{"id":1489,"date":"2023-07-14T14:44:08","date_gmt":"2023-07-14T14:44:08","guid":{"rendered":"https:\/\/chemuza.org\/cn\/%e9%92%bc\/"},"modified":"2023-07-14T14:44:08","modified_gmt":"2023-07-14T14:44:08","slug":"%e9%92%bc","status":"publish","type":"page","link":"https:\/\/chemuza.org\/cn\/%e9%92%bc\/","title":{"rendered":"\u94bc"},"content":{"rendered":"<p>\u4f5c\u4e3a\u4e00\u79cd\u8fc7\u6e21\u5316\u5b66\u5143\u7d20\uff0c\u5b83\u5728\u8ba4\u8bc6\u5230\u5176\u5bf9\u751f\u7269\u7684\u91cd\u8981\u4f5c\u7528\u65b9\u9762\u662f\u72ec\u4e00\u65e0\u4e8c\u7684\u3002\u6b64\u5916\uff0c\u5b83\u901a\u5e38\u7528\u4e8e\u6c7d\u8f66\u548c\u822a\u7a7a\u5de5\u4e1a\u4e2d\u7684\u5408\u91d1\u3001\u7ed3\u6784\u4ef6\u3002\u4e86\u89e3\u94bc\u662f\u4ec0\u4e48\u3001\u5b83\u7684\u7279\u6027\u53ca\u5176\u4e00\u822c\u5e94\u7528\u3002<\/p>\n<h2><strong>\u4ec0\u4e48\u662f\u94bc\uff1f<\/strong><\/h2>\n<p>\u5b83\u662f\u4e00\u79cd\u5316\u5b66\u5143\u7d20\uff0c\u5c5e\u4e8e\u8fc7\u6e21\u91d1\u5c5e\u7cfb\u5217\u3002\u5b83\u5448\u94f6\u8272\uff0c\u5316\u5b66\u7279\u6027\u4e0e\u94ec\u76f8\u4f3c\uff0c\u786c\u5ea6\u9ad8\uff0c\u80fd\u7ea7\u9ad8\u3002\u6b64\u5916\uff0c\u5b83\u8fd8\u5177\u6709\u78c1\u6027\u3001\u826f\u597d\u7684\u5bfc\u7535\u6027\u548c\u8010\u8150\u8680\u6027\u3002\u5b83\u662f\u5730\u7403\u4e0a\u4e00\u79cd\u975e\u5e38\u4e30\u5bcc\u7684\u91d1\u5c5e\uff0c\u4f46\u4ece\u672a\u53d1\u73b0\u5176\u7eaf\u51c0\u72b6\u6001\u3002<\/p>\n<h3><strong>\u94bc\u7b26\u53f7<\/strong><\/h3>\n<p><span class=\"content-chemical-element\" style=\"float: left;width: 65px;height: 65px;border: 3px solid #666; display:flex;\n    justify-content: center;align-items: center;margin-right: 15px;\"><span style=\"font-size: 38px;\">\u94bc<\/span><\/span>\u6765\u81ea\u62c9\u4e01\u8bed<em>molybdaena<\/em> \uff0c\u662f\u7531\u94c5\u7ec4\u6210\u7684\u77ff\u7269\u8d28\u7684\u672f\u8bed\u3002\u53cd\u8fc7\u6765\uff0c\u8fd9\u4e2a\u8868\u8fbe\u65b9\u5f0f\u6765\u81ea\u5e0c\u814a\u8bed<em>molybdaina<\/em> \uff0c\u5b83\u6e90\u81ea\u5355\u8bcd<em>molybdos<\/em> 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\u989c\u8272\u94f6\u767d\u7070\uff0c\u8d28\u5730\u5149\u6ed1\uff0c\u65e0\u81ed\u3002<\/li>\n<li><strong>\u6e29\u5ea6<\/strong>\uff1a\u8010\u9ad8\u6e29\u4e14\u84b8\u6c14\u538b\u4f4e\u3002<\/li>\n<li><strong>\u6c27\u5316<\/strong>\uff1a\u5728\u5ba4\u6e29\u4e0b\u4e0d\u4f1a\u6c27\u5316\uff0c\u4f46\u5728 600\u00b0C \u4ee5\u4e0a\u65f6\u4f1a\u8fc5\u901f\u6c27\u5316\u3002<\/li>\n<li><strong>\u6c34\u4e2d\u6eb6\u89e3\u5ea6<\/strong>\uff1aMoO <sub>4<\/sub> <sup>-2<\/sup>\u79bb\u5b50\u53ef\u6eb6\uff0c\u4f46\u5728\u6c34\u4e2d\u7684\u6eb6\u89e3\u5ea6\u8f83\u4f4e\u3002<\/li>\n<li><strong>\u8010\u8150\u8680\u6027<\/strong>\uff1a\u5728\u5ba4\u6e29\u548c\u9ad8\u8fbe 400\u00b0C \u7684\u6e29\u5ea6\u4e0b\uff0c\u5b83\u80fd\u591f\u4fdd\u6301\u5176\u7a33\u5b9a\u7684\u6210\u5206\u5e76\u8010\u76d0\u9178\u3002<\/li>\n<li><strong>\u4f53\u79ef<\/strong>\uff1a\u8868\u73b0\u51fa\u70ed\u81a8\u80c0\u6216\u81a8\u80c0\u7cfb\u6570\u5c0f\u4e8e5.04\u00d710-6\uff081\/K\uff09\u3002<\/li>\n<\/ul>\n<h2><strong>\u94bc\u7684\u5316\u5b66\u548c\u7269\u7406\u6027\u8d28<\/strong><\/h2>\n<ol>\n<li><strong>\u539f\u5b50\u5e8f\u6570<\/strong>\uff1a42<\/li>\n<li><strong>\u5bc6\u5ea6\uff08\u514b\/\u6beb\u5347\uff09<\/strong> \uff1a10280\u516c\u65a4\/\u7acb\u65b9\u7c73<\/li>\n<li><strong>\u5171\u4ef7\u534a\u5f84 (\u00c5)<\/strong> \uff1a154 pm<\/li>\n<li><strong>\u7194\u5316\u7113<\/strong>\uff1a32 kJ\/mol<\/li>\n<li><strong>\u7535\u8d1f\u6027<\/strong>\uff1a2.16<\/li>\n<li><strong>\u6bd4\u70ed<\/strong>\uff1a250 J\/(K-kg)<\/li>\n<li><strong>\u539f\u5b50\u8d28\u91cf\uff08\u514b\/\u6469\u5c14\uff09<\/strong> \uff1a95.94<\/li>\n<li><strong>\u786c\u5ea6<\/strong>\uff1a5.5\uff08\u83ab\u6c0f\u786c\u5ea6\uff09<\/li>\n<li><strong>\u6cb8\u70b9<\/strong>\uff1a4639\u00b0C (4912K)<\/li>\n<li><strong>\u94c1\u9508<\/strong>\uff1a<strong> <\/strong>\u5f3a\u9178<\/li>\n<li><strong>\u539f\u5b50\u534a\u5f84 (\u00c5)<\/strong> \uff1a190 pm<\/li>\n<li><strong>\u7194\u70b9<\/strong>\uff1a2623\u00b0C (2896K)<\/li>\n<li><strong>\u7535\u5b50\u6392\u5e03<\/strong>\uff1a[Kr]4d <sup>5<\/sup> 5s <sup>1<\/sup><\/li>\n<li><strong>\u6c27\u5316\u6001<\/strong>: 2, 3, 4, 5, 6<\/li>\n<li><strong>\u6c7d\u5316\u7113<\/strong>\uff1a598 kJ\/mol<\/li>\n<li><strong>\u7b2c\u4e00\u7535\u79bb\u52bf\uff08eV\uff09<\/strong> \uff1a684.3 kJ\/mol<\/li>\n<li><strong>\u6bcf\u7ea7\u7535\u5b50\u6570<\/strong>\uff1a2\u30018\u300118\u300113\u30011<\/li>\n<\/ol>\n<h2><strong>\u94bc\u7684\u8d77\u6e90<\/strong><\/h2>\n<p>\u5b83\u5f52\u529f\u4e8e\u745e\u5178\u5316\u5b66\u5bb6 Carl Wilhelm Scheele \u5728 1778 \u5e74\u63d0\u51fa\uff0c\u5f53\u65f6\u4ed6\u5c06\u8f89\u94bc\u77ff\u77ff\u7269\u4e0e\u785d\u9178\u53cd\u5e94\uff0c\u76f4\u5230\u83b7\u5f97\u9178\u6027\u6df7\u5408\u7269\u3002\u7531\u6b64\u4ea7\u751f\u7684\u5316\u5408\u7269\u88ab\u547d\u540d\u4e3a<em>\u201cacidum<\/em> <em>molybdenae\u201d<\/em> \uff0c\u56e0\u4e3a\u76f4\u5230 18 \u4e16\u7eaa\uff0c\u8fd9\u79cd\u5143\u7d20\u4ec5\u5728\u7164\u6216\u94c5\u4e2d\u88ab\u53d1\u73b0\u3002<\/p>\n<p>\u7136\u540e\uff0c\u5728\u5b83\u88ab\u53d1\u73b0\u56db\u5e74\u540e\uff0c\u5373 1782 \u5e74\uff0c\u5316\u5b66\u5bb6 Peter Jacob Hjelm \u81f4\u529b\u4e8e\u901a\u8fc7\u7528\u78b3\u8fd8\u539f\u4ee5\u524d\u7684\u5316\u5408\u7269\u6765\u5206\u79bb\u5b83\u3002\u7136\u800c\uff0c\u4ece 19 \u4e16\u7eaa\u5f00\u59cb\uff0c\u94bc\u7684\u7279\u6027\u5f97\u5230\u4e86\u66f4\u5927\u7684\u5546\u4e1a\u548c\u5de5\u4e1a\u7528\u9014\uff0c\u4f8b\u5982\u4f5c\u4e3a\u7edd\u7f18\u5242\u3002<\/p>\n<h2><strong>\u94bc\u6709\u4ec0\u4e48\u7528\u9014\uff1f<\/strong><\/h2>\n<p>\u7531\u4e8e\u5176\u9ad8\u5f3a\u5ea6\u3001\u5b8c\u7f8e\u7684\u5bfc\u7535\u6027\u548c\u673a\u68b0\u6027\u80fd\uff0c\u5176\u5728\u7535\u7f06\u5236\u9020\u4e2d\u7684\u5e94\u7528\u5f88\u5e38\u89c1\u3002\u540c\u6837\uff0c\u77f3\u6cb9\u5de5\u4e1a\u5229\u7528\u5176\u5316\u5408\u7269\u4f5c\u4e3a\u67d0\u4e9b\u8fc7\u7a0b\u7684\u50ac\u5316\u5242\u3002\u53d1\u73b0\u8fd9\u79cd\u91d1\u5c5e\u7684\u5176\u4ed6\u7528\u9014\uff1a<\/p>\n<ul>\n<li>\u94bc\u7684\u4e3b\u8981\u529f\u80fd\u4e4b\u4e00\u5728\u4e8e\u5176\u5408\u91d1\uff0c\u7528\u4e8e\u5236\u9020\u673a\u68b0\u96f6\u4ef6\uff0c\u5e76\u80fd\u5728\u78e8\u635f\u6d3b\u52a8\u6216\u8150\u8680\u73af\u5883\u4e2d\u62b5\u6297\u65f6\u95f4\u7684\u6d41\u901d\u3002<\/li>\n<li>\u5b83\u7528\u4e8e\u6c7d\u8f66\u5de5\u4e1a\u5236\u9020\u53d1\u52a8\u673a\u96f6\u4ef6\u3002<\/li>\n<li>\u5728\u571f\u6728\u5efa\u7b51\u4e2d\u4f5c\u4e3a\u6df7\u51dd\u571f\u6dfb\u52a0\u5242\u4ee5\u62b5\u6297\u786b\u7684\u5f71\u54cd\u3002<\/li>\n<li>\u5b83\u7528\u4e8e\u5728\u67d3\u6599\u3001\u6cb9\u6f06\u3001\u67d3\u6599\u548c\u6a61\u80f6\u5316\u5408\u7269\u7684\u5236\u9020\u4e2d\u5236\u9020\u989c\u6599\u3002<\/li>\n<li>\u4e8c\u786b\u5316\u94bc\u7528\u4f5c\u53d1\u52a8\u673a\u7684\u6da6\u6ed1\u5242\u3002<\/li>\n<li>\u7528\u4e8e\u5236\u9020\u4e0d\u9508\u94a2\u7684\u5408\u91d1\u4f7f\u7528\u7ea6 6% 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