{"id":412,"date":"2023-07-23T12:23:32","date_gmt":"2023-07-23T12:23:32","guid":{"rendered":"https:\/\/chemuza.org\/cn\/%e8%8b%84%e5%9f%bac14h12o2\/"},"modified":"2023-07-23T12:23:32","modified_gmt":"2023-07-23T12:23:32","slug":"%e8%8b%84%e5%9f%bac14h12o2","status":"publish","type":"post","link":"https:\/\/chemuza.org\/cn\/%e8%8b%84%e5%9f%bac14h12o2\/","title":{"rendered":"\u8054\u82ef \u2013 c14h12o2"},"content":{"rendered":"<p>Benzil \u6216 C14H10O2 \u662f\u4e00\u79cd\u9ec4\u8272\u7ed3\u6676\u6709\u673a\u5316\u5408\u7269\uff0c\u7528\u4f5c\u67d3\u6599\u5408\u6210\u7684\u524d\u4f53\u548c\u805a\u5408\u7269\u5316\u5b66\u4e2d\u7684\u5149\u5f15\u53d1\u5242\u3002\u5b83\u8fd8\u53ef\u4ee5\u5145\u5f53\u8fd8\u539f\u5242\uff0c\u5e76\u4e14\u662f\u5f62\u6210\u4e8c\u82ef\u4e59\u9187\u9178\u7684\u4e2d\u95f4\u4f53\u3002<\/p>\n<figure class=\"wp-block-table\">\n<table>\n<tbody>\n<tr>\n<td><strong>\u56fd\u9645\u7eaf\u7cb9\u548c\u5e94\u7528\u5316\u5b66\u8054\u5408\u4f1a\u540d\u79f0<\/strong><\/td>\n<td>1,2-\u4e8c\u82ef\u57fa-1,2-\u4e8c\u7fa7\u57fa\u4e59\u70ef<\/td>\n<\/tr>\n<tr>\n<td><strong>\u5206\u5b50\u5f0f<\/strong><\/td>\n<td>C14H10O2<\/td>\n<\/tr>\n<tr>\n<td> <strong>CAS \u53f7<\/strong><\/td>\n<td>134-81-6<\/td>\n<\/tr>\n<tr>\n<td><strong>\u540c\u4e49\u8bcd<\/strong><\/td>\n<td>1,2-\u4e8c\u82ef\u57fa-1,2-\u4e19\u4e8c\u916e\u30011,2-\u4e8c\u82ef\u57fa\u4e59\u4e8c\u916e\u3001\u82ef\u5076\u9170\u3001\u82ef\u5076\u9170<\/td>\n<\/tr>\n<tr>\n<td><strong>\u4e59\u9170\u80c6\u78b1<\/strong><\/td>\n<td>InChI=1S\/C14H10O2\/c15-13(14(16)17)11-6-8-12(9-7-11)10-5-3-1-2-4-6\/h1-9H,10- 17H2<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n<h6 class=\"wp-block-heading\">\u82c4\u57fa\u5206\u5b50\u91cf<\/h6>\n<p>\u82ef\u5076\u9170\u7684\u5206\u5b50\u91cf\u4e3a210.24 g\/mol\u3002\u5b83\u662f\u82ef\u5076\u9170\u5206\u5b50\u4e2d\u6240\u6709\u539f\u5b50\u7684\u539f\u5b50\u8d28\u91cf\u4e4b\u548c\u3002\u82ef\u5076\u9170\u7684\u5206\u5b50\u91cf\u662f\u6839\u636e\u5176\u5206\u5b50\u5f0f C14H10O2 \u8ba1\u7b97\u7684\u3002<\/p>\n<h6 class=\"wp-block-heading\">\u82ef\u82ef\u5bc6\u5ea6 g\/mL<\/h6>\n<p>\u82ef\u5076\u9170\u7684\u5bc6\u5ea6\u4e3a1.20 g\/mL\u3002\u5b83\u662f\u7269\u8d28\u6bcf\u5355\u4f4d\u4f53\u79ef\u8d28\u91cf\u7684\u6d4b\u91cf\u3002\u82ef\u5076\u6c2e\u7684\u5bc6\u5ea6\u76f8\u5bf9\u8f83\u4f4e\uff0c\u4e0e\u5176\u4ed6\u5bc6\u5ea6\u8f83\u9ad8\u7684\u7269\u8d28\u76f8\u6bd4\u66f4\u5bb9\u6613\u5904\u7406\u3002<\/p>\n<h6 class=\"wp-block-heading\">\u82c4\u57fa\u7684\u6cb8\u70b9<\/h6>\n<p>\u6c7d\u6cb9\u7684\u6cb8\u70b9\u4e3a 350\u00b0C (662\u00b0F)\u3002\u5b83\u662f\u6db2\u4f53\u7684\u84b8\u6c14\u538b\u7b49\u4e8e\u5927\u6c14\u538b\u529b\u5e76\u4e14\u6db2\u4f53\u8f6c\u53d8\u4e3a\u84b8\u6c14\u65f6\u7684\u6e29\u5ea6\u3002\u7269\u8d28\u7684\u6cb8\u70b9\u53d6\u51b3\u4e8e\u538b\u529b\u3001\u5206\u5b50\u91cf\u548c\u5206\u5b50\u95f4\u529b\u7b49\u591a\u79cd\u56e0\u7d20\u3002<\/p>\n<h6 class=\"wp-block-heading\">\u82c4\u57fa\u7194\u70b9<\/h6>\n<p>\u82ef\u5076\u9170\u7684\u7194\u70b9\u4e3a 98\u00b0C (270\u00b0F)\u3002\u8fd9\u662f\u56fa\u4f53\u53d8\u6210\u6db2\u4f53\u7684\u6e29\u5ea6\u3002\u82ef\u5076\u9170\u7684\u7194\u70b9\u76f8\u5bf9\u8f83\u4f4e\uff0c\u4f7f\u5176\u6210\u4e3a\u6709\u673a\u5408\u6210\u4e2d\u6709\u7528\u7684\u4e2d\u95f4\u4f53\u3002<\/p>\n<h6 class=\"wp-block-heading\">\u82ef\u82ef\u6469\u5c14\u8d28\u91cf<\/h6>\n<p>C14H10O2 \u7684\u6469\u5c14\u8d28\u91cf\u4e3a 210.24 g\/mol\u3002\u5b83\u662f\u542b\u6709\u4e0e12\u514b\u7eaf\u78b312\u4e2d\u542b\u6709\u7684\u5b9e\u4f53\u6570\u91cf\u76f8\u540c\u6570\u91cf\u7684\u5b9e\u4f53\uff08\u4f8b\u5982\u539f\u5b50\u3001\u5206\u5b50\u3001\u79bb\u5b50\uff09\u7684\u7269\u8d28\u7684\u91cf\u3002\u82ef\u5076\u9170\u7684\u6469\u5c14\u8d28\u91cf\u6839\u636e\u5176\u5206\u5b50\u5f0f C14H10O2 \u8ba1\u7b97\u3002 <\/p>\n<div class=\"wp-block-image\">\n<figure class=\"alignright size-large is-resized\"><img decoding=\"async\" loading=\"lazy\" src=\"https:\/\/chemuza.org\/wp-content\/uploads\/2023\/08\/benzil.jpg\" alt=\"\u82ef\u7532\u9170\" width=\"232\" height=\"175\" srcset=\"\" sizes=\"auto, \"><\/figure>\n<\/div>\n<h6 class=\"wp-block-heading\">\u82c4\u57fa\u7684\u7ed3\u6784<\/h6>\n<p>\u82ef\u5076\u9170\u662f\u4e00\u79cd\u9ec4\u8272\u7ed3\u6676\u6709\u673a\u5316\u5408\u7269\uff0c\u5206\u5b50\u5f0f\u4e3aC14H10O2\u3002\u5b83\u662f\u7531\u4e24\u4e2a\u8fde\u63a5\u5230\u4e2d\u5fc3\u78b3\u78b3\u53cc\u952e\u7684\u82ef\u57fa\u7ec4\u6210\u7684\u4e8c\u916e\u3002\u5206\u5b50\u662f\u5e73\u9762\u7684\uff0c\u53cc\u952e\u4e5f\u662f\u5e73\u9762\u7684\u3002\u82ef\u5076\u9170\u5206\u5b50\u5177\u6709\u7279\u6709\u7684\u4eae\u9ec4\u8272\uff0c\u4f7f\u5176\u53ef\u7528\u4f5c\u5206\u6790\u5316\u5b66\u4e2d\u7684\u53c2\u8003\u5316\u5408\u7269\u3002<\/p>\n<h6 class=\"wp-block-heading\">\u8054\u82ef\u5206\u5b50\u5f0f<\/h6>\n<p>\u82ef\u5076\u9170\u7684\u5316\u5b66\u5f0f\u662fC14H10O2\u3002\u5b83\u4ee3\u8868\u82ef\u5076\u9170\u7684\u7ec4\u6210\u5143\u7d20\u53ca\u5176\u76f8\u5bf9\u6bd4\u4f8b\u3002\u8be5\u5f0f\u8868\u660e\u82ef\u5076\u9170\u753114\u4e2a\u78b3\u539f\u5b50\u300112\u4e2a\u6c22\u539f\u5b50\u548c2\u4e2a\u6c27\u539f\u5b50\u7ec4\u6210\u3002<\/p>\n<h6 class=\"wp-block-heading\">\u82ef\u5076\u6c2e\u6838\u78c1\u5171\u632f\u56fe<\/h6>\n<p>C14H10O2 \u53ef\u4ee5\u901a\u8fc7\u6838\u78c1\u5171\u632f (NMR) \u5149\u8c31\u8fdb\u884c\u5206\u6790\u3002\u6838\u78c1\u5171\u632f\u6ce2\u8c31\u662f\u4e00\u79cd\u5f3a\u5927\u7684\u5de5\u5177\uff0c\u53ef\u4ee5\u63d0\u4f9b\u6709\u5173\u5206\u5b50\u5316\u5b66\u7ed3\u6784\u548c\u76f8\u4e92\u4f5c\u7528\u7684\u4fe1\u606f\u3002\u5728\u6838\u78c1\u5171\u632f\u6ce2\u8c31\u4e2d\uff0c\u539f\u5b50\u6838\u7684\u78c1\u6027\u7528\u4e8e\u786e\u5b9a\u539f\u5b50\u6838\u7684\u5316\u5b66\u73af\u5883\u5e76\u83b7\u53d6\u6709\u5173\u5206\u5b50\u7684\u952e\u5408\u548c\u5316\u5b66\u4f4d\u79fb\u7684\u4fe1\u606f\u3002 C14H10O2 NMR\u8c31\u63d0\u4f9b\u4e86\u6709\u5173\u5206\u5b50\u4e2d\u8d28\u5b50\u6570\u548c\u6bcf\u4e2a\u8d28\u5b50\u7684\u5316\u5b66\u73af\u5883\u7684\u4fe1\u606f\uff0c\u6709\u52a9\u4e8e\u786e\u8ba4C14H10O2\u7684\u7ed3\u6784\u3002<\/p>\n<figure class=\"wp-block-table\">\n<table>\n<tbody>\n<tr>\n<td><strong>\u5916\u8c8c<\/strong><\/td>\n<td>\u9ec4\u8272\u7ed3\u6676\u56fa\u4f53<\/td>\n<\/tr>\n<tr>\n<td><strong>\u6bd4\u91cd<\/strong><\/td>\n<td>1.20\u514b\/\u6beb\u5347<\/td>\n<\/tr>\n<tr>\n<td><strong>\u989c\u8272<\/strong><\/td>\n<td>\u9ec4\u8272\u7684<\/td>\n<\/tr>\n<tr>\n<td><strong>\u95fb<\/strong><\/td>\n<td>\u65e0\u5473<\/td>\n<\/tr>\n<tr>\n<td><strong>\u6469\u5c14\u8d28\u91cf<\/strong><\/td>\n<td>210.24 \u514b\/\u6469\u5c14<\/td>\n<\/tr>\n<tr>\n<td><strong>\u5bc6\u5ea6<\/strong><\/td>\n<td>1.20\u514b\/\u6beb\u5347<\/td>\n<\/tr>\n<tr>\n<td><strong>\u878d\u5408\u70b9<\/strong><\/td>\n<td>94.8\u2103<\/td>\n<\/tr>\n<tr>\n<td><strong>\u6cb8\u70b9<\/strong><\/td>\n<td>350\u00b0C (662\u00b0F)<\/td>\n<\/tr>\n<tr>\n<td><strong>\u95ea\u70b9<\/strong><\/td>\n<td>\u65e0\u6cd5\u4f7f\u7528<\/td>\n<\/tr>\n<tr>\n<td><strong>\u6c34\u4e2d\u6eb6\u89e3\u5ea6<\/strong><\/td>\n<td>\u5fae\u6eb6\u4e8e\u6c34<\/td>\n<\/tr>\n<tr>\n<td><strong>\u6eb6\u89e3\u5ea6<\/strong><\/td>\n<td>\u6eb6\u4e8e\u4e59\u9187\u3001\u4e59\u919a<\/td>\n<\/tr>\n<tr>\n<td><strong>\u84b8\u6c7d\u538b\u529b<\/strong><\/td>\n<td>\u65e0\u6cd5\u4f7f\u7528<\/td>\n<\/tr>\n<tr>\n<td><strong>\u84b8\u6c14\u5bc6\u5ea6<\/strong><\/td>\n<td>\u65e0\u6cd5\u4f7f\u7528<\/td>\n<\/tr>\n<tr>\n<td><strong>\u9178\u5ea6<\/strong><\/td>\n<td>\u65e0\u6cd5\u4f7f\u7528<\/td>\n<\/tr>\n<tr>\n<td><strong>\u9178\u78b1\u5ea6<\/strong><\/td>\n<td>\u65e0\u6cd5\u4f7f\u7528<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n<h5 class=\"wp-block-heading\"><strong>\u82c4\u57fa\u7684\u5b89\u5168\u6027\u548c\u5371\u9669\u6027<\/strong><\/h5>\n<p>C14H10O2 \u88ab\u8ba4\u4e3a\u662f\u4e2d\u7b49\u6bd2\u6027\u7269\u8d28\uff0c\u5e94\u5c0f\u5fc3\u5904\u7406\u3002\u5b83\u9ad8\u5ea6\u6613\u71c3\uff0c\u5e94\u8fdc\u79bb\u70ed\u6e90\u548c\u706b\u82b1\u3002\u5438\u5165 C14H10O2 \u84b8\u6c14\u53ef\u80fd\u4f1a\u5f15\u8d77\u773c\u775b\u3001\u9f3b\u5b50\u548c\u5589\u5499\u523a\u6fc0\u4ee5\u53ca\u547c\u5438\u7cfb\u7edf\u95ee\u9898\u3002\u76ae\u80a4\u63a5\u89e6 C14H10O2 \u53ef\u80fd\u4f1a\u5bfc\u81f4\u76ae\u80a4\u523a\u6fc0\u548c\u53d1\u7ea2\u3002\u6444\u5165 C14H10O2 \u53ef\u80fd\u4f1a\u5f15\u8d77\u80c3\u523a\u6fc0\u548c\u6d88\u5316\u95ee\u9898\u3002\u5982\u679c\u5927\u91cf\u6444\u5165\uff0c\u53ef\u80fd\u4f1a\u5bfc\u81f4\u66f4\u4e25\u91cd\u7684\u5065\u5eb7\u95ee\u9898\uff0c\u4f8b\u5982\u5455\u5410\u3001\u5934\u6655\u548c\u610f\u8bc6\u4e27\u5931\u3002\u5904\u7406 C14H10O2 \u65f6\uff0c\u52a1\u5fc5\u4f69\u6234\u9632\u62a4\u624b\u5957\u548c\u62a4\u76ee\u955c\uff0c\u5e76\u5728\u901a\u98ce\u826f\u597d\u7684\u533a\u57df\u5de5\u4f5c\uff0c\u4ee5\u5c3d\u91cf\u51cf\u5c11\u63a5\u89e6\u3002\u5982\u679c\u63a5\u89e6C14H10O2\u540e\u51fa\u73b0\u4e0d\u826f\u53cd\u5e94\uff0c\u5efa\u8bae\u7acb\u5373\u54a8\u8be2\u533b\u751f\u3002<\/p>\n<figure class=\"wp-block-table\">\n<table>\n<tbody>\n<tr>\n<td><strong>\u5371\u9669\u7b26\u53f7<\/strong><\/td>\n<td>\u6613\u71c3<\/td>\n<\/tr>\n<tr>\n<td><strong>\u5b89\u5168\u8bf4\u660e<\/strong><\/td>\n<td>S24\/25 \u2013 \u907f\u514d\u63a5\u89e6\u76ae\u80a4\u548c\u773c\u775b<\/td>\n<\/tr>\n<tr>\n<td><strong>\u8054\u5408\u56fd\u8bc6\u522b\u53f7<\/strong><\/td>\n<td>UN2024 \u2013 \u5371\u9669\u54c1\uff0c\u5371\u9669\u7b49\u7ea7 3<\/td>\n<\/tr>\n<tr>\n<td><strong>\u6d77\u5173\u7f16\u7801<\/strong><\/td>\n<td>2915.90.90<\/td>\n<\/tr>\n<tr>\n<td><strong>\u5371\u9669\u7b49\u7ea7<\/strong><\/td>\n<td>3 \u2013 \u6613\u71c3\u6db2\u4f53<\/td>\n<\/tr>\n<tr>\n<td><strong>\u5305\u88c5\u7ec4\u522b<\/strong><\/td>\n<td>III \u2013 \u4e2d\u7b49\u98ce\u9669<\/td>\n<\/tr>\n<tr>\n<td><strong>\u6bd2\u6027<\/strong><\/td>\n<td>\u4e2d\u5ea6\u6bd2\u6027<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n<h5 class=\"wp-block-heading\"><strong>\u82ef\u5076\u9170\u7684\u5408\u6210\u65b9\u6cd5<\/strong><\/h5>\n<p>C14H10O2 \u53ef\u4ee5\u901a\u8fc7\u591a\u79cd\u65b9\u6cd5\u5408\u6210\uff0c\u5305\u62ec\uff1a<\/p>\n<ul>\n<li>\u4e8c\u82ef\u7532\u9187\u7684\u6c27\u5316\uff1a\u4e8c\u82ef\u7532\u9187\u7528\u4e09\u6c27\u5316\u94ec\u6c27\u5316\u5f62\u6210C14H10O2\u3002\u8fd9\u662f\u5408\u6210 C14H10O2 \u4e2d\u5e38\u7528\u7684\u65b9\u6cd5\uff0c\u56e0\u4e3a\u5b83\u7b80\u5355\u4e14\u6210\u672c\u6548\u76ca\u9ad8\u3002<\/li>\n<li>\u74e6\u514b\u6c27\u5316\uff1a\u8be5\u65b9\u6cd5\u6d89\u53ca\u4f7f\u7528\u94af\u50ac\u5316\u5242\u548c\u6c22\u8fc7\u6c27\u5316\u7269\u6c27\u5316\u5242\u5c06\u70ef\u70c3\u8f6c\u5316\u4e3a C14H10O2\u3002\u8be5\u53cd\u5e94\u901a\u5e38\u5728\u6eb6\u5242\u5982\u4e59\u9187\u6216\u6c34\u7684\u5b58\u5728\u4e0b\u8fdb\u884c\u3002<\/li>\n<li> Knoevenagel\u7f29\u5408\uff1a\u5728\u8be5\u65b9\u6cd5\u4e2d\uff0c\u82ef\u7532\u919b\u548c\u5df4\u6bd4\u59a5\u9178\u5728\u5f3a\u78b1\uff08\u4f8b\u5982\u6c22\u6c27\u5316\u94a0\u6216\u6c22\u6c27\u5316\u94be\uff09\u5b58\u5728\u4e0b\u53cd\u5e94\u5408\u6210C14H10O2\u3002<\/li>\n<li>\u4e4c\u5c14\u66fc\u53cd\u5e94\uff1a\u8be5\u65b9\u6cd5\u6d89\u53ca\u901a\u8fc7\u94dc\u50ac\u5316\u53cd\u5e94\u5076\u8054\u4e24\u79cd\u82b3\u9999\u65cf\u5316\u5408\u7269\u3002\u5728C14H10O2\u7684\u5408\u6210\u4e2d\uff0c\u4e24\u4e2a\u82ef\u7532\u919b\u5206\u5b50\u53cd\u5e94\u5f62\u6210C14H10O2\u3002<\/li>\n<li> Baeyer-Villiger \u6c27\u5316\uff1a\u5728\u6b64\u65b9\u6cd5\u4e2d\uff0c\u5728\u8fc7\u6c27\u9178\u6c27\u5316\u5242\u548c\u50ac\u5316\u91cf\u7684\u53d4\u80fa\u5b58\u5728\u4e0b\uff0c\u901a\u8fc7\u5c06\u73af\u5df1\u916e\u6c27\u5316\u4e3a C14H10O2 \u6765\u5408\u6210 C14H10O2\u3002<\/li>\n<\/ul>\n<p> C14H10O2 \u5408\u6210\u65b9\u6cd5\u7684\u9009\u62e9\u53d6\u51b3\u4e8e\u591a\u79cd\u56e0\u7d20\uff0c\u5305\u62ec\u539f\u6750\u6599\u7684\u53ef\u7528\u6027\u3001\u6240\u9700\u7684\u4ea7\u54c1\u6536\u7387\u548c\u7eaf\u5ea6\uff0c\u4ee5\u53ca\u5408\u6210\u8fc7\u7a0b\u4e2d\u6d89\u53ca\u7684\u6210\u672c\u548c\u65f6\u95f4\u3002<\/p>\n<h5 class=\"wp-block-heading\"><strong>\u82c4\u57fa\u7684\u7528\u9014<\/strong><\/h5>\n<p>C14H10O2 \u662f\u4e00\u79cd\u591a\u529f\u80fd\u5316\u5b66\u54c1\uff0c\u5728\u5404\u4e2a\u9886\u57df\u90fd\u6709\u591a\u79cd\u7528\u9014\u3002 C14H10O2 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