{"id":1305,"date":"2023-07-20T04:02:59","date_gmt":"2023-07-20T04:02:59","guid":{"rendered":"https:\/\/chemuza.org\/cn\/2-%e5%b7%b1%e9%86%87-c6h14o-2\/"},"modified":"2023-07-20T04:02:59","modified_gmt":"2023-07-20T04:02:59","slug":"2-%e5%b7%b1%e9%86%87-c6h14o-2","status":"publish","type":"post","link":"https:\/\/chemuza.org\/cn\/2-%e5%b7%b1%e9%86%87-c6h14o-2\/","title":{"rendered":"2-\u5df1\u9187 \u2013 c6h14o, 626-93-7"},"content":{"rendered":"<p>2-\u5df1\u9187\u662f\u5177\u6709\u516d\u4e2a\u78b3\u539f\u5b50\u7684\u9187\u3002\u5b83\u7684\u7b2c\u4e8c\u4e2a\u78b3\u539f\u5b50\u4e0a\u8fde\u63a5\u6709\u4e00\u4e2a\u7f9f\u57fa (-OH)\uff0c\u4f7f\u5176\u53ef\u7528\u4e8e\u5404\u79cd\u5de5\u4e1a\u5e94\u7528\u548c\u4f5c\u4e3a\u9999\u6599\u6210\u5206\u3002<\/p>\n<figure class=\"wp-block-table\">\n<table>\n<tbody>\n<tr>\n<td>\u56fd\u9645\u7eaf\u7cb9\u548c\u5e94\u7528\u5316\u5b66\u8054\u5408\u4f1a\u540d\u79f0<\/td>\n<td>2-\u5df1\u9187<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u5f0f<\/td>\n<td>C6H14O<\/td>\n<\/tr>\n<tr>\n<td> CAS \u53f7<\/td>\n<td>626-93-7<\/td>\n<\/tr>\n<tr>\n<td>\u540c\u4e49\u8bcd<\/td>\n<td>2-\u5df1\u9187\u3001\u6b63\u5df1\u9187\u3001\u5df1\u9187<\/td>\n<\/tr>\n<tr>\n<td>\u4e59\u9170\u80c6\u78b1<\/td>\n<td>InChI=1S\/C6H14O\/c1-3-5-6(7)4-2\/h6-7H,3-5H2,1-2H3<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n<h2 class=\"wp-block-heading\"> <strong>2-\u5df1\u9187\u7684\u6027\u8d28<\/strong><\/h2>\n<h3 class=\"wp-block-heading\">2-\u5df1\u9187\u7ed3\u6784\u5f0f<\/h3>\n<p>2-\u5df1\u9187\u7684\u5316\u5b66\u5f0f\u662fC6H14O\u3002\u5b83\u7531\u516d\u4e2a\u78b3\u539f\u5b50\u3001\u5341\u56db\u4e2a\u6c22\u539f\u5b50\u548c\u4e00\u4e2a\u6c27\u539f\u5b50\u7ec4\u6210\u3002\u8be5\u516c\u5f0f\u4ee3\u8868\u4e86\u5206\u5b50\u7684\u786e\u5207\u7ec4\u6210\uff0c\u63d0\u4f9b\u4e86\u6709\u5173\u5176\u5143\u7d20\u6210\u5206\u7684\u6709\u4ef7\u503c\u7684\u4fe1\u606f\u3002<\/p>\n<h3 class=\"wp-block-heading\"> 2-\u5df1\u9187 \u6469\u5c14\u8d28\u91cf<\/h3>\n<p>2-\u5df1\u9187\u7684\u6469\u5c14\u8d28\u91cf\u901a\u8fc7\u6dfb\u52a0\u5176\u6240\u6709\u7ec4\u6210\u539f\u5b50\u7684\u539f\u5b50\u8d28\u91cf\u6765\u8ba1\u7b97\u3002 2-\u5df1\u9187\u6709 6 \u4e2a\u78b3\u539f\u5b50\u300114 \u4e2a\u6c22\u539f\u5b50\u548c 1 \u4e2a\u6c27\u539f\u5b50\uff0c\u5176\u6469\u5c14\u8d28\u91cf\u7ea6\u4e3a 102.18 \u514b\/\u6469\u5c14\u3002\u8be5\u503c\u5bf9\u4e8e\u5404\u79cd\u5316\u5b66\u8ba1\u7b97\u548c\u8f6c\u6362\u81f3\u5173\u91cd\u8981\u3002<\/p>\n<h3 class=\"wp-block-heading\"> 2-\u5df1\u9187\u7684\u6cb8\u70b9<\/h3>\n<p>2-\u5df1\u9187\u7684\u6cb8\u70b9\u662f\u5728\u6807\u51c6\u5927\u6c14\u538b\u4e0b\u4ece\u6db2\u4f53\u53d8\u6210\u6c14\u4f53\u7684\u6e29\u5ea6\u3002 2-\u5df1\u9187\u7684\u6cb8\u70b9\u7ea6\u4e3a 157 \u81f3 158 \u6444\u6c0f\u5ea6\uff08315 \u81f3 316 \u534e\u6c0f\u5ea6\uff09\u3002\u8fd9\u79cd\u76f8\u5bf9\u8f83\u9ad8\u7684\u6cb8\u70b9\u4f7f\u5176\u9002\u5408\u9700\u8981\u8010\u70ed\u6027\u7684\u5e94\u7528\u3002<\/p>\n<h3 class=\"wp-block-heading\"> 2-\u5df1\u9187\u7194\u70b9<\/h3>\n<p>2-\u5df1\u9187\u7684\u7194\u70b9\u662f\u5b83\u4ece\u56fa\u6001\u8f6c\u53d8\u4e3a\u6db2\u6001\u7684\u6e29\u5ea6\u3002 hexan-2-ol \u7684\u7194\u70b9\u7ea6\u4e3a -47 \u6444\u6c0f\u5ea6\uff08-53 \u534e\u6c0f\u5ea6\uff09\u3002\u8fd9\u79cd\u4f4e\u7194\u70b9\u8868\u660e\u5b83\u5728\u5927\u591a\u6570\u6b63\u5e38\u5ba4\u6e29\u4e0b\u662f\u6db2\u4f53\u3002<\/p>\n<h3 class=\"wp-block-heading\"> 2-\u5df1\u9187\u5bc6\u5ea6 g\/mL<\/h3>\n<p> 2-\u5df1\u9187\u7684\u5bc6\u5ea6\u662f\u6307\u5355\u4f4d\u4f53\u79ef\u5185\u8be5\u7269\u8d28\u7684\u8d28\u91cf\u3002 2-\u5df1\u9187\u7684\u5bc6\u5ea6\u7ea6\u4e3a 0.811 \u514b\u6bcf\u6beb\u5347 (g\/mL)\u3002\u901a\u8fc7\u8be5\u5bc6\u5ea6\u503c\u53ef\u4ee5\u4e86\u89e3\u7269\u8d28\u7684\u81f4\u5bc6\u7a0b\u5ea6\u6216\u6d53\u5ea6\u3002<\/p>\n<h3 class=\"wp-block-heading\"> 2-\u5df1\u9187\u5206\u5b50\u91cf<\/h3>\n<p>2-\u5df1\u9187\u7684\u5206\u5b50\u91cf\u662f\u5176\u5316\u5b66\u5f0f\u4e2d\u6240\u6709\u539f\u5b50\u7684\u539f\u5b50\u91cf\u4e4b\u548c\u3002 2-\u5df1\u9187\u7684\u5206\u5b50\u5f0f\u4e3aC6H14O\uff0c\u5176\u5206\u5b50\u91cf\u7ea6\u4e3a102.18\u514b\/\u6469\u5c14\u3002\u8be5\u503c\u7528\u4e8e\u5404\u79cd\u5316\u5b66\u8ba1\u7b97\u548c\u6d4b\u91cf\u3002<\/p>\n<h3 class=\"wp-block-heading\"> 2-\u5df1\u9187\u7684\u7ed3\u6784<\/h3>\n<div class=\"wp-block-image\">\n<figure class=\"alignright size-large\"><img decoding=\"async\" src=\"https:\/\/chemuza.org\/wp-content\/uploads\/2023\/08\/2-hexanol.jpg\" alt=\"2-\u5df1\u9187\" srcset=\"\" sizes=\"\"><\/figure>\n<\/div>\n<p> 2-\u5df1\u9187\u7684\u7ed3\u6784\u7531\u516d\u78b3\u94fe\u7ec4\u6210\uff0c\u7b2c\u4e8c\u4e2a\u78b3\u539f\u5b50\u4e0a\u8fde\u63a5\u6709\u7f9f\u57fa\uff08-OH\uff09\u3002\u8fd9\u79cd\u6392\u5217\u8d4b\u4e88\u4e86\u5b83\u7279\u6709\u7684\u6027\u8d28\u548c\u53cd\u5e94\u6027\u3002\u8be5\u7ed3\u6784\u53ef\u4ee5\u53ef\u89c6\u5316\u4e3a\u76f4\u94fe\uff0c\u7f9f\u57fa\u5728\u7b2c\u4e8c\u4e2a\u78b3\u4f4d\u7f6e\u4e0a\u652f\u5316\u3002<\/p>\n<h3 class=\"wp-block-heading\"> 2-\u5df1\u9187\u7684\u6eb6\u89e3\u5ea6<\/h3>\n<p>2-\u5df1\u9187\u9002\u5ea6\u6eb6\u4e8e\u6c34\u3002\u7531\u4e8e\u7f9f\u57fa\u7684\u5b58\u5728\uff0c\u5b83\u53ef\u4ee5\u5728\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u4e0e\u6c34\u6df7\u5408\u3002\u7136\u800c\uff0c\u5176\u6eb6\u89e3\u5ea6\u968f\u7740\u78b3\u94fe\u957f\u5ea6\u7684\u589e\u52a0\u800c\u964d\u4f4e\u3002\u8f83\u6613\u6eb6\u4e8e\u4e59\u9187\u3001\u4e19\u916e\u3001\u6c2f\u4eff\u7b49\u6709\u673a\u6eb6\u5242\u3002 2-\u5df1\u9187\u5728\u4e0d\u540c\u6eb6\u5242\u4e2d\u7684\u6eb6\u89e3\u5ea6\u5f71\u54cd\u5176\u5728\u5404\u79cd\u7cfb\u7edf\u4e2d\u7684\u5e94\u7528\u548c\u884c\u4e3a\u3002<\/p>\n<figure class=\"wp-block-table\">\n<table>\n<tbody>\n<tr>\n<td>\u5916\u8c8c<\/td>\n<td>\u65e0\u8272\u6db2\u4f53<\/td>\n<\/tr>\n<tr>\n<td>\u6bd4\u91cd<\/td>\n<td>0.811\u514b\/\u6beb\u5347<\/td>\n<\/tr>\n<tr>\n<td>\u989c\u8272<\/td>\n<td>\u65e0\u8272<\/td>\n<\/tr>\n<tr>\n<td>\u95fb<\/td>\n<td>\u7279\u5f81\u6c14\u5473<\/td>\n<\/tr>\n<tr>\n<td>\u6469\u5c14\u8d28\u91cf<\/td>\n<td>102.18 \u514b\/\u6469\u5c14<\/td>\n<\/tr>\n<tr>\n<td>\u5bc6\u5ea6<\/td>\n<td>0.811\u514b\/\u6beb\u5347<\/td>\n<\/tr>\n<tr>\n<td>\u878d\u5408\u70b9<\/td>\n<td>-47\u00b0C (-53\u00b0F)<\/td>\n<\/tr>\n<tr>\n<td>\u6cb8\u70b9<\/td>\n<td>157-158\u00b0C (315-316\u00b0F)<\/td>\n<\/tr>\n<tr>\n<td>\u95ea\u70b9<\/td>\n<td>58\u00b0C\uff08136\u00b0F\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u6c34\u4e2d\u6eb6\u89e3\u5ea6<\/td>\n<td>\u4e2d\u7b49\u6eb6\u89e3\u5ea6<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u5ea6<\/td>\n<td>\u6eb6\u4e8e\u4e59\u9187\u3001\u4e19\u916e\u3001\u6c2f\u4eff\u7b49\u6709\u673a\u6eb6\u5242<\/td>\n<\/tr>\n<tr>\n<td>\u84b8\u6c7d\u538b\u529b<\/td>\n<td>25\u00b0C \u65f6\u4e3a 0.48 \u6beb\u7c73\u6c5e\u67f1<\/td>\n<\/tr>\n<tr>\n<td>\u84b8\u6c14\u5bc6\u5ea6<\/td>\n<td>3.5\uff08\u7a7a\u6c14=1\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u9178\u5ea6<\/td>\n<td>16.3<\/td>\n<\/tr>\n<tr>\n<td>\u9178\u78b1\u5ea6<\/td>\n<td>\u8fd1\u4f3c\u4e2d\u6027\uff08pH 7 \u5de6\u53f3\uff09<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n<p>\u8bf7\u6ce8\u610f\uff0c\u6240\u63d0\u4f9b\u7684\u503c\u662f\u8fd1\u4f3c\u503c\uff0c\u53ef\u80fd\u4f1a\u6839\u636e\u5177\u4f53\u6761\u4ef6\u548c\u6765\u6e90\u800c\u6709\u6240\u4e0d\u540c\u3002<\/p>\n<h2 class=\"wp-block-heading\"> <strong>2-\u5df1\u9187\u7684\u5b89\u5168\u6027\u548c\u5371\u9669\u6027<\/strong><\/h2>\n<p>Hexan-2-ol \u4f1a\u5e26\u6765\u4e00\u5b9a\u7684\u5b89\u5168\u98ce\u9669\uff0c\u5fc5\u987b\u52a0\u4ee5\u8003\u8651\u3002\u5c0f\u5fc3\u5904\u7406\u8fd9\u79cd\u5316\u5b66\u54c1\u975e\u5e38\u91cd\u8981\u3002\u76f4\u63a5\u63a5\u89e6 2-\u5df1\u9187\u53ef\u80fd\u4f1a\u523a\u6fc0\u76ae\u80a4\u548c\u773c\u775b\u3002\u6444\u5165\u6216\u5438\u5165\u9ad8\u6d53\u5ea6\u53ef\u80fd\u4f1a\u5bfc\u81f4\u547c\u5438\u56f0\u96be\u3002\u4f7f\u7528 2-\u5df1\u9187\u65f6\uff0c\u5efa\u8bae\u4f69\u6234\u9002\u5f53\u7684\u9632\u62a4\u8bbe\u5907\uff0c\u4f8b\u5982\u624b\u5957\u548c\u62a4\u76ee\u955c\u3002\u5145\u8db3\u7684\u901a\u98ce\u5bf9\u4e8e\u9632\u6b62\u84b8\u6c7d\u79ef\u805a\u81f3\u5173\u91cd\u8981\u3002\u5982\u679c\u610f\u5916\u63a5\u89e6\uff0c\u5e94\u7acb\u5373\u5c31\u533b\u3002\u5fc5\u987b\u5728\u5bc6\u95ed\u5bb9\u5668\u4e2d\u50a8\u5b58\u548c\u8fd0\u8f93 2-\u5df1\u9187\uff0c\u8fdc\u79bb\u706b\u6e90\uff0c\u4ee5\u5c3d\u91cf\u51cf\u5c11\u706b\u707e\u98ce\u9669\u3002<\/p>\n<figure class=\"wp-block-table\">\n<table>\n<tbody>\n<tr>\n<td>\u5371\u9669\u7b26\u53f7<\/td>\n<td>\u4e60\uff08\u70e6\u4eba\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u5b89\u5168\u8bf4\u660e<\/td>\n<td>\u907f\u514d\u63a5\u89e6\u773c\u775b\u548c\u76ae\u80a4\u3002\u5728\u901a\u98ce\u826f\u597d\u7684\u60c5\u51b5\u4e0b\u4f7f\u7528\u3002\u7a7f\u6234\u9632\u62a4\u670d\u548c\u624b\u5957\u3002<\/td>\n<\/tr>\n<tr>\n<td>\u8054\u5408\u56fd\u8bc6\u522b\u53f7<\/td>\n<td>\u8054\u5408\u56fd2282<\/td>\n<\/tr>\n<tr>\n<td>\u6d77\u5173\u7f16\u7801<\/td>\n<td>2905.12.00<\/td>\n<\/tr>\n<tr>\n<td>\u5371\u9669\u7b49\u7ea7<\/td>\n<td>3\uff08\u6613\u71c3\u6db2\u4f53\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u5305\u88c5\u7ec4\u522b<\/td>\n<td>\u4e09\u3001<\/td>\n<\/tr>\n<tr>\n<td>\u6bd2\u6027<\/td>\n<td>\u4e2d\u7b49\u6bd2\u6027\uff1b\u541e\u54bd\u6709\u5bb3\u6216<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>\u5438\u5165\u7684<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/figure>\n<h2 class=\"wp-block-heading\"><strong>2-\u5df1\u9187\u7684\u5408\u6210\u65b9\u6cd5<\/strong><\/h2>\n<p>\u6709\u591a\u79cd\u5408\u62102-\u5df1\u9187\u7684\u65b9\u6cd5\u3002<\/p>\n<p>\u5e38\u89c1\u7684\u65b9\u6cd5\u662f\u787c\u6c22\u5316-\u6c27\u5316\u6cd5\u3002\u5728\u6b64\u8fc7\u7a0b\u4e2d\uff0c1-\u5df1\u70ef\uff08\u4e00\u79cd\u70ef\u70c3\uff09\u5728<a href=\"https:\/\/chemuza.org\/cn\/\u56db\u6c22\u544b\u5583-thf-c4h8o\/\">\u56db\u6c22\u544b\u5583 (THF) \u7b49\u6eb6\u5242\u5b58\u5728\u4e0b\u4e0e\u787c\u70f7 (BH3) \u53cd\u5e94\u3002<\/a>\u8be5\u787c\u6c22\u5316\u6b65\u9aa4\u5bfc\u81f4\u6709\u673a\u787c\u70f7\u4e2d\u95f4\u4f53\u7684\u5f62\u6210\u3002\u4f7f\u7528\u8fc7\u6c27\u5316\u6c22 (H2O2) \u6216\u8fc7\u787c\u9178\u94a0 (NaBO3) \u6c27\u5316\u4e2d\u95f4\u4f53\u4ea7\u751f 2-\u5df1\u9187\u3002<\/p>\n<p>\u53e6\u4e00\u79cd\u65b9\u6cd5\u6d89\u53ca2-\u5df1\u916e\u7684\u50ac\u5316\u6c22\u5316\u3002\u4e3a\u4e86\u83b7\u5f97 2-\u5df1\u9187\uff0c\u9700\u8981\u5728\u6c22\u6e90\u5b58\u5728\u4e0b\u4f7f\u7528\u94c2 (Pt)\u3001\u94af (Pd) \u6216\u954d (Ni) \u7b49\u50ac\u5316\u5242\u8fd8\u539f 2-\u5df1\u916e\u3002\u8be5\u6c22\u5316\u53cd\u5e94\u5c06\u916e\u5b98\u80fd\u56e2\u8f6c\u5316\u4e3a\u7f9f\u57fa\uff0c\u4ece\u800c\u5f62\u62102-\u5df1\u9187\u3002<\/p>\n<p>\u683c\u6c0f\u53cd\u5e94\u901a\u8fc7\u683c\u6c0f\u8bd5\u5242\uff08\u4f8b\u5982\u7532\u57fa\u6eb4\u5316\u9541\uff08CH3MgBr\uff09\uff09\u4e0e<a href=\"https:\/\/chemuza.org\/cn\/\u7532\u70f7-\u7532\u919b-h2co\/\">\u7532\u919b<\/a>\uff08CH2O\uff09\u6216\u591a\u805a\u7532\u919b\uff08CH2O\uff09n\u5728\u919a\u6eb6\u5242\u4e2d\u53cd\u5e94\u6765\u5408\u6210\u5df1-2-\u9187\u3002\u8be5\u53cd\u5e94\u4ea7\u751f\u4e2d\u95f4\u4f53\uff0c\u8be5\u4e2d\u95f4\u4f53\u53d1\u751f\u6c34\u89e3\uff0c\u4ece\u800c\u4ea7\u751f 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