-heading\">\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u7194\u70b9<\/h6>\n<p>Wilkinson\u50ac\u5316\u5242\uff0c\u4e5f\u79f0\u4e3aRhCl(PPh3)3\uff0c\u7194\u70b9\u7ea6\u4e3a207-209\u00b0C\u3002\u6839\u636e\u50ac\u5316\u5242\u7684\u7eaf\u5ea6\u548c\u6d4b\u91cf\u65b9\u6cd5\uff0c\u8be5\u503c\u53ef\u80fd\u7565\u6709\u4e0d\u540c\u3002<\/p>\n<h6 class=\"wp-block-heading\">\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u5bc6\u5ea6g\/ml<\/h6>\n<p>\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u7684\u5bc6\u5ea6\u7ea6\u4e3a 1.4 g\/mL\u3002\u8be5\u503c\u4e5f\u4f1a\u6839\u636e\u50ac\u5316\u5242\u7684\u7eaf\u5ea6\u548c\u6d4b\u91cf\u65b9\u6cd5\u800c\u53d8\u5316\u3002<\/p>\n<h6 class=\"wp-block-heading\">\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u5206\u5b50\u91cf<\/h6>\n<p>Wilkinson\u50ac\u5316\u5242\uff0c\u4e5f\u79f0\u4e3aRhCl(PPh3)3\uff0c\u5206\u5b50\u91cf\u4e3a925.08 g\/mol\u3002\u8be5\u503c\u662f\u901a\u8fc7\u6dfb\u52a0\u6784\u6210\u7edc\u5408\u7269\u7684\u539f\u5b50\u7684\u539f\u5b50\u91cf\u6765\u8ba1\u7b97\u7684\u3002\u5206\u5b50\u91cf\u5bf9\u4e8e\u786e\u5b9a\u6d89\u53ca\u50ac\u5316\u5242\u7684\u53cd\u5e94\u7684\u5316\u5b66\u8ba1\u91cf\u5f88\u91cd\u8981\u3002<\/p>\n<h6 class=\"wp-block-heading\">\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u7684\u7ed3\u6784<\/h6>\n<div class=\"wp-block-image\">\n<figure class=\"alignright size-large is-resized\"><img decoding=\"async\" loading=\"lazy\" src=\"https:\/\/chemuza.org\/wp-content\/uploads\/2023\/08\/Wilkinson-s-catalyst.png\" alt=\"\" width=\"258\" height=\"118\" srcset=\"\" sizes=\"auto, \"><\/figure>\n<\/div>\n<p> Wilkinson \u50ac\u5316\u5242\u6216 RhCl(PPh3)3 \u7684\u7ed3\u6784\u7531\u4e0e\u4e09\u4e2a\u4e09\u82ef\u57fa\u81a6\u914d\u4f53 (PPh3) \u914d\u4f4d\u7684\u94d1\u539f\u5b50\u548c\u6c2f\u79bb\u5b50 (Cl-) \u7ec4\u6210\u3002\u8be5\u914d\u5408\u7269\u5177\u6709\u65b9\u5f62\u5e73\u9762\u51e0\u4f55\u5f62\u72b6\uff0c\u94d1\u539f\u5b50\u4f4d\u4e8e\u4e2d\u5fc3\uff0c\u56db\u4e2a\u914d\u4f53\u6392\u5217\u5728\u5176\u5468\u56f4\u7684\u5e73\u9762\u4e0a\u3002 PPh3 \u914d\u4f53\u5bf9\u4e8e\u7a33\u5b9a\u914d\u5408\u7269\u5e76\u4fc3\u8fdb\u5176\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u53cd\u5e94\u6d3b\u6027\u975e\u5e38\u91cd\u8981\u3002<\/p>\n<h6 class=\"wp-block-heading\">\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u516c\u5f0f<\/h6>\n<p>\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u7684\u5206\u5b50\u5f0f\u4e3aRhCl(PPh3)3\u3002\u8be5\u5f0f\u8868\u793a\u914d\u5408\u7269\u7684\u5316\u5b66\u8ba1\u91cf\uff0c\u8868\u660e\u914d\u5408\u7269\u4e2d\u67091\u4e2a\u94d1\u539f\u5b50\u30011\u4e2a\u6c2f\u79bb\u5b50\u548c3\u4e2a\u4e09\u82ef\u57fa\u81a6\u914d\u4f53\u3002\u8be5\u516c\u5f0f\u5bf9\u4e8e\u786e\u5b9a\u7279\u5b9a\u53cd\u5e94\u6240\u9700\u7684\u50ac\u5316\u5242\u91cf\u4ee5\u53ca\u8ba1\u7b97\u4ea7\u7269\u7684\u7406\u8bba\u4ea7\u7387\u975e\u5e38\u91cd\u8981\u3002<\/p>\n<figure class=\"wp-block-table\">\n<table>\n<tbody>\n<tr>\n<td>\u5916\u8c8c<\/td>\n<td>\u6df1\u7ea2\u8272\u7ed3\u6676\u56fa\u4f53<\/td>\n<\/tr>\n<tr>\n<td>\u6bd4\u91cd<\/td>\n<td>1.4\u514b\/\u6beb\u5347<\/td>\n<\/tr>\n<tr>\n<td>\u989c\u8272<\/td>\n<td>\u6df1\u7ea2<\/td>\n<\/tr>\n<tr>\n<td>\u95fb<\/td>\n<td>\u65e0\u5473<\/td>\n<\/tr>\n<tr>\n<td>\u6469\u5c14\u8d28\u91cf<\/td>\n<td>925.08 \u514b\/\u6469\u5c14<\/td>\n<\/tr>\n<tr>\n<td>\u5bc6\u5ea6<\/td>\n<td>1.4\u514b\/\u6beb\u5347<\/td>\n<\/tr>\n<tr>\n<td>\u878d\u5408\u70b9<\/td>\n<td>207-209\u2103<\/td>\n<\/tr>\n<tr>\n<td>\u6cb8\u70b9<\/td>\n<td>\u5728 ~180\u00b0C \u65f6\u5206\u89e3<\/td>\n<\/tr>\n<tr>\n<td>\u95ea\u70b9<\/td>\n<td>\u4e0d\u9002\u7528<\/td>\n<\/tr>\n<tr>\n<td>\u6c34\u4e2d\u6eb6\u89e3\u5ea6<\/td>\n<td>\u4e0d\u6eb6\u6027<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u5ea6<\/td>\n<td>\u6eb6\u4e8e\u82ef\u3001\u7532\u82ef\u3001\u6c2f\u4eff\u7b49\u6709\u673a\u6eb6\u5242<\/td>\n<\/tr>\n<tr>\n<td>\u84b8\u6c7d\u538b\u529b<\/td>\n<td>\u4e0d\u9002\u7528<\/td>\n<\/tr>\n<tr>\n<td>\u84b8\u6c14\u5bc6\u5ea6<\/td>\n<td>\u4e0d\u9002\u7528<\/td>\n<\/tr>\n<tr>\n<td>\u9178\u5ea6<\/td>\n<td>\u4e0d\u9002\u7528<\/td>\n<\/tr>\n<tr>\n<td>\u9178\u78b1\u5ea6<\/td>\n<td>\u4e0d\u9002\u7528<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n<p>\u6ce8\uff1a\u6b64\u8868\u4e2d\u63d0\u4f9b\u7684\u503c\u662f\u8fd1\u4f3c\u503c\uff0c\u53ef\u80fd\u4f1a\u6839\u636e\u4fe1\u606f\u6765\u6e90\u7684\u4e0d\u540c\u800c\u6709\u6240\u4e0d\u540c\u3002<\/p>\n<h5 class=\"wp-block-heading\"><strong>\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u7684\u5b89\u5168\u548c\u5371\u9669<\/strong><\/h5>\n<p>\u4f7f\u7528\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u65f6\uff0c\u91c7\u53d6\u9002\u5f53\u7684\u5b89\u5168\u9884\u9632\u63aa\u65bd\u4ee5\u907f\u514d\u6f5c\u5728\u5371\u9669\u975e\u5e38\u91cd\u8981\u3002\u8be5\u590d\u5408\u7269\u4e0d\u88ab\u8ba4\u4e3a\u5177\u6709\u5267\u6bd2\uff0c\u4f46\u4ecd\u5e94\u5c0f\u5fc3\u5904\u7406\uff0c\u4ee5\u907f\u514d\u610f\u5916\u6444\u5165\u6216\u5438\u5165\u3002\u5904\u7406\u50ac\u5316\u5242\u65f6\u5e94\u907f\u514d\u63a5\u89e6\u773c\u775b\u6216\u76ae\u80a4\uff0c\u5e76\u4f69\u6234\u9002\u5f53\u7684\u9632\u62a4\u8bbe\u5907\uff0c\u4f8b\u5982\u624b\u5957\u548c\u5b89\u5168\u773c\u955c\u3002\u6b64\u5916\uff0c\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u5e94\u50a8\u5b58\u5728\u9634\u51c9\u3001\u5e72\u71e5\u3001\u901a\u98ce\u826f\u597d\u7684\u533a\u57df\uff0c\u8fdc\u79bb\u70ed\u6e90\u6216\u706b\u7130\u3002\u672a\u4f7f\u7528\u7684\u50ac\u5316\u5242\u7684\u5904\u7406\u5e94\u6309\u7167\u5f53\u5730\u6cd5\u89c4\u8fdb\u884c\u3002<\/p>\n<figure class=\"wp-block-table\">\n<table>\n<tbody>\n<tr>\n<td>\u5371\u9669\u7b26\u53f7<\/td>\n<td>\u672a\u5206\u914d<\/td>\n<\/tr>\n<tr>\n<td>\u5b89\u5168\u8bf4\u660e<\/td>\n<td>S22\uff1a\u4e0d\u8981\u5438\u5165\u7c89\u5c18\/\u70df\u96fe\/\u6c14\u4f53\/\u70df\u96fe\/\u84b8\u6c14\/\u6c14\u6eb6\u80f6\u3002 S24\/25\uff1a\u907f\u514d\u63a5\u89e6\u76ae\u80a4\u548c\u773c\u775b\u3002 S36\/37\/39\uff1a\u7a7f\u6234\u9002\u5f53\u7684\u9632\u62a4\u670d\u3001\u624b\u5957\u548c\u773c\u90e8\/\u9762\u90e8\u9632\u62a4\u88c5\u7f6e\u3002<\/td>\n<\/tr>\n<tr>\n<td>\u8054\u5408\u56fd\u8bc6\u522b\u53f7<\/td>\n<td>\u4e0d\u9002\u7528<\/td>\n<\/tr>\n<tr>\n<td>\u6d77\u5173\u7f16\u7801<\/td>\n<td>28500090<\/td>\n<\/tr>\n<tr>\n<td>\u5371\u9669\u7b49\u7ea7<\/td>\n<td>\u4e0d\u9002\u7528<\/td>\n<\/tr>\n<tr>\n<td>\u5305\u88c5\u7ec4\u522b<\/td>\n<td>\u4e0d\u9002\u7528<\/td>\n<\/tr>\n<tr>\n<td>\u6bd2\u6027<\/td>\n<td>\u4f4e\u6bd2\uff1b\u4e0d\u88ab\u89c6\u4e3a\u5267\u6bd2\uff0c\u4f46\u4ecd\u5e94\u5c0f\u5fc3\u5904\u7406\uff0c\u4ee5\u907f\u514d\u610f\u5916\u6444\u5165\u6216\u5438\u5165<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n<h5 class=\"wp-block-heading\"><strong><br \/>\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u5408\u6210\u65b9\u6cd5<\/strong><\/h5>\n<p>\u5408\u6210\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u7684\u5e38\u7528\u65b9\u6cd5\u5305\u62ec\u5728\u56de\u6d41\u4e59\u9187\u4e2d\u7528\u8fc7\u91cf\u7684\u4e09\u82ef\u57fa\u81a6\u5904\u7406\u6c34\u5408\u6c2f\u5316\u94d1(III)\u3002\u8be5\u65b9\u6cd5\u53ef\u4ee5\u6309\u5982\u4e0b\u65b9\u5f0f\u8fdb\u884c\uff1a<\/p>\n<p>\u9996\u5148\uff0c\u5c06\u6c34\u5408\u6c2f\u5316\u94d1(III)\u6eb6\u89e3\u5728\u4e59\u9187\u4e2d\u5f62\u6210\u6eb6\u6db2\u3002\u7136\u540e\u5411\u6eb6\u6db2\u4e2d\u6dfb\u52a0\u8fc7\u91cf\u7684\u4e09\u82ef\u57fa\u81a6\u5e76\u5c06\u6df7\u5408\u7269\u56de\u6d41\u6570\u5c0f\u65f6\u3002\u76d1\u6d4b\u6eb6\u6db2\u4e2d\u50ac\u5316\u5242\u7684\u5f62\u6210\uff0c\u53ef\u4ee5\u901a\u8fc7\u989c\u8272\u4ece\u9ec4\u8272\u5230\u7ea2\u8272\u7684\u53d8\u5316\u6765\u8bc6\u522b\u50ac\u5316\u5242\u3002<\/p>\n<p>\u5728\u5408\u6210\u8fc7\u7a0b\u4e2d\uff0c\u4e09\u82ef\u57fa\u81a6\u65e2\u5145\u5f53\u914d\u4f53\u53c8\u5145\u5f53\u8fd8\u539f\u5242\u3002\u4e09\u5f53\u91cf\u7684\u4e09\u82ef\u57fa\u81a6\u4e0e\u94d1\u539f\u5b50\u914d\u4f4d\u5f62\u6210\u7a33\u5b9a\u7684\u7edc\u5408\u7269\uff0c\u800c\u7b2c\u56db\u5f53\u91cf\u7684\u4e09\u82ef\u57fa\u81a6\u5c06\u94d1(III)\u8fd8\u539f\u4e3a\u94d1(I)\u3002\u7ed3\u679c\uff0c\u53cd\u5e94\u7684\u6700\u7ec8\u4ea7\u7269\u662f RhCl(PPh3)3\uff0c\u5176\u4e2d\u4e09\u4e2a\u4e09\u82ef\u57fa\u81a6\u914d\u4f53\u8fde\u63a5\u5230\u94d1\u4e2d\u5fc3\u3002<\/p>\n<p>\u5b8c\u6210\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u7684\u5408\u6210\u540e\uff0c\u53ef\u4ee5\u901a\u8fc7\u8fc7\u6ee4\u53cd\u5e94\u6df7\u5408\u7269\u5e76\u7528\u4e59\u9187\u548c\u4e59\u919a\u6d17\u6da4\u6765\u5206\u79bb\u50ac\u5316\u5242\u3002\u7136\u540e\u5c06\u83b7\u5f97\u7684\u56fa\u4f53\u5728\u771f\u7a7a\u4e0b\u5e72\u71e5\u3002\u5fc5\u987b\u5c0f\u5fc3\u5904\u7406\u50ac\u5316\u5242\uff0c\u4ee5\u907f\u514d\u66b4\u9732\u5728\u7a7a\u6c14\u548c\u6e7f\u6c14\u4e2d\uff0c\u8fd9\u4f1a\u635f\u5bb3\u5176\u7eaf\u5ea6\u548c\u6d3b\u6027\u3002<\/p>\n<p>\u603b\u4f53\u800c\u8a00\uff0c\u8be5\u65b9\u6cd5\u4e3a\u5927\u89c4\u6a21\u5408\u6210\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u4e00\u79cd\u76f8\u5bf9\u7b80\u5355\u6709\u6548\u7684\u65b9\u6cd5\u3002<\/p>\n<h5 class=\"wp-block-heading\"><strong>\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u7684\u7528\u9014<\/strong><\/h5>\n<p>\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u5728\u6709\u673a\u5408\u6210\u4e2d\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u3002<\/p>\n<ul>\n<li>\u5e7f\u6cdb\u7528\u4e8e\u4fc3\u8fdb\u70ef\u70c3\u3001\u7094\u70c3\u7b49\u4e0d\u9971\u548c\u6709\u673a\u5316\u5408\u7269\u7684\u52a0\u6c22\u3002<\/li>\n<li>\u8be5\u50ac\u5316\u5242\u5728\u52a0\u6c22\u7532\u9170\u5316\uff08\u5c06\u70ef\u70c3\u8f6c\u5316\u4e3a\u76f4\u94fe\u9187\u7684\u8fc7\u7a0b\uff09\u4e2d\u81f3\u5173\u91cd\u8981\u3002<\/li>\n<li>\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u5e7f\u6cdb\u5e94\u7528\u4e8e\u533b\u836f\u3001\u519c\u7528\u5316\u5b66\u54c1\u548c\u9ad8\u5206\u5b50\u6750\u6599\u7684\u5408\u6210\u3002<\/li>\n<li>\u5b83\u53ef\u4ee5\u4fc3\u8fdb\u5404\u79cd\u53cd\u5e94\uff0c\u5305\u62ecCC\u548cCO\u952e\u7684\u5f62\u6210\uff0c\u4ece\u800c\u5bfc\u81f4\u590d\u6742\u6709\u673a\u5206\u5b50\u7684\u5408\u6210\u3002<\/li>\n<li>\u8be5\u50ac\u5316\u5242\u5e38\u4e0e\u5176\u4ed6\u50ac\u5316\u5242\u7ed3\u5408\u4f7f\u7528\uff0c\u4ee5\u8fbe\u5230\u7279\u5b9a\u7684\u53cd\u5e94\u7ed3\u679c\u3002<\/li>\n<\/ul>\n<p>\u4f7f\u7528\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u53ef\u4ee5\u5b9e\u73b0\u66f4\u9ad8\u6548\u3001\u66f4\u53ef\u6301\u7eed\u7684\u5316\u5b66\u8fc7\u7a0b\u3002\u8fd9\u53ef\u4ee5\u51cf\u5c11\u5e9f\u7269\u4ea7\u751f\u548c\u80fd\u6e90\u6d88\u8017\uff0c\u4fc3\u8fdb\u53ef\u6301\u7eed\u5316\u5b66\u5b9e\u8df5\u3002<\/p>\n<p><strong>\u95ee\u9898\uff1a<\/strong><\/p>\n<h6 class=\"wp-block-heading\">\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u6742\u5316<\/h6>\n<p>Wilkinson \u50ac\u5316\u5242 (RhCl(PPh3)3) \u7684\u6742\u5316\u6d89\u53ca\u4e2d\u5fc3\u94d1\u539f\u5b50\u8fdb\u884c\u6742\u5316\uff0c\u4e0e\u5176\u5468\u56f4\u539f\u5b50\u5f62\u6210\u5316\u5b66\u952e\u3002<\/p>\n<p>\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u4e2d\u7684\u94d1\u539f\u5b50\u5177\u6709 d8 \u7535\u5b50\u6784\u578b\uff0c\u8fd9\u610f\u5473\u7740\u5b83\u6709 8 \u4e2a\u53ef\u7528\u4e8e\u5316\u5b66\u952e\u5408\u7684\u4ef7\u7535\u5b50\u3002\u5728\u4e09\u4e2a\u4e09\u82ef\u57fa\u81a6 (PPh3) \u914d\u4f53\u548c\u4e00\u4e2a\u6c2f\u5316\u7269 (Cl) \u914d\u4f53\u5b58\u5728\u4e0b\uff0c\u94d1\u539f\u5b50\u5f62\u6210\u5177\u6709\u626d\u66f2\u7684\u5e73\u9762\u65b9\u5f62\u51e0\u4f55\u5f62\u72b6\u7684\u7edc\u5408\u7269\u3002<\/p>\n<p> Wilkinson\u50ac\u5316\u5242\u4e2d\u94d1\u539f\u5b50\u7684\u6742\u5316\u662fsp3d2\u6742\u5316\u3002\u8fd9\u610f\u5473\u7740\u94d1\u539f\u5b50\u4f7f\u75285\u4e2a\u539f\u5b50\u8f68\u9053\uff0c\u5305\u62ec1\u4e2a4s\u8f68\u9053\u30013\u4e2a4p\u8f68\u9053\u548c1\u4e2a4d\u8f68\u9053\uff0c\u5f62\u62105\u4e2asp3d2\u6742\u5316\u8f68\u9053\u3002<\/p>\n<p>\u5728\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u4e2d\uff0c\u4e2d\u5fc3\u94d1\u539f\u5b50\u8fdb\u884c sp3d2 \u6742\u5316\uff0c\u4ea7\u751f\u4e94\u4e2a\u6742\u5316\u8f68\u9053\u3002\u8fd9\u4e9b\u6742\u5316\u8f68\u9053\u4e4b\u4e00\u4e0e\u6c2f\u914d\u4f53\u5f62\u6210\u897f\u683c\u739b\u952e\uff0c\u800c\u5176\u4f59\u56db\u4e2a\u6742\u5316\u8f68\u9053\u4e0e\u4e09\u4e2a\u4e09\u82ef\u57fa\u81a6\u914d\u4f53\u5f62\u6210\u897f\u683c\u739b\u952e\u3002\u94d1\u539f\u5b50\u7684\u4e24\u4e2a 4d \u8f68\u9053\u4e0e\u914d\u4f53\u5f62\u6210 pi \u952e\uff0c\u4ece\u800c\u5b8c\u6210\u914d\u4f4d\u7403\u3002<\/p>\n<p>\u603b\u4f53\u800c\u8a00\uff0cWilkinson \u50ac\u5316\u5242\u4e2d\u94d1\u539f\u5b50\u7684 sp3d2 \u6742\u5316\u53ef\u4ee5\u4e0e\u5176\u5468\u56f4\u7684\u914d\u4f53\u5f62\u6210\u7262\u56fa\u7684\u5316\u5b66\u952e\u5408\uff0c\u8fd9\u5bf9\u4e8e\u5176\u5728\u5404\u79cd\u6709\u673a\u53cd\u5e94\u4e2d\u4f5c\u4e3a\u5747\u76f8\u50ac\u5316\u5242\u7684\u6709\u6548\u6027\u81f3\u5173\u91cd\u8981\u3002<\/p>\n<h6 class=\"wp-block-heading\">\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u7684\u9009\u62e9\u6027<\/h6>\n<p>\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u662f\u4e00\u79cd\u9ad8\u9009\u62e9\u6027\u50ac\u5316\u5242\uff0c\u5e38\u7528\u4e8e\u6709\u673a\u5408\u6210\u4e2d\u4ee5\u8fbe\u5230\u7279\u5b9a\u7684\u53cd\u5e94\u7ed3\u679c\u3002\u8be5\u50ac\u5316\u5242\u7531\u4e8e\u5176\u72ec\u7279\u7684\u7535\u5b50\u548c\u7a7a\u95f4\u7279\u6027\u800c\u8868\u73b0\u51fa\u9ad8\u9009\u62e9\u6027\uff0c\u4f7f\u5176\u80fd\u591f\u533a\u5206\u4e0d\u540c\u7c7b\u578b\u7684\u53cd\u5e94\u7269\u548c\u4e2d\u95f4\u4f53\u3002<\/p>\n<p>\u4f8b\u5982\uff0c\u5728\u6c22\u5316\u53cd\u5e94\u4e2d\uff0c\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u5728\u5176\u4ed6\u5b98\u80fd\u56e2\uff08\u4f8b\u5982 C=O \u548c C\u2261C \u952e\uff09\u5b58\u5728\u4e0b\u5bf9 C=C \u952e\u7684\u8fd8\u539f\u8868\u73b0\u51fa\u9ad8\u9009\u62e9\u6027\u3002 \u3002\u8fd9\u79cd\u9009\u62e9\u6027\u6e90\u4e8e\u94f1\u79bb\u5b50\u7684\u7535\u5b50\u7279\u6027\uff0c\u4f7f\u5176\u80fd\u591f\u4f18\u5148\u4e0e C=C \u952e\u76f8\u4e92\u4f5c\u7528\u5e76\u4fc3\u8fdb\u5176\u8fd8\u539f\u3002<\/p>\n<p>\u7c7b\u4f3c\u5730\uff0c\u5728\u52a0\u6c22\u7532\u9170\u5316\u53cd\u5e94\u4e2d\uff0c\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u8868\u73b0\u51fa\u5bf9\u5f62\u6210\u76f4\u94fe\u919b\u800c\u4e0d\u662f\u652f\u94fe\u6216\u73af\u72b6\u919b\u7684\u9009\u62e9\u6027\u3002\u8fd9\u79cd\u9009\u62e9\u6027\u6e90\u4e8e\u914d\u4f53\u7684\u7a7a\u95f4\u7279\u6027\uff0c\u8fd9\u6709\u52a9\u4e8e\u63a7\u5236\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u53cd\u5e94\u7269\u548c\u4e2d\u95f4\u4f53\u7684\u65b9\u5411\u3002<\/p>\n<h6 class=\"wp-block-heading\">\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u516c\u5f0f<\/h6>\n<p>\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u7684\u5206\u5b50\u5f0f\u4e3aRhCl(PPh3)3\uff0c\u4ee3\u8868\u94d1\u539f\u5b50(Rh)\u3001\u6c2f\u79bb\u5b50(Cl)\u548c\u4e09\u4e2a\u4e09\u82ef\u57fa\u81a6\u914d\u4f53(PPh3)\u4e4b\u95f4\u5f62\u6210\u7684\u7edc\u5408\u7269\u3002<\/p>\n<p>\u5728\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242\u4e2d\uff0c\u94d1\u539f\u5b50\u4e3b\u52a8\u8868\u73b0\u51fa+1\u6c27\u5316\u6001\uff0c\u5e76\u4e0e\u6c2f\u79bb\u5b50\u548c\u4e09\u4e2a\u4e09\u82ef\u57fa\u81a6\u914d\u4f53\u5f62\u6210\u914d\u4f4d\u952e\u3002\u6c2f\u79bb\u5b50\u548c\u4e09\u82ef\u57fa\u81a6\u914d\u4f53\u5145\u5f53\u7535\u5b50\u4f9b\u4f53\uff0c\u5e76\u901a\u8fc7\u4e0e\u94d1\u539f\u5b50\u76f8\u4e92\u4f5c\u7528\u6765\u4e3b\u52a8\u7a33\u5b9a\u7edc\u5408\u7269\u3002<\/p>\n<p>\u4e09\u82ef\u57fa\u81a6\u914d\u4f53\u7531\u8fde\u63a5\u5230\u4e2d\u5fc3\u78f7\u539f\u5b50\u7684\u4e09\u4e2a\u82ef\u73af\u7ec4\u6210\uff0c\u8be5\u4e2d\u5fc3\u78f7\u539f\u5b50\u4e0e\u94d1\u539f\u5b50\u952e\u5408\u3002\u8fd9\u4e9b\u914d\u4f53\u5728\u7a33\u5b9a\u914d\u5408\u7269\u5e76\u5f71\u54cd\u5176\u5728\u5404\u79cd\u6709\u673a\u53cd\u5e94\u4e2d\u7684\u53cd\u5e94\u6027\u65b9\u9762\u53d1\u6325\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002<\/p>\n<p> Wilkinson \u50ac\u5316\u5242\u7684\u603b\u4f53\u5f0f RhCl(PPh3)3 \u8868\u660e\u4e86\u914d\u5408\u7269\u7684\u5316\u5b66\u8ba1\u91cf\u4ee5\u53ca\u6240\u6d89\u53ca\u7684\u914d\u4f53\u548c\u4e2d\u5fc3\u91d1\u5c5e\u539f\u5b50\u7684\u6027\u8d28\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Wilkinson \u50ac\u5316\u5242\u6216 RhCl(PPh3)2 \u662f\u4e00\u79cd\u975e\u5e38\u6d3b\u8dc3\u7684\u5747\u76f8\u50ac\u5316\u5242\uff0c\u7528\u4e8e\u6709\u673a\u5408\u6210\uff0c\u7279\u522b\u662f\u6c22\u5316\u53cd\u5e94 &#8230; <a title=\"\u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242 \u2013 rhcl(pph3)2, 14694-95-2\" class=\"read-more\" href=\"https:\/\/chemuza.org\/cn\/%e5%a8%81%e5%b0%94%e9%87%91%e6%a3%ae%e5%82%ac%e5%8c%96%e5%89%82\/\" aria-label=\"\u66f4\u591a \u5a01\u5c14\u91d1\u68ee\u50ac\u5316\u5242 \u2013 rhcl(pph3)2, 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